Three-year performance of in-situ mass stabilised contaminated site soils using MgO-bearing binders

This paper provides physical and chemical performances of mass stabilised organic and inorganic contaminated site soils using a new group of MgO-bearing binders over 3 years and evaluated the time-dependent performance during the 3 years. This study took place at a contaminated site in Castleford, UK in 2011, where MgO, ground granulated blastfurnace slag (GGBS) and Portland cement (PC) were mixed with the contaminated soils in a dry form using the ALLU mass mixing equipment. Soil cores were retrieved 40-day, 1-year and 3-year after the treatment. The core quality, strength, and the leaching properties were determined via physical observation, unconfined compressive strength (UCS) and batch leaching tests. After 3-year treatment, the UCS values of ALLU mixes were in the range of 50–250 kPa; the leachate concentrations of Cd, Pb, Cu and Zn (except Ni) in all mixes were lower than their drinking water standards; and the leachability of total organics was in the range of 10–105 mg/L. No apparent degradation of the mass stabilised materials after 3 years’ exposure to the field conditions was found. MgO-GGBS blends were found able to provide higher strength and less leachability of contaminants compared to PC and MgO-only mixes in mass stabilised soils

The Impact of Cultural Familiarity on Students’ Social Media Usage in Higher Education

Using social media (SM) in Higher education (HE) becomes unavoidable in the new teaching and learning pedagogy. The current generation of students creates their groups on SM for collaboration. However, SM can be a primary source of learning distraction due to its nature, which does not support structured learning. Hence, derived from the literature, this study proposes three learning customised system features, to be implemented on SM when used in Higher Education HE. Nevertheless, some psychological factors appear to have a stronger impact on students’ adoption of SM in learning than the proposed features. A Quantitative survey was conducted at a university in Uzbekistan to collect 52 undergraduate students’ perception of proposed SM learning customised features in Moodle. These features aim to provide localised, personalised, and privacy control self-management environment for collaboration in Moodle. These features could be significant in predicting students’ engagement with SM in HE. The data analysis showed a majority of positive feedback towards the proposed learning customised SM. However, the surveyed students’ engagement with these features was observed as minimal. The course leader initiated a semi-structured interview to investigate the reason. Although the students confirmed their acceptance of the learning customised features, their preferences to alternate SM, which is Telegram overridden their usage of the proposed learning customized SM, which is Twitter. The students avoided the Moodle integrated Twitter (which provided highly accepted features) and chose to use the Telegram as an external collaboration platform driven by their familiarity and social preferences with the Telegram since it is the popular SM in Uzbekistan. This study is part of an ongoing PhD research which involves deeper frame of learners’ cognitive usage of the learning management system. However, this paper exclusively discusses the cultural familiarity impact of student’s adoption of SM in HE

Strength and drying shrinkage of slag paste activated by sodium carbonate and reactive MgO

This paper investigates the potential of combining Na2CO3 and reactive MgO as a sustainable activator for ground granulated blastfurnace slag. Two very different reactivity MgOs were added at 5–10 % and the Na2CO3 content varied from 4% to 8% by the weight of slag. The strength and drying shrinkage of the activated slag pastes were tested up to 90 d. It was found that the optimum reactive MgO addition was 5% regardless of the MgO type and Na2CO3 content. MgO with the higher reactivity significantly increased the early strength of the paste but had almost no effect on the strength at 90 d. On the other hand, the effect of the lower reactivity MgO on the strength was more profound at later ages and low Na2CO3 dosage. In terms of drying shrinkage, increasing the Na2CO3 content from 4% to 6% caused a remarkable decrease of drying shrinkage while increasing it from 6% to 8% had negligible effect. X-ray diffraction and thermogravimetric analysis revealed that the major hydration products were calcium silicate hydrate gel and hydrotalcite-like phases, similar to those in conventional alkali-activated slag cements. There was also a large quantity of calcite formed especially in the 8% Na2CO3 pastes due to causticisation. It was concluded that the combination of reactive MgO and Na2CO3 could serve as a potential sustainable activator for slags.The first author is grateful to Cambridge Trust and China Scholarship Council (CSC) for sponsoring his Ph.D. studentship.This is the accepted manuscript for a paper published in Construction and Building Materials, Volume 81, 15 April 2015, Pages 58–65, doi:10.1016/j.conbuildmat.2015.01.08

Evaluation of novel reactive MgO activated slag binder for the immobilisation of lead and zinc.

