Electron Confinement, Orbital Ordering, and Orbital Moments in d0d^0-d1d^1 Oxide Heterostructures

The (SrTiO$_3$)$_m$/(SrVO$_3$)$_n$ $d^0-d^1$ multilayer system is studied with first principles methods through the observed insulator-to-metal transition with increasing thickness of the SrVO$_3$ layer. When correlation effects with reasonable magnitude are included, crystal field splittings from the structural relaxations together with spin-orbit coupling (SOC) determines the behavior of the electronic and magnetic structures. These confined slabs of SrVO$_3$ prefer $Q_{orb}$=($\pi,\pi$) orbital ordering of $\ell_z = 0$ and $\ell_z = -1$ ($j_z=-1/2$) orbitals within the plane, accompanied by $Q_{spin}$=(0,0) spin order (ferromagnetic alignment). The result is a SOC-driven ferromagnetic Mott insulator. The orbital moment of 0.75 $\mu_B$ strongly compensates the spin moment on the $\ell_z = -1$ sublattice. The insulator-metal transition for $n = 1 \to 5$ (occurring between $n$=4 and $n$=5) is reproduced. Unlike in the isoelectronic $d^0-d^1$ TiO$_2$/VO$_2$ (rutile structure) system and in spite of some similarities in orbital ordering, no semi-Dirac point [{\it Phys. Rev. Lett.} {\bf 102}, 166803 (2009)] is encountered, but the insulator-to-metal transition occurs through a different type of unusual phase. For n=5 this system is very near (or at) a unique semimetallic state in which the Fermi energy is topologically determined and the Fermi surface consists of identical electron and hole Fermi circles centered at $k$=0. The dispersion consists of what can be regarded as a continuum of radially-directed Dirac points, forming a "Dirac circle".Comment: 9 pages, 8 figure

The NASA integrated test facility and its impact on flight research

The Integrated Test Facility (ITF), being built at NASA Ames-Dryden Flight Research Facility, will provide new test capabilities for emerging research aircraft. An overview of the ITF and the challenges being addressed by this unique facility are outlined. The current ITF capabilities, being developed with the X-29 Forward Swept Wing Program, are discussed along with future ITF activities

Pest-predator spatial relationships in winter rape: implications for integrated crop management

Douglas Warner, Les J Allen-Williams, Andrew W Ferguson, and Ingrid H Williams, 'Pest–predator spatial relationships in winter rape: implications for integrated crop management', Pest Management Science, Vol. 56 (11): 977-982, November 2000, doi: 10.1002/1526-4998(200011)56:113.0.CO;2-U. Copyright © 2000 Society of Chemical IndustryThe brassica pod midge (Dasineura brassicae) is an important and widespread pest of winter and spring oilseed rape throughout Europe. Pods infested by D brassicae larvae split prematurely, releasing seeds, and the larvae drop to the soil into which they burrow to pupate. At this stage in its lifecycle D brassicae is potentially vulnerable to predation by carabid beetles foraging on the soil surface. This is the first study in the UK to focus on carabid beetles as predators of D brassicae in the oilseed rape crop. The spatio-temporal distributions of larvae of D brassicae dropping to the soil from the crop canopy and of adult carabid beetles active on the soil surface were analysed in two consecutive years. Insect samples were collected from spatially referenced sampling points across each crop. Counts of insects were mapped and analysed, and the degree of spatial association between predator and prey determined using Spatial Analysis by Distance Indices (SADIE). Carabid species abundant and active during peak drop of first generation D brassicae larvae included Agonum dorsale, Amara similata, Harpalus rufipes and Nebria brevicollis. The larvae of D brassicae had a marked edge distribution within the crop. SADIE analysis revealed significant spatial association between larvae of D brassicae and adult H rufipes (P <0.05) in 1998, but not with adults of A dorsale, A similata or N brevicollis. In 1999, there was strong spatial association only between larvae of D brassicae and adult A dorsale (P <0.01). Aggregation of N brevicollis adults occurred in some areas of greatest D brassicae larval counts in 1999, but overall spatial association was not signi®cant. The distributions are discussed in terms of their relevance to integrated crop management (ICM) strategies and spatial targeting of insecticides.Peer reviewe

