Nature of bonding and electronic structure in MgB2, a boron intercalation superconductor

Chemical bonding and electronic structure of MgB2, a boron-based newly discovered superconductor, is studied using self-consistent band structure techniques. Analysis of the transformation of the band structure for the hypothetical series of graphite - primitive graphite - primitive graphite-like boron - intercalated boron, shows that the band structure of MgB2 is graphite-like, with pi-bands falling deeper than in ordinary graphite. These bands possess a typically delocalized and metallic, as opposed to covalent, character. The in-plane sigma-bands retain their 2D covalent character, but exhibit a metallic hole-type conductivity. The coexistence of 2D covalent in-plane and 3D metallic-type interlayer conducting bands is a peculiar feature of MgB2. We analyze the 2D and 3D features of the band structure of MgB2 and related compounds, and their contributions to conductivity.Comment: 4 pages in revtex, 3 figures in 4 separate EPS file

Ginzburg-Landau theory of vortices in a multi-gap superconductor

The Ginzburg-Landau functional for a two-gap superconductor is derived within the weak-coupling BCS model. The two-gap Ginzburg-Landau theory is, then, applied to investigate various magnetic properties of MgB2 including an upturn temperature dependence of the transverse upper critical field and a core structure of an isolated vortex. Orientation of vortex lattice relative to crystallographic axes is studied for magnetic fields parallel to the c-axis. A peculiar 30-degree rotation of the vortex lattice with increasing strength of an applied field observed by neutron scattering is attributed to the multi-gap nature of superconductivity in MgB2.Comment: 11 page