Scanning Electron Microscopy in the Evaluation of Consolidation Treatments for Stone

The use of scanning electron microscopy (SEM) examination is shown to be an important tool in the evaluation of the effectiveness of consolidant treatments in stone. This implies the visualization of the attachment of the resin to the stone, the assessment of the degree of penetration and the distribution of the resin in the stone matrix. These factors can then be correlated with the chemical nature of the stone and the resin. A sample preparation technique for limestone, based on acid etching of the surface, is described. This technique improves the visualization of the resin within the stone

Development of biocolonization resistant mortars: preliminary results

Restoration of Buildings and Monuments, vol. 13, nº 6 (2007), p.389-400The negative impact of biocolonization on buildings, particularly rendered ones, prompted the evaluation of a hydraulic mortar formulation to which copper metal, either as a powder or as fibres, was added as a means to control this problem. The study used in situ exposure in a location prone to biocolonization for over nine years. The results have proved that over this time period, no biocolonization occurred on samples containing 0.35 % by weight of copper powder with regards to the dry mortar mix. The mortar proved to acquire a slightly bluer-green hue which diminished after the nine year outdoor exposure. The mortars formulated with copper have a lower porosity as well as a lower capillary water absorption coefficient a definite advantage for their eventual life span. On the other hand, the mechanical resistance is slightly decreased but not significantly so. Further studies are envisioned to assess the performance with other types of binder, such as aerial lime

Dual-barrel conductance micropipet as a new approach to the study of ionic crystal dissolution kinetics

A new approach to the study of ionic crystal dissolution kinetics is described, based on the use of a dual-barrel theta conductance micropipet. The solution in the pipet is undersaturated with respect to the crystal of interest, and when the meniscus at the end of the micropipet makes contact with a selected region of the crystal surface, dissolution occurs causing the solution composition to change. This is observed, with better than 1 ms time resolution, as a change in the ion conductance current, measured across a potential bias between an electrode in each barrel of the pipet. Key attributes of this new technique are: (i) dissolution can be targeted at a single crystal surface; (ii) multiple measurements can be made quickly and easily by moving the pipet to a new location on the surface; (iii) materials with a wide range of kinetics and solubilities are open to study because the duration of dissolution is controlled by the meniscus contact time; (iv) fast kinetics are readily amenable to study because of the intrinsically high mass transport rates within tapered micropipets; (v) the experimental geometry is well-defined, permitting finite element method modeling to allow quantitative analysis of experimental data. Herein, we study the dissolution of NaCl as an example system, with dissolution induced for just a few milliseconds, and estimate a first-order heterogeneous rate constant of 7.5 (±2.5) × 10–5 cm s–1 (equivalent surface dissolution flux ca. 0.5 μmol cm–2 s–1 into a completely undersaturated solution). Ionic crystals form a huge class of materials whose dissolution properties are of considerable interest, and we thus anticipate that this new localized microscale surface approach will have considerable applicability in the future

Deterioration of brick masonry caused by acid rain, in “Materials Degradation caused by Acid Rain”

R.Baboian ed, Washington D.