9 research outputs found

    Nephrostomy tube misplacement in the inferior vena cava following percutaneous nephrostomy

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    Percutaneous renal interventions are characterized by bleeding and infectious complications, as well as trauma to organs located near the kidney, renal or inferior vena cava (IVC). The article presents a clinical observation of a rare complication of percutaneous nephrostomy (PCN), i.e. migration of the distal end of the nephrostomy tube into the IVC. Its timely removal followed by re-nephrostomy made it possible to avoid bleeding and restore drainage of the pyelocalyceal system. Along with this, the article presents a literature review on this condition in the eLibrary, Springer, MedLine, Embase, UpToDate databases from 2000 to 2021. The indications for PCN, the frequency and risk factors of IVC damage during percutaneous renal interventions, as well as treatment tactics were studied. After the initial evaluation of the literature, ten articles were selected for further analysis. The main risk factors associated with IVC perforation after PCN include the surgeon's lack of experience in instrumental imaging, misjudgment of the length of the nephrostomy tube, and its insertion depth, resulting in its inadequate placement. Removal of the nephrostomy tube from the IVC under radiological and ultrasound guidance or open surgery are the main methods to correct for this complication

    Π‘ΠΌΠ΅ΡˆΠ°Π½Π½Ρ‹Π΅ M-V-Sb-оксиды ΠΊΠ°ΠΊ ΠΊΠ°Ρ‚Π°Π»ΠΈΠ·Π°Ρ‚ΠΎΡ€Ρ‹ оксидСгидрогСнизаци

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    The properties of mixed M-V-Sb (M = Ni, Co, Bi, Sn) oxides, supported on aluminum oxide, have been physically characterized and their activities estimated .in dehydrogenation of light paraffins, ethyl benzene and ethanol. The most selective NiVSb catalyst was easily reduced which allowed for proposing of the reduction-oxidation mechanism .The result of kinetic researches has shown that, the concentration of oxygen in the gas phase is the key parameter responsible for dehydrogenation selectivity. To maintain the optimal process conditions, oxygen was distributed along the catalyst layers.Π‘ΠΌΠ΅ΡˆΠ°Π½Π½Ρ‹Π΅ M-V-Sb-оксиды ( M = Ni, Co, Bi, Sn), нанСсСнныС Π½Π° оксид алюминия, Π±Ρ‹Π»ΠΈ физичСски ΠΎΡ…Π°Ρ€Π°ΠΊΡ‚Π΅Ρ€ΠΈΠ·ΠΎΠ²Π°Π½Ρ‹ Π² свойствах ΠΈ ΠΎΡ†Π΅Π½Π΅Π½Ρ‹ ΠΏΠΎ активности Π² Ρ€Π΅Π°ΠΊΡ†ΠΈΠΈ дСгидрирования Π»Π΅Π³ΠΊΠΈΡ… ΠΏΠ°Ρ€Π°-Ρ„ΠΈΠ½ΠΎΠ², этилбСнзола ΠΈ этанола. НаиболСС сСлСктивный ΠΊΠ°Ρ‚Π°Π»ΠΈΠ·Π°Ρ‚ΠΎΡ€ Ni-V-Sb Π»Π΅Π³ΠΊΠΎ восстанавли-вался, Ρ‡Ρ‚ΠΎ ΠΏΠΎΠ·Π²ΠΎΠ»ΠΈΠ»ΠΎ Π²Ρ‹Π΄Π²ΠΈΠ½ΡƒΡ‚ΡŒ ΠΏΡ€Π΅Π΄ΠΏΠΎΠ»ΠΎΠΆΠ΅Π½ΠΈΠ΅ ΠΎΠ± ΠΎΠΊΠΈΡΠ»ΠΈΡ‚Π΅Π»ΡŒΠ½ΠΎ-Π²ΠΎΡΡΡ‚Π°Π½ΠΎΠ²ΠΈΡ‚Π΅Π»ΡŒΠ½ΠΎΠΌ ΠΌΠ΅Ρ…Π°Π½ΠΈΠ·ΠΌΠ΅ Ρ€Π΅Π°ΠΊΡ†ΠΈΠΈ. Π Π΅Π·ΡƒΠ»ΡŒΡ‚Π°Ρ‚Ρ‹ кинСтичСских исслСдований ΠΏΠΎΠΊΠ°Π·Π°Π»ΠΈ, Ρ‡Ρ‚ΠΎ концСнтрация кислорода Π³Π°Π·ΠΎΠ²ΠΎΠΉ Ρ„Π°Π·Ρ‹ являСтся ΠΊΠ»ΡŽΡ‡Π΅Π²Ρ‹ΠΌ ΠΏΠ°Ρ€Π°ΠΌΠ΅Ρ‚Ρ€ΠΎΠΌ, отвСтствСнным Π·Π° Π΄Π΅Π³ΠΈΠ΄Ρ€ΠΈΡ€ΡƒΡŽΡ‰ΡƒΡŽ ΡΠ΅Π»Π΅ΠΊΡ‚ΠΈΠ²Π½ΠΎΡΡ‚ΡŒ. Для ΠΏΠΎΠ΄-дСрТания ΡƒΠΊΠ°Π·Π°Π½Π½ΠΎΠ³ΠΎ ΠΎΠΏΡ‚ΠΈΠΌΡƒΠΌΠ° использовалась распрСдСлСнная ΠΏΠΎΠ΄Π°Ρ‡Π° кислорода ΠΏΠΎ слою ΠΊΠ°Ρ‚Π°Π»ΠΈΠ·Π°Ρ‚ΠΎΡ€Π°

