Kraus representation in the presence of initial correlations

We examine the validity of the Kraus representation in the presence of initial correlations and show that it is assured only when a joint dynamics is locally unitary.Comment: REVTeX4, 12 page

Geometrical Models of the Phase Space Structures Governing Reaction Dynamics

Hamiltonian dynamical systems possessing equilibria of ${saddle} \times {centre} \times...\times {centre}$ stability type display \emph{reaction-type dynamics} for energies close to the energy of such equilibria; entrance and exit from certain regions of the phase space is only possible via narrow \emph{bottlenecks} created by the influence of the equilibrium points. In this paper we provide a thorough pedagogical description of the phase space structures that are responsible for controlling transport in these problems. Of central importance is the existence of a \emph{Normally Hyperbolic Invariant Manifold (NHIM)}, whose \emph{stable and unstable manifolds} have sufficient dimensionality to act as separatrices, partitioning energy surfaces into regions of qualitatively distinct behavior. This NHIM forms the natural (dynamical) equator of a (spherical) \emph{dividing surface} which locally divides an energy surface into two components (`reactants' and `products'), one on either side of the bottleneck. This dividing surface has all the desired properties sought for in \emph{transition state theory} where reaction rates are computed from the flux through a dividing surface. In fact, the dividing surface that we construct is crossed exactly once by reactive trajectories, and not crossed by nonreactive trajectories, and related to these properties, minimizes the flux upon variation of the dividing surface. We discuss three presentations of the energy surface and the phase space structures contained in it for 2-degree-of-freedom (DoF) systems in the threedimensional space $\R^3$, and two schematic models which capture many of the essential features of the dynamics for $n$-DoF systems. In addition, we elucidate the structure of the NHIM.Comment: 44 pages, 38 figures, PDFLaTe

Effective rate equations for the over-damped motion in fluctuating potentials

We discuss physical and mathematical aspects of the over-damped motion of a Brownian particle in fluctuating potentials. It is shown that such a system can be described quantitatively by fluctuating rates if the potential fluctuations are slow compared to relaxation within the minima of the potential, and if the position of the minima does not fluctuate. Effective rates can be calculated; they describe the long-time dynamics of the system. Furthermore, we show the existence of a stationary solution of the Fokker-Planck equation that describes the motion within the fluctuating potential under some general conditions. We also show that a stationary solution of the rate equations with fluctuating rates exists.Comment: 18 pages, 2 figures, standard LaTeX2

Quantum Process Tomography of the Quantum Fourier Transform

The results of quantum process tomography on a three-qubit nuclear magnetic resonance quantum information processor are presented, and shown to be consistent with a detailed model of the system-plus-apparatus used for the experiments. The quantum operation studied was the quantum Fourier transform, which is important in several quantum algorithms and poses a rigorous test for the precision of our recently-developed strongly modulating control fields. The results were analyzed in an attempt to decompose the implementation errors into coherent (overall systematic), incoherent (microscopically deterministic), and decoherent (microscopically random) components. This analysis yielded a superoperator consisting of a unitary part that was strongly correlated with the theoretically expected unitary superoperator of the quantum Fourier transform, an overall attenuation consistent with decoherence, and a residual portion that was not completely positive - although complete positivity is required for any quantum operation. By comparison with the results of computer simulations, the lack of complete positivity was shown to be largely a consequence of the incoherent errors during the quantum process tomography procedure. These simulations further showed that coherent, incoherent, and decoherent errors can often be identified by their distinctive effects on the spectrum of the overall superoperator. The gate fidelity of the experimentally determined superoperator was 0.64, while the correlation coefficient between experimentally determined superoperator and the simulated superoperator was 0.79; most of the discrepancies with the simulations could be explained by the cummulative effect of small errors in the single qubit gates.Comment: 26 pages, 17 figures, four tables; in press, Journal of Chemical Physic

Strong friction limit in quantum mechanics: the Quantum Smoluchowski equation

For a quantum system coupled to a heat bath environment the strong friction limit is studied starting from the exact path integral formulation. Generalizing the classical Smoluchowski limit to low temperatures a time evolution equation for the position distribution is derived and the strong role of quantum fluctuations in this limit is revealed.Comment: 4 pages, PRL in pres

Test Particle in a Quantum Gas

A master equation with a Lindblad structure is derived, which describes the interaction of a test particle with a macroscopic system and is expressed in terms of the operator valued dynamic structure factor of the system. In the case of a free Fermi or Bose gas the result is evaluated in the Brownian limit, thus obtaining a single generator master equation for the description of quantum Brownian motion in which the correction due to quantum statistics is explicitly calculated. The friction coefficients for Boltzmann and Bose or Fermi statistics are compared.Comment: 9 pages, revtex, no figure

Decoherence Free Subspaces for Quantum Computation

Decoherence in quantum computers is formulated within the Semigroup approach. The error generators are identified with the generators of a Lie algebra. This allows for a comprehensive description which includes as a special case the frequently assumed spin-boson model. A generic condition is presented for error-less quantum computation: decoherence-free subspaces are spanned by those states which are annihilated by all the generators. It is shown that these subspaces are stable to perturbations and moreover, that universal quantum computation is possible within them.Comment: 4 pages, no figures. Conditions for decoherence-free subspaces made more explicit, updated references. To appear in PR

Completely Positive Quantum Dissipation

A completely positive master equation describing quantum dissipation for a Brownian particle is derived starting from microphysical collisions, exploiting a recently introduced approach to subdynamics of a macrosystem. The obtained equation can be cast into Lindblad form with a single generator for each Cartesian direction. Temperature dependent friction and diffusion coefficients for both position and momentum are expressed in terms of the collision cross-section.Comment: 8 pages, revtex, no figure

Quantum Brownian Motion With Large Friction

Quantum Brownian motion in the strong friction limit is studied based on the exact path integral formulation of dissipative systems. In this limit the time-nonlocal reduced dynamics can be cast into an effective equation of motion, the quantum Smoluchowski equation. For strongly condensed phase environments it plays a similar role as master equations in the weak coupling range. Applications for chemical, mesoscopic, and soft matter systems are discussed and reveal the substantial role of quantum fluctuations.Comment: 11 pages, 6 figures, to appear in: Chaos: "100 years of Brownian motion

Qubit Decoherence and Non-Markovian Dynamics at Low Temperatures via an Effective Spin-Boson Model

Quantum Brownian oscillator model (QBM), in the Fock-space representation, can be viewed as a multi-level spin-boson model. At sufficiently low temperature, the oscillator degrees of freedom are dynamically reduced to the lowest two levels and the system behaves effectively as a two-level (E2L) spin-boson model (SBM) in this limit. We discuss the physical mechanism of level reduction and analyze the behavior of E2L-SBM from the QBM solutions. The availability of close solutions for the QBM enables us to study the non-Markovian features of decoherence and leakage in a SBM in the non-perturbative regime (e.g. without invoking the Born approximation) in better details than before. Our result captures very well the characteristic non-Markovian short time low temperature behavior common in many models.Comment: 19 pages, 8 figure