1,205 research outputs found
Phase Separation in Binary Fluid Mixtures with Continuously Ramped Temperature
We consider the demixing of a binary fluid mixture, under gravity, which is
steadily driven into a two phase region by slowly ramping the temperature. We
assume, as a first approximation, that the system remains spatially isothermal,
and examine the interplay of two competing nonlinearities. One of these arises
because the supersaturation is greatest far from the meniscus, creating
inversion of the density which can lead to fluid motion; although isothermal,
this is somewhat like the Benard problem (a single-phase fluid heated from
below). The other is the intrinsic diffusive instability which results either
in nucleation or in spinodal decomposition at large supersaturations.
Experimental results on a simple binary mixture show interesting oscillations
in heat capacity and optical properties for a wide range of ramp parameters. We
argue that these oscillations arise under conditions where both nonlinearities
are important
A cluster mode-coupling approach to weak gelation in attractive colloids
Mode-coupling theory (MCT) predicts arrest of colloids in terms of their
volume fraction, and the range and depth of the interparticle attraction. We
discuss how effective values of these parameters evolve under cluster
aggregation. We argue that weak gelation in colloids can be idealized as a
two-stage ergodicity breaking: first at short scales (approximated by the bare
MCT) and then at larger scales (governed by MCT applied to clusters). The
competition between arrest and phase separation is considered in relation to
recent experiments. We predict a long-lived `semi-ergodic' phase of mobile
clusters, showing logarithmic relaxation close to the gel line.Comment: 4 pages, 3 figure
Coexistence and Phase Separation in Sheared Complex Fluids
We demonstrate how to construct dynamic phase diagrams for complex fluids
that undergo transitions under flow, in which the conserved composition
variable and the broken-symmetry order parameter (nematic, smectic,
crystalline, etc.) are coupled to shear rate. Our construction relies on a
selection criterion, the existence of a steady interface connecting two stable
homogeneous states. We use the (generalized) Doi model of lyotropic nematic
liquid crystals as a model system, but the method can be easily applied to
other systems, provided non-local effects are included.Comment: 4 pages REVTEX, 5 figures using epsf macros. To appear in Physical
Review E (Rapid Communications
Are polymer melts "ideal"?
It is commonly accepted that in concentrated solutions or melts
high-molecular weight polymers display random-walk conformational properties
without long-range correlations between subsequent bonds. This absence of
memory means, for instance, that the bond-bond correlation function, , of
two bonds separated by monomers along the chain should exponentially decay
with . Presenting numerical results and theoretical arguments for both
monodisperse chains and self-assembled (essentially Flory size-distributed)
equilibrium polymers we demonstrate that some long-range correlations remain
due to self-interactions of the chains caused by the chain connectivity and the
incompressibility of the melt. Suggesting a profound analogy with the
well-known long-range velocity correlations in liquids we find, for instance,
to decay algebraically as . Our study suggests a precise
method for obtaining the statistical segment length \bstar in a computer
experiment.Comment: 4 pages, 3 figure
Zero-range processes with saturated condensation: the steady state and dynamics
We study a class of zero-range processes in which the real-space condensation
phenomenon does not occur and is replaced by a saturated condensation: that is,
an extensive number of finite-size "condensates" in the steady state. We
determine the conditions under which this occurs, and investigate the dynamics
of relaxation to the steady state. We identify two stages: a rapid initial
growth of condensates followed by a slow process of activated evaporation and
condensation. We analyze these nonequilibrium dynamics with a combination of
meanfield approximations, first-passage time calculations and a
fluctuation-dissipation type approach.Comment: 21 pages, 12 figure
Dynamics of a polymer in a quenched random medium: A Monte Carlo investigation
We use an off - lattice bead - spring model of a self - avoiding polymer
chain immersed in a 3-dimensional quenched random medium to study chain
dynamics by means of a Monte - Carlo (MC) simulation. The chain center of mass
mean-squared displacement as a function of time reveals two crossovers which
depend both on chain length and on the degree of Gaussian disorder
. The first one from normal to anomalous diffusion regime is found at
short time and observed to vanish rapidly as with growing disorder. The second crossover back to normal diffusion,
, scales as with
being some scaling function. The diffusion coefficient depends strongly
on disorder and drops dramatically at a {\em critical dispersion} of the disorder potential so that for the chain center of mass is practically frozen.The time-dependent
Rouse modes correlation function reveals a characteristic plateau at
which is the hallmark of a non - ergodic regime. These
findings agree well with our recent theoretical predictions.Comment: 7 pages, 6 figures, submitted to Europhys. Letter
Two-Dimensional Copolymers and Exact Conformal Multifractality
We consider in two dimensions the most general star-shaped copolymer, mixing
random (RW) or self-avoiding walks (SAW) with specific interactions thereof.
Its exact bulk or boundary conformal scaling dimensions in the plane are all
derived from an algebraic structure existing on a random lattice (2D quantum
gravity). The multifractal dimensions of the harmonic measure of a 2D RW or SAW
are conformal dimensions of certain star copolymers, here calculated exactly as
non rational algebraic numbers. The associated multifractal function f(alpha)
are found to be identical for a random walk or a SAW in 2D. These are the first
examples of exact conformal multifractality in two dimensions.Comment: 4 pages, 2 figures, revtex, to appear in Phys. Rev. Lett., January
199
Multifractal Dimensions for Branched Growth
A recently proposed theory for diffusion-limited aggregation (DLA), which
models this system as a random branched growth process, is reviewed. Like DLA,
this process is stochastic, and ensemble averaging is needed in order to define
multifractal dimensions. In an earlier work [T. C. Halsey and M. Leibig, Phys.
Rev. A46, 7793 (1992)], annealed average dimensions were computed for this
model. In this paper, we compute the quenched average dimensions, which are
expected to apply to typical members of the ensemble. We develop a perturbative
expansion for the average of the logarithm of the multifractal partition
function; the leading and sub-leading divergent terms in this expansion are
then resummed to all orders. The result is that in the limit where the number
of particles n -> \infty, the quenched and annealed dimensions are {\it
identical}; however, the attainment of this limit requires enormous values of
n. At smaller, more realistic values of n, the apparent quenched dimensions
differ from the annealed dimensions. We interpret these results to mean that
while multifractality as an ensemble property of random branched growth (and
hence of DLA) is quite robust, it subtly fails for typical members of the
ensemble.Comment: 82 pages, 24 included figures in 16 files, 1 included tabl
Theory and simulation of gelation, arrest and yielding in attracting colloids
We present some recent theory and simulation results addressing the phenomena
of colloidal gelation at both high and low volume fractions, in the presence of
short-range attractive interactions. We discuss the ability of mode-coupling
theory and its adaptations to address situations with strong heterogeneity in
density and/or dynamics. We include a discussion of the effect of attractions
on the shear-thinning and yield behaviour under flow.Comment: 17 pages, 6 figure
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