High-pressure/high-temperature synthesis of transition metal oxide perovskites

Perovskite and related Ruddlesden-Popper type transition metal oxides synthesised at high pressures and temperatures during the last decade are reviewed. More than 60 such new materials have been reported since 1995. Important developments have included perovskites with complex cation orderings on A and B sites, multiferroic bismuth-based perovskites, and new manganites showing colossal magnetoresistance (CMR) and charge ordering properties

Mutual selection in time-varying networks

Copyright @ 2013 American Physical SocietyTime-varying networks play an important role in the investigation of the stochastic processes that occur on complex networks. The ability to formulate the development of the network topology on the same time scale as the evolution of the random process is important for a variety of applications, including the spreading of diseases. Past contributions have investigated random processes on time-varying networks with a purely random attachment mechanism. The possibility of extending these findings towards a time-varying network that is driven by mutual attractiveness is explored in this paper. Mutual attractiveness models are characterized by a linking function that describes the probability of the existence of an edge, which depends mutually on the attractiveness of the nodes on both ends of that edge. This class of attachment mechanisms has been considered before in the fitness-based complex networks literature but not on time-varying networks. Also, the impact of mutual selection is investigated alongside opinion formation and epidemic outbreaks. We find closed-form solutions for the quantities of interest using a factorizable linking function. The voter model exhibits an unanticipated behavior as the network never reaches consensus in the case of mutual selection but stays forever in its initial macroscopic configuration, which is a further piece of evidence that time-varying networks differ markedly from their static counterpart with respect to random processes that take place on them. We also find that epidemic outbreaks are accelerated by uncorrelated mutual selection compared to previously considered random attachment

A three stage model for adsorption of nonionic surfactants

Copyright @ 1993 American Institute of Physics.A three stage model for the adsorption of nonionic surfactants is proposed which makes use of existing theory from studies of random sequential adsorption. The model is simulated and the adsorption curves are found. The theory of random sequential adsorption is used to calculate the coverage exactly at the end of each of the three stages

Local molecular field theory for the treatment of electrostatics

We examine in detail the theoretical underpinnings of previous successful applications of local molecular field (LMF) theory to charged systems. LMF theory generally accounts for the averaged effects of long-ranged components of the intermolecular interactions by using an effective or restructured external field. The derivation starts from the exact Yvon-Born-Green hierarchy and shows that the approximation can be very accurate when the interactions averaged over are slowly varying at characteristic nearest-neighbor distances. Application of LMF theory to Coulomb interactions alone allows for great simplifications of the governing equations. LMF theory then reduces to a single equation for a restructured electrostatic potential that satisfies Poisson's equation defined with a smoothed charge density. Because of this charge smoothing by a Gaussian of width sigma, this equation may be solved more simply than the detailed simulation geometry might suggest. Proper choice of the smoothing length sigma plays a major role in ensuring the accuracy of this approximation. We examine the results of a basic confinement of water between corrugated wall and justify the simple LMF equation used in a previous publication. We further generalize these results to confinements that include fixed charges in order to demonstrate the broader impact of charge smoothing by sigma. The slowly-varying part of the restructured electrostatic potential will be more symmetric than the local details of confinements.Comment: To be published in J Phys-Cond Matt; small misprint corrected in Eq. (12) in V

Luscher Term for k-string Potential from Holographic One Loop Corrections

We perform a systematic analysis of k-strings in the framework of the gauge/gravity correspondence. We discuss the Klebanov-Strassler supergravity background which is known to be dual to a confining supersymmetric gauge theory with chiral symmetry breaking. We obtain the k-string tension in agreement with expectations of field theory. Our main new result is the study of one-loop corrections on the string theoretic side. We explicitly find the frequency spectrum for both the bosons and the fermions for quadratic fluctuations about the classical supergravity solution. Further we use the massless modes to compute 1/L contributions to the one loop corrections to the k-string energy. This corresponds to the Luscher term contribution to the k-string potential on the gauge theoretic side of the correspondence.Comment: 39 pages, 3 figures. New Calculation showing explicit k -> M - k symmetry of Energy utilizing the new figure. Discussion of non-k-dependence of Luscher term at end of last section right before Conclusion. Same version to be published in JHE

Numerical Simulation of Baroclinic Jovian Vortices

We examine the evolution of baroclinic vortices in a time-dependent, nonlinear numerical model of a Jovian atmosphere. The model uses a normal-mode expansion in the vertical, using the barotropic and first two baroclinic modes. Results for the stability of baroclinic vortices on an f plane in the absence of a mean zonal flow are similar to results of Earth vortex models, although the presence of a fluid interior on the Jovian planets shifts the stability boundaries to smaller length scales. The presence of a barotropic mean zonal flow in the interior stabilizes vortices against instability and significantly modifies the finite amplitude form of baroclinic instabilities. The effect of a zonal flow on a form of barotropic instability produces periodic oscillations in the latitude and longitude of the vortex as observed at the level of the cloud tops. This instability may explain some, but not all, observations of longitudinal oscillations of vortices on the outer planets. Oscillations in aspect ratio and orientation of stable vortices in a zonal shear flow are observed in this baroclinic model, as in simpler twodimensional models. Such oscillations are also observed in the atmospheres of Jupiter and Neptune. The meridional propagation and decay of vortices on a β plane is inhibited by the presence of a mean zonal flow. The direction of propagation of a vortex relative to the mean zonal flow depends upon the sign of the meridional potential vorticity gradient; combined with observations of vortex drift rates, this may provide a constraint on model assumption for the flow in the deep interior of the Jovian planets

Network growth model with intrinsic vertex fitness

© 2013 American Physical SocietyWe study a class of network growth models with attachment rules governed by intrinsic node fitness. Both the individual node degree distribution and the degree correlation properties of the network are obtained as functions of the network growth rules. We also find analytical solutions to the inverse, design, problems of matching the growth rules to the required (e.g., power-law) node degree distribution and more generally to the required degree correlation function. We find that the design problems do not always have solutions. Among the specific conditions on the existence of solutions to the design problems is the requirement that the node degree distribution has to be broader than a certain threshold and the fact that factorizability of the correlation functions requires singular distributions of the node fitnesses. More generally, the restrictions on the input distributions and correlations that ensure solvability of the design problems are expressed in terms of the analytical properties of their generating functions