262 research outputs found
ΠΡΡΠ»Π΅Π΄ΠΎΠ²Π°Π½ΠΈΡ Π²ΠΎΠ·ΠΌΠΎΠΆΠ½ΠΎΡΡΠΈ ΠΏΠΎΠ»ΡΡΠ΅Π½ΠΈΡ ΡΠ°ΠΌΠΎΠ²ΡΠΏΠ΅Π΅Π½ΠΈΠ²Π°ΡΡΠ΅Π³ΠΎΡΡ ΠΊΠΎΠΌΠΏΠΎΠ·ΠΈΡΠ½Π½ΠΎΠ³ΠΎ ΠΌΠ°ΡΠ΅ΡΠΈΠ°Π»Π° ΠΏΡΡΠ΅ΠΌ Π°ΠΊΠΊΡΠΌΡΠ»ΠΈΡΡΡΡΠ΅ΠΉ ΠΌΠ½ΠΎΠ³ΠΎΡΠ»ΠΎΠΉΠ½ΠΎΠΉ ΠΏΡΠΎΠΊΠ°ΡΠΊΠΈ
Mathematical model of stacked one-sided arrangement of the burners
Paper is aimed at computer simulation of the turbulent methane-air combustion in upgraded U-shaped boiler unit. To reduce the temperature in the flame and hence NOx release every burner output was reduced, but the number of the burners was increased. The subject of studying: complex of characteristics with space-time fields in the upgraded steam boiler E-370 with natural circulation. The flare structure, temperature and concentrations were determined computationally
ΠΠΠΠ-4-ΠΠΠΠΠΠΠΠ ΠΠΠΠΠΠΠΠ«Π ΠΠΠΠΠΠ£ΠΠΠ Π ΠΠΠ§ΠΠ‘Π’ΠΠ ΠΠΠΠΠ€ΠΠΠΠ’ΠΠ ΠΠ ΠΠΠΠΠ’Π ΠΠ€ΠΠ ΠΠ’ΠΠ§ΠΠ‘ΠΠΠ₯ Π‘ΠΠ‘Π’ΠΠ ΠΠΠ― Π ΠΠΠΠΠΠΠΠΠ― ΠΠΠ Π―ΠΠΠΠΠ«Π₯ ΠΠΠΠΠΠ’ΠΠ
Novel hydrophilic ionic polymer nanoparticles based on the N-alkylated hypercrosslinked poly-4-vinylpyridine (nanosponges β NS) have porous structure, pH-independent positive charge and contain the aromatic rings. These nanosponges have not yet been studied in the capillary electrophoresis mode, but their characteristics suggest the possibility of creating the fused silica capillary walls coating for the separation of anionic and cationic analytes. In the current research, the authors, for the first time, have proposed the approaches to the formation of coatings based on the nanosponges with a molecular weight of 400 and 10 kDa. It was established that the stability of such coatings could be achieved by the introduction of NS into the background electrolyte. The pH range of background electrolytes for the subsequent electrophoretic experiments was determined to be from 4 to 9. The NS-based