The development and technical realization of the method of laser sounding of the atmosphere based on the effects of mixing of reference and external fields of scattering inside a laser cavity are presented. An approximate theory of the method was developed on the basis of the investigations using the model of a three-mirror laser. The nonlinear effect of a wideband laser on frequency-dependent external influences of the atmosphere was investigated. The field measurements of gaseous composition of the atmosphere were performed on the basis of a given method of coherent reception using a tunable CO2 laser