Pengaruh Gaya Kepemimpinan Transformasional Dan Komunikasi Organisasi Terhadap Kinerja Karyawan (Studi Pada Karyawan Bank Jatim Cabang Malang)

The purpose of this research are: Firstly, to determine and analyze the effect of transformational leadership style on employees work performance. Secondly, to find and analyze the impact of organizational communication on employees work performance. Thirdly, to determine and analyze the influence of transformational leadership style and organizational communication simultaneously on employees work performance. The type of this research is survey with quantitive approach. The population in this research was all employees of Jatim bank Malang as many as 74 people. This research was using saturate or census sampling technique, that is establishment of the number samples from all members of the population is 74 people. This research used analyze tool which multiple linear regression analysis. The results of this study indicate that: (1) transformational leadership style has a significant positive effect on employee work performance. (2) organizational communication has a significant positive effect on employee work performance. (3) simultaneously, transformational leadership style and organizational communication has significantly effect to employee work performance. (4) this research resulted that the influence of transformational leadership style and organizational communication to employee performance by 56.6% while the remaining 43.4% is influenced by other factors. For instance, one of them is ability which can affect to employee work performance. (5) in terms of affecting employee work performance, transformational leadership style experienced more dominant than organizationalcommunication

Geometrothermodynamics in Horava-Lifshitz gravity

We investigate the thermodynamic geometries of the most general static, spherically symmetric, topological black holes of the Ho\v{r}ava--Lifshitz gravity. In particular, we show that a Legendre invariant metric derived in the context of geometrothermodynamics for the equilibrium manifold reproduces correctly the phase transition structure of these black holes. Moreover, the limiting cases in which the mass, the entropy or the Hawking temperature vanish are also accompanied by curvature singularities which indicate the limit of applicability of the thermodynamics and the geometrothermodynamics of black holes. The Einstein limit and the case of a black hole with flat horizon are also investigated.Comment: Preliminary draf

Preparation and structural characterization of nickel(II), cobalt(II), zinc(II) and tin(IV) complexes of the isatin Schiff bases of S-methyl and S-benzyldithiocarbazates

The molecular structures of the isatin Schiff bases of S- methyldithiocarbazate (Hisasme) and S-benzyldithiocarbazate (Hisasbz) have been determined by X-ray diffraction and their complexes of general formula [ML ]·n(solvate) [M = Co, Ni, Zn ; L = anionic forms of Hisasme or Hisasbz; solvate = DMF, DMSO; n = 1, 2] and [Sn(L)PhCl]·nMeOH (n = 0, 1) have been synthesized and characterized by a variety of physicochemical techniques and X-ray diffraction. The bis-ligand complexes, [Ni(isasbz)]·2DMSO and [Co(isasme)]·DMF have a six-coordinate, distorted octahedral geometry with the two uninegatively charged tridentate ONS ligands coordinated to the metal ions meridionally via the amide O-atoms, the azomethine nitrogen atoms and the thiolate sulfur atoms. By contrast, the crystal structure of [Zn(isasbz)]·2DMF shows a four-coordinate distorted tetrahedral geometry with the two Schiff bases coordinated as NS bidentate ligands via the azomethine nitrogen atoms and the thiolate sulfur atoms. Steric constraints of the rigid tridentate ligands lead to unusual 'pseudo- coordination' of the O-donors which occupy sites close to the metal but too distant to be considered as true coordinate bonds. The crystal structures of the tin(IV) complexes [SnLPhCl]·nMeOH (L = isasme and isasbz; n = 0, 1) also show that the Schiff bases act as monoanionic bidentate NS chelating agents coordinating the tin(IV) ion via the azomethine nitrogen atoms and the thiolate sulfur atoms, the tin atom in each complex is five-coordinate with a highly distorted geometry intermediate of square pyramidal and trigonal bipyramidal. Again Sn⋯O contacts are weak and do not qualify as coordinate bonds

Synthesis, characterization and X-ray crystallographic structural study of copper(II) and nickel(II) complexes of the 2-quinoline carboxaldehyde Schiff base of S-methyldithiocarbazate (Hqaldsme)

Complexes of general formulae, [Cu(qaldsme)(X)(CH3OH)(n)] and [Ni(qaldsme)(2)] (.) 0.5CH(3)CN (qaldsme = anionic form of the 2-quinoline carboxaldehyde Schiff base of S-methyldithiocarbazate; X = NCS-, I-, NO3-; n = 0 or 1) have been synthesized and characterized by magnetic and spectroscopic techniques. X-ray crystal structure determination of [Cu(qaldsme)(ONO2)(CH3OH)] (1), [Cu(qaldsme)(NCS)](2) (2) and [Ni(qaldsme)(2)] (.) 0.5CH(3)CN (4) shows that the nitrato-complex of copper (1) is monomeric and five-coordinate and the thiocyanato-complex (2) has a novel thiolate sulfur-bridged dimeric structure in which each of the copper(II) ions adopts a five-coordinate, approximately square-pyramidal geometry, with a CuN3S2 coordination kernel. The nickel(II) complex (3) has a distorted octahedral geometry with meridional dispositions of the two uninegatively charged tridentate NNS ligands. In all these complexes, the Schiff bases are coordinated in their iminothiolate forms via the quinoline nitrogen atom, the azomethine nitrogen atom and the thiolate sulfur atom. (c) 2006 Elsevier Ltd. All rights reserved

Preparation, spectroscopic characterization and X-ray crystal and molecular structures of nickel(II), copper(II) and zinc(II) complexes of the Schiff base formed from isatin and S-methyldithiocarbazate (Hisa-sme)

Complexes of general formula, [M(isa-sme)2] · n(solvate) [M = Ni2+, Cu2+, Zn2+, Cd2+; isa-sme = monoanionic form of the Schiff base formed by condensation of isatin with S-methyldithiocarbazate; n = 1 or 1.5; solvate = MeCN, DMSO, MeOH or H2O] have been synthesized and characterized by a variety of physicochemical techniques. An X-ray crystallographic structure determination of the [Ni(isa-sme)2] · MeCN complex reveals a six-coordinate, distorted octahedral geometry. The two uninegatively charged, tridentate, Schiff base ligands are coordinated to the nickel(II) ion meridionally via the amide O-atoms, the azomethine N-atoms and the thiolate S-atoms. By contrast, the crystal structure of [Zn(isa-sme)2] · MeOH shows a four-coordinate distorted tetrahedral geometry. The two dithiocarbazate ligands are coordinated as N, S bidentate chelates with the amide O-atom not coordinated. The structure of the copper(II) complex [Cu(isa-sme)2] · DMSO is complicated and comprises two different complexes in the asymmetric unit, one four- and the other five-coordinate. The four-coordinate copper(II) has a distorted (flattened) tetrahedral geometry as seen in the Zn(II) analogue whereas the five-coordinate copper(II) has a distorted square-pyramidal geometry with one ligand coordinated to the copper(II) ion as a tridentate (N, S, O) ligand and the other coordinated as a bidentate N, S chelate. EPR spectroscopy indicates that in solution only one form is present, that being a distorted tetrahedral complex