98 research outputs found
A Transition State Analogue for the Oxidation of Binuclear Palladium(II) to Binuclear Palladium(III) Complexes
Full text linkMultilayer‐Functionalized Reduced Graphene Oxide Decorated with Gold Nanoparticles as a Designed Nanonanocatalyst for the Selective Oxidation of Cyclohexene by Molecular Oxygen in a Solvent‐Free System
No full textNachweis und Bestimmung von Pyren- und, Benz(a)pyrenchinonen durch Fluorescenzspektrographie bei ? 197�C. Anwendung zur Analyse von Luftverunreinigungen
No full textA Novel Method for Preparation of Hydroxyalkyl Carboxylates by Potassium Permanganate Oxidation of Cyclic Acetals
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Transforming Olefins into γ
No full textWe have developed a strategy to transform olefins into homoallylic nitriles through a mechanism that combines copper catalysis with alkyl nitrile radicals. The radicals are easily generated from alkyl nitriles in the presence of the mild oxidant di-tert-butyl peroxide. This cross-dehydrogenative coupling between simple olefins and alkylnitriles bears advantages over the conventional use of halides and toxic cyanide reagents. With this method, we showcase the facile synthesis of a flavoring agent, a natural product, and a polymer precursor from simple olefins
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