coatings were compared with the previously investigated coatings based on the crosslinked polystyrene nanoparticles (NPs), functionalized with the quaternary ammonium groups. Capillaries modified with NS (400 kDa) were tested for the electrophoretic separations of wide range of analytes: carboxylic acids, aminoacids, fluoroquinoline antibiotics, biogenic amines, and proteins. The separation selectivity of carboxylic acids on the NS-modified capillaries was different from the separation selectivity on the capillaries modified with NPs, functionalized with quaternary ammonium groups. NS affect the separation selectivity of aminoacids by interacting with these analytes, while for fluoroquinoline antibiotics NS act as an agent generating the reversed electroosmotic flow (EOF). The modification of fused silica capillary walls by NS with molecular mass of 400 kDa prevented the sorption of biogeniΡ amines and lyzocyme protein during their electrophoretic separation.Keywords: capillary electrophoresis, nanoparticles, coatings of fused silica capillary wallsDOI: http://dx.doi.org/10.15826/analitika.2019.23.2.006(Russian)D.A. Polikarpova1, D.V. Makeeva1, L.A. Kartsova1, V.A. Davankov2, L.A. Pavlova2Β 1Saint-Petersburg State University, Institute of Chemistry,Universitetskii pr. 26., St. Petersburg, Petergof, 198504, Russian Federation2A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Vavilova St. 28, Moscow, 119334, Russian FederationΠΠΎΠ²ΡΠ΅ Π³ΠΈΠ΄ΡΠΎΡΠΈΠ»ΡΠ½ΡΠ΅ ΠΈΠΎΠ½Π½ΡΠ΅ ΠΏΠΎΠ»ΠΈΠΌΠ΅ΡΠ½ΡΠ΅ Π½Π°Π½ΠΎΡΠ°ΡΡΠΈΡΡ Π½Π° ΠΎΡΠ½ΠΎΠ²Π΅ N-Π°Π»ΠΊΠΈΠ»ΠΈΡΠΎΠ²Π°Π½Π½ΠΎΠ³ΠΎ ΡΠ²Π΅ΡΡ
ΡΡΠΈΡΠΎΠ³ΠΎ ΠΏΠΎΠ»ΠΈ-4-Π²ΠΈΠ½ΠΈΠ»ΠΏΠΈΡΠΈΠ΄ΠΈΠ½Π° (Π½Π°Π½ΠΎΠ³ΡΠ±ΠΊΠΈ β ΠΠ) Β ΠΈΠΌΠ΅ΡΡ ΠΏΠΎΡΠΈΡΡΡΡ ΡΡΡΡΠΊΡΡΡΡ, Π½Π΅ΡΡΡ ΡΠ-Π½Π΅Π·Π°Π²ΠΈΡΠΈΠΌΡΠΉ ΠΏΠΎΠ»ΠΎΠΆΠΈΡΠ΅Π»ΡΠ½ΡΠΉ Π·Π°ΡΡΠ΄ ΠΈ ΡΠΎΠ΄Π΅ΡΠΆΠ°Ρ Π°ΡΠΎΠΌΠ°ΡΠΈΡΠ΅ΡΠΊΠΈΠ΅ Π·Π²Π΅Π½ΡΡ, ΡΡΠΎ ΠΏΠΎΠ·Π²ΠΎΠ»ΡΠ΅Ρ ΠΏΡΠ΅Π΄ΠΏΠΎΠ»Π°Π³Π°ΡΡ Π²ΠΎΠ·ΠΌΠΎΠΆΠ½ΠΎΡΡΡ ΡΠΎΡΠΌΠΈΡΠΎΠ²Π°Π½ΠΈΡ ΠΏΠΎΠΊΡΡΡΠΈΠΉ ΡΡΠ΅Π½ΠΎΠΊ ΠΊΠ²Π°ΡΡΠ΅Π²ΠΎΠ³ΠΎ ΠΊΠ°ΠΏΠΈΠ»Π»ΡΡΠ° Π½Π° ΠΈΡ
