16 research outputs found
The effect of Co(II) cations and their position in NaZr2(PO4)3 lattice on catalytic conversion of 2-propanol
Solid electrolytes with anionic and cationic conductivity as catalysts for isobutanol conversion
Solid electrolytes with anionic and cationic conductivity as catalysts for isobutanol conversion
Solid electrolytes with anionic and cationic conductivity as catalysts for isobutanol conversion
Plenary sessio
Activity of Bi4V2-2xCu2xO11–Δ in the transformation of isobutanol after plasma-chemical treatment
The catalytic properties of plasma-chemically and thermally treated Bi4V2-2xCu2xO11–δ with х= 0.00–0.16 (BICUVOX) in the transformation of isobutanol are studied. Plasma treatments lead to the total deactivation of the active sites of dehydration reaction, and the alcohol is converted with 100% selectivity into aldehyde. Activity of the dehydrogenation of alcohol after PCT increases in ~ 1.7 times on samples with xCu=0.04-0.06 (α.β phases) compared to the initial samples. Similar values which were found for the samples with xCu=0.0-0.06, including the double vanadate, suggests that PCT affects the ceramic matrix with Bi, O and V elements. Addition of small amounts of copper does not change this effect. © 2018, Technical University of Kosice. All rights reserved
Activity of Bi4V2-2xCu2xO11–Δ in the transformation of isobutanol after plasma-chemical treatment
The catalytic properties of plasma-chemically and thermally treated Bi4V2-2xCu2xO11–δ with х= 0.00–0.16 (BICUVOX) in the transformation of isobutanol are studied. Plasma treatments lead to the total deactivation of the active sites of dehydration reaction, and the alcohol is converted with 100% selectivity into aldehyde. Activity of the dehydrogenation of alcohol after PCT increases in ~ 1.7 times on samples with xCu=0.04-0.06 (α.β phases) compared to the initial samples. Similar values which were found for the samples with xCu=0.0-0.06, including the double vanadate, suggests that PCT affects the ceramic matrix with Bi, O and V elements. Addition of small amounts of copper does not change this effect. © 2018, Technical University of Kosice. All rights reserved