Phase Separation in Binary Fluid Mixtures with Continuously Ramped Temperature

We consider the demixing of a binary fluid mixture, under gravity, which is steadily driven into a two phase region by slowly ramping the temperature. We assume, as a first approximation, that the system remains spatially isothermal, and examine the interplay of two competing nonlinearities. One of these arises because the supersaturation is greatest far from the meniscus, creating inversion of the density which can lead to fluid motion; although isothermal, this is somewhat like the Benard problem (a single-phase fluid heated from below). The other is the intrinsic diffusive instability which results either in nucleation or in spinodal decomposition at large supersaturations. Experimental results on a simple binary mixture show interesting oscillations in heat capacity and optical properties for a wide range of ramp parameters. We argue that these oscillations arise under conditions where both nonlinearities are important

A cluster mode-coupling approach to weak gelation in attractive colloids

Mode-coupling theory (MCT) predicts arrest of colloids in terms of their volume fraction, and the range and depth of the interparticle attraction. We discuss how effective values of these parameters evolve under cluster aggregation. We argue that weak gelation in colloids can be idealized as a two-stage ergodicity breaking: first at short scales (approximated by the bare MCT) and then at larger scales (governed by MCT applied to clusters). The competition between arrest and phase separation is considered in relation to recent experiments. We predict a long-lived `semi-ergodic' phase of mobile clusters, showing logarithmic relaxation close to the gel line.Comment: 4 pages, 3 figure

Coexistence and Phase Separation in Sheared Complex Fluids

We demonstrate how to construct dynamic phase diagrams for complex fluids that undergo transitions under flow, in which the conserved composition variable and the broken-symmetry order parameter (nematic, smectic, crystalline, etc.) are coupled to shear rate. Our construction relies on a selection criterion, the existence of a steady interface connecting two stable homogeneous states. We use the (generalized) Doi model of lyotropic nematic liquid crystals as a model system, but the method can be easily applied to other systems, provided non-local effects are included.Comment: 4 pages REVTEX, 5 figures using epsf macros. To appear in Physical Review E (Rapid Communications

Are polymer melts "ideal"?

It is commonly accepted that in concentrated solutions or melts high-molecular weight polymers display random-walk conformational properties without long-range correlations between subsequent bonds. This absence of memory means, for instance, that the bond-bond correlation function, $P(s)$, of two bonds separated by $s$ monomers along the chain should exponentially decay with $s$. Presenting numerical results and theoretical arguments for both monodisperse chains and self-assembled (essentially Flory size-distributed) equilibrium polymers we demonstrate that some long-range correlations remain due to self-interactions of the chains caused by the chain connectivity and the incompressibility of the melt. Suggesting a profound analogy with the well-known long-range velocity correlations in liquids we find, for instance, $P(s)$ to decay algebraically as $s^{-3/2}$. Our study suggests a precise method for obtaining the statistical segment length \bstar in a computer experiment.Comment: 4 pages, 3 figure

Zero-range processes with saturated condensation: the steady state and dynamics

We study a class of zero-range processes in which the real-space condensation phenomenon does not occur and is replaced by a saturated condensation: that is, an extensive number of finite-size "condensates" in the steady state. We determine the conditions under which this occurs, and investigate the dynamics of relaxation to the steady state. We identify two stages: a rapid initial growth of condensates followed by a slow process of activated evaporation and condensation. We analyze these nonequilibrium dynamics with a combination of meanfield approximations, first-passage time calculations and a fluctuation-dissipation type approach.Comment: 21 pages, 12 figure

Dynamics of a polymer in a quenched random medium: A Monte Carlo investigation

We use an off - lattice bead - spring model of a self - avoiding polymer chain immersed in a 3-dimensional quenched random medium to study chain dynamics by means of a Monte - Carlo (MC) simulation. The chain center of mass mean-squared displacement as a function of time reveals two crossovers which depend both on chain length $N$ and on the degree of Gaussian disorder $\Delta$. The first one from normal to anomalous diffusion regime is found at short time $\tau_1$ and observed to vanish rapidly as $\tau_1 \propto \Delta^{- 11}$ with growing disorder. The second crossover back to normal diffusion, $\tau_2$, scales as $\tau_2 \propto N^{2\nu + 1} f(N^{2-3\nu}\Delta)$ with $f$ being some scaling function. The diffusion coefficient $D_N$ depends strongly on disorder and drops dramatically at a {\em critical dispersion} $\Delta_{c} \propto N^{-2 + 3\nu}$ of the disorder potential so that for $\Delta > \Delta_c$ the chain center of mass is practically frozen.The time-dependent Rouse modes correlation function $C_{p}(t)$ reveals a characteristic plateau at $\Delta > \Delta_c$ which is the hallmark of a non - ergodic regime. These findings agree well with our recent theoretical predictions.Comment: 7 pages, 6 figures, submitted to Europhys. Letter

Two-Dimensional Copolymers and Exact Conformal Multifractality

We consider in two dimensions the most general star-shaped copolymer, mixing random (RW) or self-avoiding walks (SAW) with specific interactions thereof. Its exact bulk or boundary conformal scaling dimensions in the plane are all derived from an algebraic structure existing on a random lattice (2D quantum gravity). The multifractal dimensions of the harmonic measure of a 2D RW or SAW are conformal dimensions of certain star copolymers, here calculated exactly as non rational algebraic numbers. The associated multifractal function f(alpha) are found to be identical for a random walk or a SAW in 2D. These are the first examples of exact conformal multifractality in two dimensions.Comment: 4 pages, 2 figures, revtex, to appear in Phys. Rev. Lett., January 199

Multifractal Dimensions for Branched Growth

A recently proposed theory for diffusion-limited aggregation (DLA), which models this system as a random branched growth process, is reviewed. Like DLA, this process is stochastic, and ensemble averaging is needed in order to define multifractal dimensions. In an earlier work [T. C. Halsey and M. Leibig, Phys. Rev. A46, 7793 (1992)], annealed average dimensions were computed for this model. In this paper, we compute the quenched average dimensions, which are expected to apply to typical members of the ensemble. We develop a perturbative expansion for the average of the logarithm of the multifractal partition function; the leading and sub-leading divergent terms in this expansion are then resummed to all orders. The result is that in the limit where the number of particles n -> \infty, the quenched and annealed dimensions are {\it identical}; however, the attainment of this limit requires enormous values of n. At smaller, more realistic values of n, the apparent quenched dimensions differ from the annealed dimensions. We interpret these results to mean that while multifractality as an ensemble property of random branched growth (and hence of DLA) is quite robust, it subtly fails for typical members of the ensemble.Comment: 82 pages, 24 included figures in 16 files, 1 included tabl

Theory and simulation of gelation, arrest and yielding in attracting colloids

We present some recent theory and simulation results addressing the phenomena of colloidal gelation at both high and low volume fractions, in the presence of short-range attractive interactions. We discuss the ability of mode-coupling theory and its adaptations to address situations with strong heterogeneity in density and/or dynamics. We include a discussion of the effect of attractions on the shear-thinning and yield behaviour under flow.Comment: 17 pages, 6 figure