ΠΎΡΠ½ΠΎΠ²Π΅ Π΄Π»Ρ ΡΠ°Π·Π΄Π΅Π»Π΅Π½ΠΈΡ Π°Π½ΠΈΠΎΠ½Π½ΡΡ
ΠΈ ΠΊΠ°ΡΠΈΠΎΠ½Π½ΡΡ
Π°Π½Π°Π»ΠΈΡΠΎΠ². Π ΡΠ°ΠΌΠΊΠ°Ρ
ΠΈΡΡΠ»Π΅Π΄ΠΎΠ²Π°Π½ΠΈΡ Π²ΠΏΠ΅ΡΠ²ΡΠ΅ ΠΏΡΠ΅Π΄Π»ΠΎΠΆΠ΅Π½Ρ ΠΏΠΎΠ΄Ρ
ΠΎΠ΄Ρ ΠΊ ΡΠΎΡΠΌΠΈΡΠΎΠ²Π°Π½ΠΈΡ ΠΏΠΎΠΊΡΡΡΠΈΠΉ Π½Π° ΠΎΡΠ½ΠΎΠ²Π΅ Π½Π°Π½ΠΎΠ³ΡΠ±ΠΎΠΊ Ρ ΠΌΠΎΠ»Π΅ΠΊΡΠ»ΡΡΠ½ΠΎΠΉ ΠΌΠ°ΡΡΠΎΠΉ 400 ΠΈ 10Β Β ΠΊΠΠ°. ΠΠΎΠΊΠ°Π·Π°Π½ΠΎ, ΡΡΠΎ Π΄Π»Ρ ΠΎΠ±Π΅ΡΠΏΠ΅ΡΠ΅Π½ΠΈΡ ΡΡΠ°Π±ΠΈΠ»ΡΠ½ΠΎΡΡΠΈ ΡΠ°ΠΊΠΈΡ
ΠΏΠΎΠΊΡΡΡΠΈΠΉ Π½Π΅ΠΎΠ±Ρ
ΠΎΠ΄ΠΈΠΌΠΎ Π²Π²Π΅Π΄Π΅Π½ΠΈΠ΅ ΠΠ Π² ΡΠΎΡΡΠ°Π² ΡΠΎΠ½ΠΎΠ²ΠΎΠ³ΠΎ ΡΠ»Π΅ΠΊΡΡΠΎΠ»ΠΈΡΠ° (Π€Π). ΠΠΏΡΠ΅Π΄Π΅Π»Π΅Π½ ΡΠ°Π±ΠΎΡΠΈΠΉ Π΄ΠΈΠ°ΠΏΠ°Π·ΠΎΠ½ ΡΠ Π€Π (4-9) Π΄Π»Ρ ΠΏΠΎΡΠ»Π΅Π΄ΡΡΡΠΈΡ
ΡΠ»Π΅ΠΊΡΡΠΎΡΠΎΡΠ΅ΡΠΈΡΠ΅ΡΠΊΠΈΡ
ΡΠΊΡΠΏΠ΅ΡΠΈΠΌΠ΅Π½ΡΠΎΠ². Π Π΅Π·ΡΠ»ΡΡΠ°ΡΡ ΡΠΎΠΏΠΎΡΡΠ°Π²Π»Π΅Π½Ρ Ρ ΠΏΠΎΠ»ΡΡΠ΅Π½Π½ΡΠΌΠΈ Π½Π°ΠΌΠΈ ΡΠ°Π½Π΅Π΅ ΡΠΊΡΠΏΠ΅ΡΠΈΠΌΠ΅Π½ΡΠ°Π»ΡΠ½ΡΠΌΠΈ Π΄Π°Π½Π½ΡΠΌΠΈ ΠΏΠΎ ΡΠΎΡΠΌΠΈΡΠΎΠ²Π°Π½ΠΈΡ ΠΏΠΎΠΊΡΡΡΠΈΠΉ Π½Π° ΠΎΡΠ½ΠΎΠ²Π΅ Π½Π°Π½ΠΎΡΠ°Π·ΠΌΠ΅ΡΠ½ΡΡ
ΡΠ°ΡΡΠΈΡ (ΠΠ§) ΡΡΠΈΡΠΎΠ³ΠΎ ΠΏΠΎΠ»ΠΈΡΡΠΈΡΠΎΠ»Π°, ΡΡΠ½ΠΊΡΠΈΠΎΠ½Π°Π»ΠΈΠ·ΠΈΡΠΎΠ²Π°Π½Π½ΡΡ
ΡΠ΅ΡΠ²Π΅ΡΡΠΈΡΠ½ΡΠΌΠΈ Π°ΠΌΠΌΠΎΠ½ΠΈΠΉΠ½ΡΠΌΠΈ Π³ΡΡΠΏΠΏΠ°ΠΌΠΈ. ΠΠ»Ρ Π²ΡΡΠ²Π»Π΅Π½ΠΈΡ ΠΏΠ΅ΡΡΠΏΠ΅ΠΊΡΠΈΠ² ΠΏΠΎΠΊΡΡΡΠΈΡ Π½Π° ΠΎΡΠ½ΠΎΠ²Π΅ ΠΠ Ρ ΠΌΠΎΠ»Π΅ΠΊΡΠ»ΡΡΠ½ΠΎΠΉ ΠΌΠ°ΡΡΠΎΠΉ 400 ΠΊΠΠ° ΡΠ°ΡΡΠΌΠΎΡΡΠ΅Π½ ΡΠΈΡΠΎΠΊΠΈΠΉ ΡΠΏΠ΅ΠΊΡΡ Π°Π½Π°Π»ΠΈΡΠΎΠ²: ΠΊΠ°ΡΠ±ΠΎΠ½ΠΎΠ²ΡΠ΅ ΠΊΠΈΡΠ»ΠΎΡΡ, Π°ΠΌΠΈΠ½ΠΎΠΊΠΈΡΠ»ΠΎΡΡ, Π°Π½ΡΠΈΠ±ΠΈΠΎΡΠΈΠΊΠΈ ΡΡΠΎΡΡ
ΠΈΠ½ΠΎΠ»ΠΎΠ½ΠΎΠ²ΠΎΠ³ΠΎ ΡΡΠ΄Π°, Π±ΠΈΠΎΠ³Π΅Π½Π½ΡΠ΅ Π°ΠΌΠΈΠ½Ρ, Π±Π΅Π»ΠΊΠΈ. Π Π°Π·Π΄Π΅Π»Π΅Π½ΠΈΠ΅ ΠΊΠ°ΡΠ±ΠΎΠ½ΠΎΠ²ΡΡ
ΠΊΠΈΡΠ»ΠΎΡ Π½Π° ΡΠ°ΠΊΠΈΡ
ΠΊΠ°ΠΏΠΈΠ»Π»ΡΡΠ°Ρ
Ρ
Π°ΡΠ°ΠΊΡΠ΅ΡΠΈΠ·ΡΠ΅ΡΡΡ ΠΈΠ½ΠΎΠΉ ΡΠ΅Π»Π΅ΠΊΡΠΈΠ²Π½ΠΎΡΡΡΡ ΠΏΠΎ ΡΡΠ°Π²Π½Π΅Π½ΠΈΡ Ρ ΠΊΠ°ΠΏΠΈΠ»Π»ΡΡΠ°ΠΌΠΈ, ΠΏΠΎΠΊΡΡΡΡΠΌΠΈ ΠΠ§, ΡΡΠ½ΠΊΡΠΈΠΎΠ½Π°Π»ΠΈΠ·ΠΈΡΠΎΠ²Π°Π½Π½ΡΠΌΠΈ ΡΠ΅ΡΠ²Π΅ΡΡΠΈΡΠ½ΡΠΌΠΈ Π°ΠΌΠΌΠΎΠ½ΠΈΠΉΠ½ΡΠΌΠΈ Π³ΡΡΠΏΠΏΠ°ΠΌΠΈ. ΠΡΠΈ ΡΠ°Π·Π΄Π΅Π»Π΅Π½ΠΈΠΈ Π°ΠΌΠΈΠ½ΠΎΠΊΠΈΡΠ»ΠΎΡ ΠΠ Π²Π»ΠΈΡΡΡ Π½Π° ΡΠ΅Π»Π΅ΠΊΡΠΈΠ²Π½ΠΎΡΡΡ ΡΠ°Π·Π΄Π΅Π»Π΅Π½ΠΈΡ Π·Π° ΡΡΠ΅Ρ Π²Π·Π°ΠΈΠΌΠΎΠ΄Π΅ΠΉΡΡΠ²ΠΈΡ Ρ Π°Π½Π°Π»ΠΈΡΠ°ΠΌΠΈ, Π° Π² ΡΠ»ΡΡΠ°Π΅ Π°Π½ΡΠΈΠ±ΠΈΠΎΡΠΈΠΊΠΎΠ² ΠΠ Π²ΡΡΡΡΠΏΠ°ΡΡ ΡΠΎΠ»ΡΠΊΠΎ Π² ΡΠΎΠ»ΠΈ Π°Π³Π΅Π½ΡΠ°, ΠΎΠ±ΡΠ°ΡΠ°ΡΡΠ΅Π³ΠΎ ΡΠ»Π΅ΠΊΡΡΠΎΠΎΡΠΌΠΎΡΠΈΡΠ΅ΡΠΊΠΈΠΉ ΠΏΠΎΡΠΎΠΊ (ΠΠΠ). Π£ΡΡΠ°Π½ΠΎΠ²Π»Π΅Π½ΠΎ, ΡΡΠΎ ΠΌΠΎΠ΄ΠΈΡΠΈΠΊΠ°ΡΠΈΡ ΡΡΠ΅Π½ΠΎΠΊ ΠΊΠ°ΠΏΠΈΠ»Π»ΡΡΠ° ΠΠ Ρ ΠΌΠΎΠ»Π΅ΠΊΡΠ»ΡΡΠ½ΠΎΠΉ ΠΌΠ°ΡΡΠΎΠΉ 400 ΠΊΠΠ° ΠΏΠΎΠ·Π²ΠΎΠ»ΡΠ΅Ρ ΠΏΡΠ΅Π΄ΠΎΡΠ²ΡΠ°ΡΠ°ΡΡ ΡΠΎΡΠ±ΡΠΈΡ ΠΎΡΠ½ΠΎΠ²Π½ΡΡ
Π°Π½Π°Π»ΠΈΡΠΎΠ² (Π±ΠΈΠΎΠ³Π΅Π½Π½ΡΠ΅ Π°ΠΌΠΈΠ½Ρ, Π±Π΅Π»ΠΎΠΊ Π»ΠΈΠ·ΠΎΡΠΈΠΌ) Π² ΠΏΡΠΎΡΠ΅ΡΡΠ΅ ΠΈΡ
ΡΠ»Π΅ΠΊΡΡΠΎΡΠΎΡΠ΅ΡΠΈΡΠ΅ΡΠΊΠΎΠ³ΠΎ ΡΠ°Π·Π΄Π΅Π»Π΅Π½ΠΈΡ.ΠΠ»ΡΡΠ΅Π²ΡΠ΅ ΡΠ»ΠΎΠ²Π°: ΠΊΠ°ΠΏΠΈΠ»Π»ΡΡΠ½ΡΠΉ ΡΠ»Π΅ΠΊΡΡΠΎΡΠΎΡΠ΅Π·, Π½Π°Π½ΠΎΡΠ°ΡΡΠΈΡΡ, ΠΏΠΎΠΊΡΡΡΠΈΡ ΡΡΠ΅Π½ΠΎΠΊ ΠΊΠ°ΠΏΠΈΠ»Π»ΡΡΠ°DOI: http://dx.doi.org/10.15826/analitika.2019.23.3.00
Biological Homochirality on the Earth, or in the Universe? A Selective Review
The discovery of meteoritic alpha-amino acids with significant enantiomeric excesses of the L-form has suggested that some cosmic factors could serve as the initial source for chiral imbalance of organic compounds delivered to the early Earth. The paper reviews major hypothesis considering the influence of chiral irradiation and chiral combinations of physical fields on the possible ways asymmetric synthesis and transformations of organics could take place within the solar system. They could result in a small enantiomeric imbalance of some groups of compounds. More attention is paid to the hypothesis on parity violation of weak interaction that was supposed to cause homochirality of all primary particles and a more significant homochirality of compounds directly synthesized from the latter in a plasma reactor. The first experiment with material synthesized in a plasma torch resulting from a super-high-velocity impact showed formation of alanine with the excess of L-form between 7 and 25%. The supposed conclusion is that L-amino acids could serve as a starting homochiral biomolecular pool for life to emerge all over the Universe
