200 research outputs found
Depth concentrations of deuterium ions implanted into some pure metals and alloys
Pure metals (Cu, Ti, Zr, V, Pd) and diluted Pd-alloys (Pd-Ag, Pd-Pt, Pd-Ru,
Pd-Rh) were implanted by 25 keV deuterium ions at fluences in the range
(1.2{\div}2.3)x1022 D+/m2. The post-treatment depth distributions of deuterium
ions were measured 10 days and three months after the implantation using
Elastic Recoil Detection Analysis (ERDA) and Rutherford Backscattering (RBS).
Comparison of the obtained results allowed to make conclusions about relative
stability of deuterium and hydrogen gases in pure metals and diluted Pd alloys.
Very high diffusion rates of implanted deuterium ions from V and Pd pure metals
and Pd alloys were observed. Small-angle X-ray scattering revealed formation of
nanosized defects in implanted corundum and titanium.Comment: 12 pages, 9 figure
Electronic Structure of the Complex Hydride NaAlH4
Density functional calculations of the electronic structure of the complex
hydride NaAlH4 and the reference systems NaH and AlH3 are reported. We find a
substantially ionic electronic structure for NaAlH4, which emphasizes the
importance of solid state effects in this material. The relaxed hydrogen
positions in NaAlH4 are in good agreement with recent experiment. The
electronic structure of AlH3 is also ionic. Implications for the binding of
complex hydrides are discussed.Comment: 4 pages, 5 figure
Mechanical characterisation of polymer of intrinsic microporosity PIM-1 for hydrogen storage applications
Polymers of intrinsic microporosity (PIMs) are currently attracting interest due to their unusual combination of high surface areas and capability to be processed into free-standing films. However, there has been little published work with regards to their physical and mechanical properties. In this paper, detailed characterisation of PIM-1 was performed by considering its chemical, gas adsorption and mechanical properties. The polymer was cast into films, and characterised in terms of their hydrogen adsorption at â196 °C up to much higher pressures (17 MPa) than previously reported (2 MPa), demonstrating the maximum excess adsorbed capacity of the material and its uptake behaviour in higher pressure regimes. The measured tensile strength of the polymer film was 31 MPa with a Youngâs modulus of 1.26 GPa, whereas the average storage modulus exceeded 960 MPa. The failure strain of the material was 4.4%. It was found that the film is thermally stable at low temperatures, down to â150 °C, and decomposition of the material occurs at 350 °C. These results suggest that PIM-1 has sufficient elasticity to withstand the elastic deformations occurring within state-of-the-art high-pressure hydrogen storage tanks and sufficient thermal stability to be applied at the range of temperatures necessary for gas storage applications
INFLUENCE OF ELECTRODE THICKNESS ON CHARGE DISCHARGE BEHAVIOR OF AB(5)-TYPE METAL HYDRIDE ELECTRODES
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