Structure and properties of the stable two-dimensional conducting polymer Mg5C60

We present a study on the structural, spectroscopic, conducting, and magnetic properties of Mg5C60, which is a two-dimensional (2D) fulleride polymer. The polymer phase is stable up to the exceptionally high temperature of 823 K. The infrared and Raman studies suggest the formation of single bonds between the fulleride ions and possibly Mg-C-60 covalent bonds. Mg5C60 is a metal at ambient temperature, as shown by electron spin resonance and microwave conductivity measurements. The smooth transition from a metallic to a paramagnetic insulator state below 200 K is attributed to Anderson localization driven by structural disorder

Transport properties and the anisotropy of Ba_{1-x}K_xFe_2As_2 single crystals in normal and superconducting states

The transport and superconducting properties of Ba_{1-x}K_xFe_2As_2 single crystals with T_c = 31 K were studied. Both in-plane and out-of plane resistivity was measured by modified Montgomery method. The in-plane resistivity for all studied samples, obtained in the course of the same synthesis, is almost the same, unlike to the out-of plane resistivity, which differ considerably. We have found that the resistivity anisotropy \gamma=\rho_c /\rho_{ab} is almost temperature independent and lies in the range 10-30 for different samples. This, probably, indicates on the extrinsic nature of high out-of-plane resistivity, which may appear due to the presence of the flat defects along Fe-As layers in the samples. This statement is supported by comparatively small effective mass anisotropy, obtained from the upper critical field measurements, and from the observation of the so-called "Friedel transition", which indicates on the existence of some disorder in the samples in c-direction.Comment: 5 pages, 5 figure

Anomalous behaviour of the in-plane electrical conductivity of the layered superconductor κ\kappa-(BEDT-TTF)2_2Cu(NCS)2_2

The quasiparticle scattering rates in high-quality crystals of the quasi-two-dimensional superconductor $\kappa$-(BEDT-TTF)$_2$Cu(NCS)$_2$ ~are studied using the Shubnikov-de Haas effect and MHz penetration-depth experiments. There is strong evidence that the broadening of the Landau-levels is primarily caused by spatial inhomogeneities, indicating a quasiparticle lifetime for the Landau states $\gg 3$ ps. In contrast to the predictions of Fermi-liquid theory, the scattering time derived from the intralayer conductivity is found to be much shorter ($0.14-0.56$ ps)

On-chain electrodynamics of metallic (TMTSF)_2 X salts: Observation of Tomonaga-Luttinger liquid response

We have measured the electrodynamic response in the metallic state of three highly anisotropic conductors, (TMTSF)_2 X, where X=PF_6, AsF_6, or ClO_4, and TMTSF is the organic molecule tetramethyltetraselenofulvalene. In all three cases we find dramatic deviations from a simple Drude response. The optical conductivity has two features: a narrow mode at zero frequency, with a small spectral weight, and a mode centered around 200 cm^{-1}, with nearly all of the spectral weight expected for the relevant number of carriers and single particle bandmass. We argue that these features are characteristic of a nearly one-dimensional half- or quarter-filled band with Coulomb correlations, and evaluate the finite energy mode in terms of a one-dimensional Mott insulator. At high frequencies (\hbar\omega > t_\perp, the transfer integral perpendicular to the chains), the frequency dependence of the optical conductivity \sigma_1(\omega) is in agreement with calculations based on an interacting Tomonaga-Luttinger liquid, and is different from what is expected for an uncorrelated one-dimensional semiconductor. The zero frequency mode shows deviations from a simple Drude response, and can be adequately described with a frequency dependent mass and relaxation rate.Comment: 12 pages, 7 figures, RevTeX; minor corrections to text and references; To be published in Phys. Rev. B, 15 July 199

Transport properties of strongly correlated metals:a dynamical mean-field approach

