Effect of Anisotropic Reactivity on the Rate of Diffusion-Controlled Reactions: Comparative Analysis of the Models of Patches and Hemispheres

AbstractA comparative analysis of two models of anisotropic reactivity in bimolecular diffusion-controlled reaction kinetics is presented. One is the conventional model of reactive patches (MRP), where the surface of a molecule is assumed to be reactive over a certain region (circular patch) with the rest of the surface being inert. Another one is the model of reactive hemispheres (MRH), assuming that a molecule is reactive within a certain distance from a point on its surface. The accuracy of the known and newly derived simple analytical expressions for the reaction rate is tested by comparison with the simulation results obtained by the original Brownian dynamics method. These formulas prove to be quite accurate in the practically important limit of strong anisotropy corresponding to small size of the reactive patches or hemispheres. Numerical calculations confirm earlier predictions that the MRP rates are much smaller than the MRH rates for the same radii of the reactive regions, especially in the case where both reacting molecules are anisotropic

Effect of nodes, ellipticity and impurities on the spin resonance in Iron-based superconductors

We analyze doping dependence of the spin resonance of an s+- superconductor and its sensitivity to the ellipticity of electron pockets, to magnetic and non-magnetic impurities, and to the angle dependence of the superconducting gap along electron Fermi surfaces. We show that the maximum intensity of the resonance shifts from commensurate to incommensurate momentum above some critical doping which decreases with increasing ellipticity. Angle dependence of the gap and particularly the presence of accidental nodes lowers the overall intensity of the resonance peak and shifts its position towards the onset of the particle-hole continuum. Still, however, the resonance remains a true \delta-function in the clean limit. When non-magnetic or magnetic impurities are present, the resonance broadens and its position shifts. The shift depends on the type of impurities and on the ratio of intraband and interband scattering components. The ratio Omega_{res}/T_c increases almost linearly with the strength of the interband impurity scattering, in agreement with the experimental data. We also compare spin response of s+- and s++ superconductors. We show that there is no resonance for s++ gap, even when there is a finite mismatch between electron and hole Fermi surfaces shifted by the antiferromagnetic momentum.Comment: 12 pages, 10 figures, submitted to PR

Crossover and scaling in a nearly antiferromagnetic Fermi liquid in two dimensions

We consider two-dimensional Fermi liquids in the vicinity of a quantum transition to a phase with commensurate, antiferromagnetic long-range order. Depending upon the Fermi surface topology, mean-field spin-density-wave theory predicts two different types of such transitions, with mean-field dynamic critical exponents $z=1$ (when the Fermi surface does not cross the magnetic zone boundary, type $A$) and $z=2$ (when the Fermi surface crosses the magnetic zone boundary, type $B$). The type $A$ system only displays $z=1$ behavior at all energies and its scaling properties are similar (though not identical) to those of an insulating Heisenberg antiferromagnet. Under suitable conditions precisely stated in this paper, the type $B$ system displays a crossover from relaxational behavior at low energies to type $A$ behavior at high energies. A scaling hypothesis is proposed to describe this crossover: we postulate a universal scaling function which determines the entire, temperature-, wavevector-, and frequency-dependent, dynamic, staggered spin susceptibility in terms of 4 measurable, $T=0$, parameters (determining the distance, energy, and order parameter scales, plus one crossover parameter). The scaling function contains the full scaling behavior in all regimes for both type $A$ and $B$ systems. The crossover behavior of the uniform susceptibility and the specific heat is somewhat more complicated and is also discussed. Explicit computation of the crossover functions is carried out in a large $N$ expansion on a mean-field model. Some new results for the critical properties on the ordered side of the transition are also obtained in a spin-density wave formalism. The possible relevance of our results to the doped cuprate compounds is briefly discussed.Comment: 20 pages, REVTeX, 6 figures (uuencoded compressed PostScript file for figures is appended

Effect of point-contact transparency on coherent mixing of Josephson and transport supercurrents

The influence of electron reflection on dc Josephson effect in a ballistic point contact with transport current in the banks is considered theoretically. The effect of finite transparency on the vortex-like currents near the contact and at the phase difference $\phi =\pi ,$ which has been predicted recently \cite{KOSh}, is investigated. We show that at low temperatures even a small reflection on the contact destroys the mentioned vortex-like current states, which can be restored by increasing of the temperature.Comment: 6 pages, 8 Figures, Latex Fil

Quasiparticle spectrum in a nearly antiferromagnetic Fermi liquid: shadow and flat bands

We consider a two-dimensional Fermi liquid in the vicinity of a spin-density-wave transition to a phase with commensurate antiferromagnetic long-range order. We assume that near the transition, the Fermi surface is large and crosses the magnetic Brillouin zone boundary. We show that under these conditions, the self-energy corrections to the dynamical spin susceptibility, $\chi (q, \omega)$, and to the quasiparticle spectral function function, $A(k, \omega)$, are divergent near the transition. We identify and sum the series of most singular diagrams, and obtain a solution for $\chi(q, \omega)$ and an approximate solution for $A(k, \omega)$. We show that (i) $A(k)$ at a given, small $\omega$ has an extra peak at $k = k_F + \pi$ (`shadow band'), and (ii) the dispersion near the crossing points is much flatter than for free electrons. The relevance of these results to recent photoemission experiments in $YBCO$ and $Bi2212$ systems is discussed.Comment: a sign and amplitude of the vertex renormalization and few typos are correcte

