A general analytical method for evaluation of the thermodynamic properties of matters using virial coefficients with Morse potential at high temperature

WOS: 000491355000011In this paper, we established an analytical formula for the second virial coefficient (SVC) with Morse potential without using any numerical methods, and the obtained formula is applied to the calculation of the speed of sound of some matter at high temperature. This approach is based on the series expansion formula and special functions, which allows the exact evaluations of any thermodynamic properties of matter using the SVC. As an application, the obtained analytical formula is used for evaluation of the SVC with Morse potential for high-temperature gas and the plasma region of the intermolecular interactions of neutral atom gases of B, Si, Zn, H-2, N-2, O-2, NO, CO, He, Ne, Ar, Kr, and Xe. Based on the obtained formula of SVC, the speed of sound for gases of N-2, Ar, and Zn are also determined analytically. A specific maximum temperature is chosen for every gas to ensure that there are still neutral atoms in the gas, and low temperatures are avoided due to quantum effects. The results are compared with numerical data and another analytical data from the literature. The new analytical solution is shown to be in good agreement with the compared data and is verified to supply proper thermodynamic data