Although Portland cement is the most widely used binder in the stabilisation/solidification (S/S) processes, slag-based binders have gained significant attention recently due to their economic and environmental merits. In the present study, a novel binder, reactive MgO activated slag, is compared with hydrated lime activated slag in the immobilisation of lead and zinc. A series of lead or zinc-doped pastes and mortars were prepared with metal to binder ratio from 0.25% to 1%. The hydration products and microstructure were studied by X-ray diffraction, thermogravimetric analysis and scanning electron microscopy. The major hydration products were calcium silicate hydrate and hydrotalcite-like phases. The unconfined compressive strength was measured up to 160 d. Findings show that lead had a slight influence on the strength of MgO-slag paste while zinc reduced the strength significantly as its concentration increased. Leachate results using the TCLP tests revealed that the immobilisation degree was dependent on the pH and reactive MgO activated slag showed an increased pH buffering capacity, and thus improved the immobilisation efficiency compared to lime activated slag. It was proposed that zinc was mainly immobilised within the structure of the hydrotalcite-like phases or in the form of calcium zincate, while lead was primarily precipitated as the hydroxide. It is concluded, therefore, that reactive MgO activated slag can serve as clinker-free alternative binder in the S/S process.The authors are grateful to Cambridge Trust and China Scholarship Council (CSC) for their financial help of the PhD studentship for the first author.This is the accepted manuscript version. The final version is published by Chemosphere here: http://dx.doi.org/10.1016/j.chemosphere.2014.07.027

CD137 signaling regulates acute colitis via RALDH2-expressing CD11b−CD103+ DCs

CD137, a potent costimulatory receptor for CD

Memristor-based Synaptic Networks and Logical Operations Using In-Situ Computing

We present new computational building blocks based on memristive devices. These blocks, can be used to implement either supervised or unsupervised learning modules. This is achieved using a crosspoint architecture which is an efficient array implementation for nanoscale two-terminal memristive devices. Based on these blocks and an experimentally verified SPICE macromodel for the memristor, we demonstrate that firstly, the Spike-Timing-Dependent Plasticity (STDP) can be implemented by a single memristor device and secondly, a memristor-based competitive Hebbian learning through STDP using a $1\times 1000$ synaptic network. This is achieved by adjusting the memristor's conductance values (weights) as a function of the timing difference between presynaptic and postsynaptic spikes. These implementations have a number of shortcomings due to the memristor's characteristics such as memory decay, highly nonlinear switching behaviour as a function of applied voltage/current, and functional uniformity. These shortcomings can be addressed by utilising a mixed gates that can be used in conjunction with the analogue behaviour for biomimetic computation. The digital implementations in this paper use in-situ computational capability of the memristor.Comment: 18 pages, 7 figures, 2 table

Three-year performance of in-situ solidified/stabilised soil using novel MgO-bearing binders.

A new group of MgO-bearing binders has been developed recently which showed improved sustainability and technical performance compared to Portland cement (PC). However, the application of these MgO-bearing binders in the Solidification/Stabilisation (S/S) techniques is very limited. This study investigates the three-year performance of a highly contaminated soil treated by in-situ S/S using MgO-bearing binders and PC. The core quality, strength, permeability and the leaching properties of the S/S materials were evaluated. The effects of binder composition, addition of inorgano-organo-clay (IOC) and the grout content on the properties of the 3-y S/S materials are discussed. It is found that although MgO alone provided negligible strength to the soil, it is superior in immobilising both inorganic and organic contaminants. Replacing MgO by ground granulated blast-furnace slag (GGBS) significantly enhanced the strength while also performed well in immobilising the contaminants. The improved pH buffering capacity was attributed to the low solubilities of brucite and hydrotalcite-like phases formed in the MgO-bearing binders, and was also the reason for the improved performance in stabilising contaminants. The addition of IOC slightly decreased the strength and the permeability of the S/S materials but inconsistent effect on the contaminant immobilisation was found depending on the binder composition. This study showed no degradation of the S/S materials after 3 y exposure to field conditions and has proved the applicability and the advantages of MgO-bearing binders over PC in S/S.The authors are grateful to the funding from EPSRC (Grant No.: NMZJ/116 RG60240) to support this research. The samples were all retreived from a field trial sponsored by EPSRC/TSB (Grant No.: TP/5/CON/6/I/H0304E).This is the final version of the article. It first appeared from Elsevier via http://dx.doi.org/10.1016/j.chemosphere.2015.09.046 The data reported in this study can be accessed at: http://www.repository.cam.ac.uk/handle/1810/250325

Strength and hydration properties of reactive MgO-activated ground granulated blastfurnace slag paste

Ground granulated blastfurnace slag (GGBS) is widely used as a partial replacement for Portland cement or as the major component in the alkali-activated cement to give a clinker-free binder. In this study, reactive MgO is investigated as a potentially more practical and greener alternative as a GGBS activator. This paper focuses on of the hydration of GGBS, activated by two commercial reactive MgOs, with contents ranging from 2.5% to 20% up to 90 days. The hydration kinetics and products of MgO–GGBS blends were investigated by selective dissolution, thermogravimetric analysis, X-ray diffraction and scanning electron microscopy techniques. It was found that reactive MgO was more effective than hydrated lime in activating the GGBS based on unconfined compressive strength and the efficiency increased with the reactivity and the content of the MgO. It is hence proposed that reactive MgO has the potential to serve as an effective and economical activator for GGBS.The authors are grateful to Cambridge Trust and China Scholarship Council (CSC) for their financial help of the PhD studentship for the first author.This is the accepted manuascript for a paper published in Cement and Concrete Composites, Volume 57, March 2015, Pages 8–16, doi:10.1016/j.cemconcomp.2014.10.00