Unusual Entropy of Adsorbed Methane on Zeolite-Templated Carbon

Methane adsorption at high pressures and across a wide range of temperatures was investigated on the surface of three porous carbon adsorbents with complementary structural properties. The measured adsorption equilibria were analyzed using a method that can accurately account for nonideal fluid properties and distinguish between absolute and excess quantities of adsorption, and that also allows the direct calculation of the thermodynamic potentials relevant to adsorption. On zeolite-templated carbon (ZTC), a material that exhibits extremely high surface area with optimal pore size and homogeneous structure, methane adsorption occurs with unusual thermodynamic properties that are greatly beneficial for deliverable gas storage: an enthalpy of adsorption that increases with site occupancy, and an unusually low entropy of the adsorbed phase. The origin of these properties is elucidated by comparison of the experimental results with a statistical mechanical model. The results indicate that temperature-dependent clustering (i.e., reduced configurations) of the adsorbed phase due to enhanced lateral interactions can account for the peculiarities of methane adsorbed on ZTC

Hydrogen charging in nickel and iron and its effect on their magnetic properties

The current study was undertaken to explore the possibility of detecting hydrogen cavitation in magnetic materials through magnetic propertymeasurements. It is known that dissolved hydrogen in a material causes microvoids. These voids may affect the structure‐sensitive magnetic properties such as coercivity and remanence. In this study, hydrogen was introduced into nickel and iron by two processes, namely thermal charging and cathodic charging. The effect on the magnetic properties was measured. In addition, the variation of the magnetic properties with porosity was studied

Paramagnetic structure for the soliton of the 30∘30^\circ partial dislocation in silicon

Based on ab initio calculation, we propose a new structure for the fundamental excitation of the reconstructed 30$^\circ$ partial dislocation in silicon. This soliton has a rare structure involving a five-fold coordinated atom near the dislocation core. The unique electronic structure of this defect is consistent with the electron spin resonance signature of the hitherto enigmatic thermally stable R center of plastically deformed silicon. This identification suggests the possibility of an experimental determination of the density of solitons, a key defect in understanding the plastic flow of the material.Comment: 5 pages, 4 figure