The largest oxigen bearing organic molecule repository

We present the first detection of complex aldehydes and isomers in three typical molecular clouds located within 200pc of the center of our Galaxy. We find very large abundances of these complex organic molecules (COMs) in the central molecular zone (CMZ), which we attribute to the ejection of COMs from grain mantles by shocks. The relative abundances of the different COMs with respect to that of CH3OH are strikingly similar for the three sources, located in very different environments in the CMZ. The similar relative abundances point toward a unique grain mantle composition in the CMZ. Studying the Galactic center clouds and objects in the Galactic disk having large abundances of COMs, we find that more saturated molecules are more abundant than the non-saturated ones. We also find differences between the relative abundance between COMs in the CMZ and the Galactic disk, suggesting different chemical histories of the grain mantles between the two regions in the Galaxy for the complex aldehydes. Different possibilities for the grain chemistry on the icy mantles in the GC clouds are briefly discussed. Cosmic rays can play an important role in the grain chemistry. With these new detections, the molecular clouds in the Galactic center appear to be one of the best laboratories for studying the formation of COMs in the Galaxy.Comment: 20 pages, 4 figures, accepted in Ap

The Matrix Product Approach to Quantum Spin Ladders

We present a manifestly rotational invariant formulation of the matrix product method valid for spin chains and ladders. We apply it to 2 legged spin ladders with spins 1/2, 1 and 3/2 and different magnetic structures labelled by the exchange coupling constants, which can be ferromagnetic or antiferromagnetic along the legs and the rungs of the ladder We compute ground state energy densities, correlation lengths and string order parameters. We present numerical evidence of the duality properties of the 3 different non ferromagnetic spin 1/2 ladders. We show that the long range topological order characteristic of isolated spin 1 chains is broken by the interchain coupling. The string order correlation function decays exponentially with a finite correlation length that we compute. A physical picture of the spin 1 ladder is given in terms of a collection of resonating spin 1 chains. Finally for ladders with spin equal or greater than 3/2 we define a class of AKLT states whose matrix product coefficients are given by 9-j symbols.Comment: REVTEX file, 16 pages, 12 figures, 6 Table