A High Power Frequency-Stabilized Tunable Two-Frequency Diode Laser System for the Generation of Coherent THz-Waves by Photomixing

A tunable two-frequency high-power diode laser system at 850 nm for terahertz (Thz)-wave generation by photomixing in low-temperature-grown GaAs photo-conductors has been developed. The difference frequency is obtained through a three laser system, where two lasers are locked to different orders of a Fabry-Perot cavity and a third is offset-locked to the first, The difference-frequency signal is generated by the offset laser and the other cavity-locked laser. The spectral purity of the beat note is better than 1 MHz. The maximum output power of -500 mW was obtained by using the master oscillator power amplifier (MOPA) technique, simultaneous injection of two seed frequencies with a single semiconductor optical amplifier. Here we report the generation of THz waves and spectroscopy of acetonitrile as proof of concept

Submillimeter-Wave Measurements and Analysis of the Ground and ν2 = 1 States of Water

In order to facilitate further studies of water in the interstellar medium, the envelopes of late-type stars, jets, and shocked regions, the frequencies of 17 newly measured H_2 ^(16)O transitions between 0.841 and 1.575 THz are reported. A complete update of the available water line frequencies and a detailed calculation of unmeasured rotational transitions and transition intensities as a function of temperature are presented for the ground and ν_2 = 1 state levels below 3000 cm^(-1) of excitation energy. The new terahertz transitions were measured with a recently developed laser difference frequency spectrometer. Six of these transitions arise from the ν_2 = 1 state, and the other 11 are in the ground state; all have lower state energies from 700 to 1750 cm^(-1) and should be accessible to Stratospheric Observatory For Infrared Astronomy (SOFIA) through the atmosphere. The transitions near 0.850 THz are accessible from the ground with existing receivers. Observations of the newly measured ν_2 = 1 state transitions, which include the 1_(1, 1)-0_(0, 0) fundamental at 1.2057 THz and five other very low J transitions, should provide valuable insights into role played by the ν2 = 1 state in the cooling dynamics of jets, shocks, masers, and strongly infrared-pumped regions. The line list is presented to assist in the planning of observational campaigns with the Far-Infrared Space Telescope (FIRST) and other proposed space missions with which a full suite of water observations can be carried out

Linear bands, zero-momentum Weyl semimetal, and topological transition in skutterudite-structure pnictides

It was reported earlier [Phys. Rev. Lett. 106, 056401 (2011)] that the skutterudite structure compound CoSb$_3$ displays a unique band structure with a topological transition versus a symmetry-preserving sublattice (Sb) displacement very near the structural ground state. The transition is through a massless Dirac-Weyl semimetal, point Fermi surface phase which is unique in that (1) it appears in a three dimensional crystal, (2) the band critical point occurs at $k$=0, and (3) linear bands are degenerate with conventional (massive) bands at the critical point (before inclusion of spin-orbit coupling). Further interest arises because the critical point separates a conventional (trivial) phase from a topological phase. In the native cubic structure this is a zero-gap topological semimetal; we show how spin-orbit coupling and uniaxial strain converts the system to a topological insulator (TI). We also analyze the origin of the linear band in this class of materials, which is the characteristic that makes them potentially useful in thermoelectric applications or possibly as transparent conductors. We characterize the formal charge as Co$^{+}$ $d^8$, consistent with the gap, with its $\bar{3}$ site symmetry, and with its lack of moment. The Sb states are characterized as $p_x$ (separately, $p_y$) $\sigma$-bonded $Sb_4$ ring states occupied and the corresponding antibonding states empty. The remaining (locally) $p_z$ orbitals form molecular orbitals with definite parity centered on the empty $2a$ site in the skutterudite structure. Eight such orbitals must be occupied; the one giving the linear band is an odd orbital singlet $A_{2u}$ at the zone center. We observe that the provocative linearity of the band within the gap is a consequence of the aforementioned near-degeneracy, which is also responsible for the small band gap.Comment: 10 pages, 7 figure

Increasing phosphorus supply is not the mechanism by which arbuscular mycorrhiza increase attractiveness of bean (Vicia faba) to aphids

Peer reviewedPublisher PD