Critical review on the origin of atmospheric oxygen: Where is organic matter?
In a short note of 1998 Davankov questioned the generally accepted notion that the unique features of the planet Earth, namely, the presence of life and atmospheric oxygen are inseparably bonded as a case and effect. Indeed, photosynthesis in terrestrial and aquatic phototrophs simultaneously produces oxygen and carbohydrates in almost equal amounts. Since the degradation of organic matter through burning or rotting also consumes an equivalent amount of oxygen, the total masses of oxygen and organic material must always remain comparable. This correlation for Earth appears to be drastically distorted in favor of oxygen, thus disproving the still widespread delusion of biogenic origin of atmospheric oxygen. Instead, by analyzing more recent data on the balance between oxygen and organics we arrive at the conclusion that radiolysis of water vapors with the preferential dissipation of hydrogen to space, most probably, was the major source of the free and oxidation-spent oxygen. The present review tries to illuminate the most important uncertainties that still remain to be clarified before an interdisciplinary and scientifically-balanced picture on the evolution of Earth gets settled
Resolution of racemates by ligand-exchange chromatography on sorbents based on L-serine, L-threonine, and L-tyrosine
Resolution of racemates by ligand-exchange chromatography on sorbents based on D-alanine, L-valine, and L-isoleucine
Revisiting the problem of correcting retention parameters for pressure and temperature in gas chromatography
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