    ΠžΠΊΠΈΡΠ»ΠΈΡ‚Π΅Π»ΡŒΠ½ΠΎΠ΅ Π΄Π΅Π³ΠΈΠ΄Ρ€ΠΈΡ€ΠΎΠ²Π°Π½ΠΈΠ΅ ΠΈΠ·ΠΎΠ±ΡƒΡ‚Π°Π½Π° Π² ΠΈΠ·ΠΎΠ±ΡƒΡ‚Π΅Π½ Π½Π° Ni-V-Sb-алюмооксидном ΠΊΠ°Ρ‚Π°Π»ΠΈΠ·Π°Ρ‚ΠΎΡ€Π΅.

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    Addition of nickel oxide in the V-Sb/Ξ³Al2O3 catalytic system, used in oxidative dehydrogenation of isobutane, significantly increases conversion (from 36 to 42-44%) at isobutene selectivity of 70 %. The developed catalysts consisting of systems V-Sb-O and V-Sb-Ni-O were characterized using XRD, XPS, and H2-TPR. Formation of the discovered nickel vanadate phase NiV2O6 is as a result of free phase VOx is a more effective catalyst due to increase in the quantity of mobile oxygen lattice. It is suggested that the set of various vanadium surface phases improves activity and selectivity of the new catalytic systems.Π’ΠΊΠ»ΡŽΡ‡Π΅Π½ΠΈΠ΅ Π΄ΠΎΠΏΠΎΠ»Π½ΠΈΡ‚Π΅Π»ΡŒΠ½ΠΎ оксида никСля Π² ΠΊΠ°Ρ‚Π°Π»ΠΈΡ‚ΠΈΡ‡Π΅ΡΠΊΡƒΡŽ систСму V-Sb/Ξ³Al2O3, ΠΈΡΠΏΠΎΠ»ΡŒΠ·ΡƒΠ΅ΠΌΡƒΡŽ Π² ΠΎΠΊΠΈΡΠ»ΠΈΡ‚Π΅Π»ΡŒΠ½ΠΎΠΌ Π΄Π΅Π³ΠΈΠ΄Ρ€ΠΈΡ€ΠΎΠ²Π°Π½ΠΈΠΈ ΠΈΠ·ΠΎΠ±ΡƒΡ‚Π°Π½Π°, Π·Π½Π°Ρ‡ΠΈΡ‚Π΅Π»ΡŒΠ½ΠΎ ΡƒΠ²Π΅Π»ΠΈΡ‡ΠΈΠ²Π°Π΅Ρ‚ ΠΊΠΎΠ½Π²Π΅Ρ€ΡΠΈΡŽ (ΠΎΡ‚ 36 Π΄ΠΎ 42-44%) ΠΏΡ€ΠΈ сСлСктивности ΠΏΠΎ ΠΈΠ·ΠΎΠ±ΡƒΡ‚Π΅Π½Ρƒ 70%. Π Π°Π·Ρ€Π°Π±ΠΎΡ‚Π°Π½Π½Ρ‹Π΅ ΠΊΠ°Ρ‚Π°Π»ΠΈΠ·Π°Ρ‚ΠΎΡ€Ρ‹, Π²ΠΊΠ»ΡŽΡ‡Π°ΡŽΡ‰ΠΈΠ΅ систСмы V-Sb-O ΠΈ V-Sb-Ni-O, Π±Ρ‹Π»ΠΈ ΠΎΡ…Π°Ρ€Π°ΠΊΡ‚Π΅Ρ€ΠΈΠ·ΠΎΠ²Π°Π½Ρ‹ ΠΌΠ΅Ρ‚ΠΎΠ΄Π°ΠΌΠΈ Π‘Π­Π’, XRD, XPS ΠΈ H2-TPR. Π€ΠΎΡ€ΠΌΠΈΡ€ΠΎΠ²Π°Π½ΠΈΠ΅ ΠΎΠ±Π½Π°Ρ€ΡƒΠΆΠ΅Π½Π½ΠΎΠΉ Ρ„Π°Π·Ρ‹ Π²Π°Π½Π°Π΄Π°Ρ‚Π° никСля NiV2O6 ΠΏΡ€ΠΈΠ²ΠΎΠ΄ΠΈΡ‚ Π·Π° счСт свободной Ρ„Π°Π·Ρ‹ VOx ΠΊ Π±ΠΎΠ»Π΅Π΅ эффСктивному ΠΊΠ°Ρ‚Π°Π»ΠΈΠ·Π°Ρ‚ΠΎΡ€Ρƒ вслСдствиС увСличСния количСства мобильного кислорода Ρ€Π΅ΡˆΠ΅Ρ‚ΠΊΠΈ. ΠŸΡ€Π΅Π΄ΠΏΠΎΠ»Π°Π³Π°Π΅Ρ‚ΡΡ, Ρ‡Ρ‚ΠΎ Π½Π°Π±ΠΎΡ€ разновидностСй повСрхностных Ρ„Π°Π· ванадия ΡƒΠ»ΡƒΡ‡ΡˆΠ°Π΅Ρ‚ Π°ΠΊΡ‚ΠΈΠ²Π½ΠΎΡΡ‚ΡŒ ΠΈ ΡΠ΅Π»Π΅ΠΊΡ‚ΠΈΠ²Π½ΠΎΡΡ‚ΡŒ Π½ΠΎΠ²ΠΎΠΉ каталитичСской систСмы

