274 research outputs found
Quantum-chemical calculation of the adsorption energy of the Pb atom on the graphene
© 2018 Author(s). Graphene can be used as sensors to detect toxic heavy metals in peripheral blood. This requires a clear understanding of adsorption process on the graphene surface. The DFT-functional method is used to calculate adsorption energy. In the article we present the calculation results and analyse interaction of Pb atom with graphene surface. It is shown that the Pb atom in B-site position on a graphene plane has a minimum of energy
Gallium(III) Citrato Complexes in Solution
The complexing gallium(III) with citric acid at pH from 2 to 10 and the gallium(III) and citric acid concentrations from 0.005 to 0.025 mol/l is studied by using pH titration. The stability constants of 1 : 1 complexes of various degrees of protonation formed in the system are found by mathematical modeling
Autoresonance in a Dissipative System
We study the autoresonant solution of Duffing's equation in the presence of
dissipation. This solution is proved to be an attracting set. We evaluate the
maximal amplitude of the autoresonant solution and the time of transition from
autoresonant growth of the amplitude to the mode of fast oscillations.
Analytical results are illustrated by numerical simulations.Comment: 22 pages, 3 figure
DBR and DFB lasers in neodymium-and ytterbium-doped photothermorefractive glasses
The first demonstration, to the best of our knowledge, of distributed Bragg reflector (DBR) and monolithic distributed feedback (DFB) lasers in photothermorefractive glass doped with rare-earth ions is reported. The lasers were produced by incorporation of the volume Bragg gratings into the laser gain elements. The need for environment-insensitive, compact, robust, narrow line laser sources has stimulated the development of hybrid devices, such as distributed Bragg reflector (DBR) lasers, in which a laser resonator is produced by Bragg mirrors incorporated in a gain element, or distributed feedback (DFB) lasers, in which a resonator is produced by a Bragg grating that occupies the whole gain element. The concept of DFB was first successfully applied to optically pumped dye lasers The PTR glass has composition (M%) The two last elements are responsible for initiation of the photostructural transformations in the glass and enable VBG recording. As it was demonstrated in our earlier studies Nd-and Yb-doped PTR glasses with 2 wt. % of Yb and Nd ions have been prepared. The measurements of emission spectra were carried out in these glasses using an Ocean Optics spectrometer when glass samples were excited with a diode laser emitting at 808 nm (in the case of Nd ions) and 915 nm (for Yb ones
Composition, properties, and structure of palladium(II) chlorides in aqueous solution
The composition, stability, and structure of palladium(II) chloride complexes in hydrochloric acid media have been determined using nuclear-magnetic relaxation, magnetochemical methods, and Rayleigh light scattering. The predominant form in solution for palladium(II) concentrations greater than 0.005 moles/liter is the octahedral Pd6Cl12 or Pd6Cl14 2-, which has antiferromagnetic properties in contrast with the paramagnetic properties of the mononuclear aquachloride. The polarizability anisotropy of Pd-Cl bonds with terminal and bridging chlorine atoms has been determined. © 1991 Plenum Publishing Corporation
Performance and Mix Measurements of Indirect Drive Cu-Doped Be Implosions
The ablator couples energy between the driver and fusion fuel in inertial confinement fusion (ICF). Because of its low opacity, high solid density, and material properties, beryllium has long been considered an ideal ablator for ICF ignition experiments at the National Ignition Facility. We report here the first indirect drive Be implosions driven with shaped laser pulses and diagnosed with fusion yield at the OMEGA laser. The results show good performance with an average DD neutron yield of ~2 × 10[superscript 9] at a convergence ratio of R[subscript 0]/R ~ 10 and little impact due to the growth of hydrodynamic instabilities and mix. In addition, the effect of adding an inner liner of W between the Be and DD is demonstrated.United States. Dept. of Energy (Lawrence Livermore National Laboratory Contract DE-AC52-07NA27344
The intact Kunitz domain protects the amyloid precursor protein from being processed by matriptase-2
Quality of colonoscopy in an emerging country: A prospective, multicentre study in Russia
Background: The quality of colonoscopy has been related to a higher risk of interval cancer, and this issue has been addressed extensively in developed countries. The aim of our study was to explore the main quality indicators of colonoscopy in a large emerging country. Methods: Consecutive patients referred for colonoscopy in 14 centres were prospectively included between July and October 2014. Before colonoscopy, several clinical and demographic variables were collected. Main quality indicators (i.e. caecal intubation rate, (advanced) adenoma detection rate, rate of adequate cleansing and sedation) were collected. Data were analysed at per patient and per centre level (only for those with at least 100 cases). Factors associated with caecal intubation rate and adenoma detection rate were explored at multivariate analysis. Results: A total of 8829 (males: 35%; mean age: 57 + 14 years) patients were included, with 11 centres enrolling at least 100 patients. Screening (including non-alarm symptoms) accounted for 59% (5188/8829) of the indications. Sedation and split preparation were used in 26% (2294/8829) and 25% (2187/8829) of the patients. Caecal intubation was achieved in 7616 patients (86%), and it was ≥85% in 8/11 (73%) centres. Adenoma detection rate was 18% (1550/8829), and it was higher than 20% in five (45%) centres, whilst it was lower than 10% in four (33%) centres. At multivariate analysis, age (OR: 1.020, 95% CI: 1.015–1.024), male sex (OR: 1.2, 95% CI: 1.1–1.3), alarm symptoms (OR: 1.8, 95% CI: 1.7–2), split preparation (OR: 1.4, 95% CI: 1.2–1.6), caecal intubation rate (OR: 1.6, 95% CI: 1.3–1.9) and withdrawal time measurement (OR: 1.2, 95% CI: 1.6–2.1) were predictors of a higher adenoma detection rate, while adequate preparation (OR: 3.4: 95% CI: 2.9–3.9) and sedation (OR: 1.3; 95% CI: 1.1–1.6) were the strongest predictors of caecal intubation rate. Conclusions: According to our study, there is a substantial intercentre variability in the main quality indicators. Overall, the caecal intubation rate appears to be acceptable in most centres, whilst the overall level of adenoma detection appears low, with less than half of the centres being higher than 20%. Educational and quality assurance programs, including higher rates of sedation and split regimen of preparation, may be necessary to increase the key quality indicators
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