Microscopic theory of weak pseudogap behavior in the underdoped cuprate superconductors I: General theory and quasiparticle properties

We derive in detail a novel solution of the spin fermion model which is valid in the quasi-static limit pi T<<omega_sf, found in the intermediate (pseudoscaling) regime of the magnetic phase diagram of cuprate superconductors, and use it to obtain results for the temperature and doping dependence of the single particle spectral density, the electron-spin fluctuation vertex function, and the low frequency dynamical spin susceptibility. The resulting strong anisotropy of the spectral density and the vertex function lead to the qualitatively different behavior of_hot_ (around k=(pi,0)) and_cold_ (around k=(pi/2,pi/2)) quasiparticles seen in ARPES experiments. We find that the broad high energy features found in ARPES measurements of the spectral density of the underdoped cuprate superconductors are determined by strong antiferromagnetic (AF) correlations and incoherent precursor effects of an SDW state, with reduced renormalized effective coupling constant. The electron spin-fluctuation vertex function, i.e. the effective interaction of low energy quasiparticles and spin degrees of freedom, is found to be strongly anisotropic and enhanced for hot quasiparticles; the corresponding charge-fluctuation vertex is considerably diminished. We thus demonstrate that, once established, strong AF correlations act to reduce substantially the effective electron-phonon coupling constant in cuprate superconductors.Comment: REVTEX with EPS figures, uses multicol.sty, epsfig,sty, psfig.st

Charge and spin density wave ordering transitions in strongly correlated metals

We study the quantum transition from a strongly correlated metal, with heavy fermionic quasiparticles, to a metal with commensurate charge or spin density wave order. To this end, we introduce and numerically analyze a large dimensionality model of Ising spins in a transverse field, coupled to two species of fermions; the analysis borrows heavily from recent progress in the solution of the Hubbard model in large dimensions. At low energies, the Ising order parameter fluctuations are characterized by the critical exponent $z \nu = 1$, while above an energy scale, $\Gamma$, there is a crossover to $z\nu = 1/2$ criticality. We show that $\Gamma$ is of the order of the width of the heavy quasiparticle band, and can be made arbitrarily small for a correlated metal close to a Mott-Hubbard insulator. Therefore, such a correlated metal has a significant intermediate energy range of $z\nu=1/2$ behavior, a single particle spectrum with a narrow quasiparticle band, and well-formed analogs of the lower and upper Hubbard bands; we suggest that these features are intimately related in general.Comment: 14 pages, REVTEX 3.0, 2 postscript figure

Survival probability of a diffusing particle in the presence of Poisson-distributed mobile traps

The problem of a diffusing particle moving among diffusing traps is analyzed in general space dimension d. We consider the case where the traps are initially randomly distributed in space, with uniform density rho, and derive upper and lower bounds for the probability Q(t) (averaged over all particle and trap trajectories) that the particle survives up to time t. We show that, for 1<=d<2, the bounds converge asymptotically to give $Q(t) \sim exp(-\lambda_d t^{d/2})$ where $\lambda_d = (2/\pi d) sin(\pi d/2) (4\pi D)^{d/2} \rho$ and D is the diffusion constant of the traps, and that $Q(t) \sim exp(- 4\pi\rho D t/ln t)$ for d=2. For d>2 bounds can still be derived, but they no longer converge for large t. For 1<=d<=2, these asymptotic form are independent of the diffusion constant of the particle. The results are compared with simulation results obtained using a new algorithm [V. Mehra and P. Grassberger, Phys. Rev. E v65 050101 (2002)] which is described in detail. Deviations from the predicted asymptotic forms are found to be large even for very small values of Q(t), indicating slowly decaying corrections whose form is consistent with the bounds. We also present results in d=1 for the case where the trap densities on either side of the particle are different. For this case we can still obtain exact bounds but they no longer converge.Comment: 13 pages, RevTeX4, 6 figures. Figures and references updated; equations corrected; discussion clarifie

Spin correlations in the algebraic spin liquid - implications for high Tc superconductors

We propose that underdoped high $T_c$ superconductors are described by an algebraic spin liquid (ASL) at high energies, which undergoes a spin-charge recombination transition at low energies. The spin correlation in the ASL is calculated via its effective theory - a system of massless Dirac fermions coupled to a U(1) gauge field. We find that without fine tuning any parameters the gauge interaction strongly enhances the staggered spin correlation even in the presence of a large single particle pseudo-gap. This allows us to show that the ASL plus spin-charge recombination picture can explain many highly unusual properties of underdoped high $T_c$ superconductors.Comment: 22 pages, 18 figures, submitted to PR

Quantum Disordered Regime and Spin Gap in the Cuprate Superconductors

We discuss the crossover from the quantum critical, $z\!=\!1$, to the quantum disordered regime in high-T$_c$ materials in relation to the experimental data on the nuclear relaxation, bulk susceptibility, and inelastic neutron scattering. In our scenario, the spin excitations develop a gap $\Delta\!\sim\!1/\xi$ well above T$_c$, which is supplemented by the quasiparticle gap below T$_c$. The above experiments yield consistent estimates for the value of the spin gap, which increases as the correlation length decreases.Comment: 14 pages, REVTeX v3.0, PostScript file for 3 figures is attached, UIUC-P-93-07-06