    Mixed M-V-Sb oxides as oxodehydrogenization catalysts

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    The properties of mixed M-V-Sb (M = Ni, Co, Bi, Sn) oxides, supported on aluminum oxide, have been physically characterized and their activities estimated .in dehydrogenation of light paraffins, ethyl benzene and ethanol. The most selective NiVSb catalyst was easily reduced which allowed for proposing of the reduction-oxidation mechanism .The result of kinetic researches has shown that, the concentration of oxygen in the gas phase is the key parameter responsible for dehydrogenation selectivity. To maintain the optimal process conditions, oxygen was distributed along the catalyst layers

    Isobutane dehydrogenation by oxidizing in isobutene on Ni-V-Sb/Ξ³Al<sub>2</sub>O<sub>3</sub> catalytic system

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    Addition of nickel oxide in the V-Sb/Ξ³Al2O3 catalytic system, used in oxidative dehydrogenation of isobutane, significantly increases conversion (from 36 to 42-44%) at isobutene selectivity of 70 %. The developed catalysts consisting of systems V-Sb-O and V-Sb-Ni-O were characterized using XRD, XPS, and H2-TPR. Formation of the discovered nickel vanadate phase NiV2O6 is as a result of free phase VOx is a more effective catalyst due to increase in the quantity of mobile oxygen lattice. It is suggested that the set of various vanadium surface phases improves activity and selectivity of the new catalytic systems

    Bioactivity and applications of polysaccharides from marine microalgae

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