The temperature dependence of the transport properties of the metallic phase of a frustrated Hubbard model on the hypercubic lattice at half-filling are calculated. Dynamical mean-field theory, which maps the Hubbard model onto a single impurity Anderson model that is solved self-consistently, and becomes exact in the limit of large dimensionality, is used. As the temperature increases there is a smooth crossover from coherent Fermi liquid excitations at low temperatures to incoherent excitations at high temperatures. This crossover leads to a non-monotonic temperature dependence for the resistance, thermopower, and Hall coefficient, unlike in conventional metals. The resistance smoothly increases from a quadratic temperature dependence at low temperatures to large values which can exceed the Mott-Ioffe-Regel value, hbar a/e^2 (where "a" is a lattice constant) associated with mean-free paths less than a lattice constant. Further signatures of the thermal destruction of quasiparticle excitations are a peak in the thermopower and the absence of a Drude peak in the optical conductivity. The results presented here are relevant to a wide range of strongly correlated metals, including transition metal oxides, strontium ruthenates, and organic metals.Comment: 19 pages, 9 eps figure

Comparison of coherent and weakly incoherent transport models for the interlayer magnetoresistance of layered Fermi liquids

The interlayer magnetoresistance of layered metals in a tilted magnetic field is calculated for two distinct models for the interlayer transport. The first model involves coherent interlayer transport and makes use of results of semi-classical or Bloch-Boltzmann transport theory. The second model involves weakly incoherent interlayer transport where the electron is scattered many times within a layer before tunneling into the next layer. The results are relevant to the interpretation of experiments on angular-dependent magnetoresistance oscillations (AMRO) in quasi-one- and quasi-two-dimensional metals. We find that the dependence of the magnetoresistance on the direction of the magnetic field is identical for both models except when the field is almost parallel to the layers. An important implication of this result is that a three-dimensional Fermi surface is not necessary for the observation of the Yamaji and Danner oscillations seen in quasi-two- and quasi-one-dimensional metals, respectively. A universal expression is given for the dependence of the resistance at AMRO maxima and minima on the magnetic field and scattering time (and thus the temperature). We point out three distinctive features of coherent interlayer transport: (i) a beat frequency in the magnetic oscillations of quasi-two-dimensional systems, (ii) a peak in the angular-dependent magnetoresistance when the field is sufficiently large and parallel to the layers, and (iii) a crossover from a linear to a quadratic field dependence for the magnetoresistance when the field is parallel to the layers. Properties (i) and (ii) are compared with published experimental data for a range of quasi-two-dimensional organic metals and for Sr2RuO4.Comment: 21 pages, RevTeX + epsf, 4 figures. Published version. Subsection added. References update

Incoherent interlayer transport and angular-dependent magnetoresistance oscillations in layered metals

The effect of incoherent interlayer transport on the interlayer resistance of a layered metal is considered. We find that for both quasi-one-dimensional and quasi-two-dimensional Fermi liquids the angular dependence of the magnetoresistance is essentially the same for coherent and incoherent transport. Consequently, the existence of a three-dimensional Fermi surface is not necessary to explain the oscillations in the magnetoresistance that are seen in many organic conductors as the field direction is varied. [S0031-9007(98)07660-1]

Incoherent Interplane Conductivity of kappa-(BEDT-TTF)2Cu[N(CN)2]Br

The interplane optical spectrum of the organic superconductor kappa-(BEDT-TTF)2Cu[N(CN)2]Br was investigated in the frequency range from 40 to 40,000 cm-1. The optical conductivity was obtained by Kramers-Kronig analysis of the reflectance. The absence of a Drude peak at low frequency is consistent with incoherent conductivity but in apparent contradiction to the metallic temperature dependence of the DC resistivity. We set an upper limit to the interplane transfer integral of tb = 0.1 meV. A model of defect-assisted interplane transport can account for this discrepancy. We also assign the phonon lines in the conductivity to the asymmetric modes of the ET molecule.Comment: 7 pages with embedded figures, submitted to PR

Influence of internal disorder on the superconducting state in the organic layered superconductor kappa-(BEDT-TTF)2Cu[N(CN)2]Br

We report high-sensitivity AC susceptibility measurements of the penetration depth in the Meissner state of the layered organic superconductor kappa-(BEDT-TTF)2Cu[N(CN)2]Br. We have studied nominally pure single crystals from the two different syntheses and employed controlled cooling procedures in order to minimize intrinsic remnant disorder at low temperatures associated with the glass transition, caused by ordering of the ethylene moieties in BEDT-TTF molecule at T_G = 75 K. We find that the optimal cooling procedures (slow cooling of -0.2 K/h or annealing for 3 days in the region of T_G) needed to establish the ground state, depend critically on the sample origin indicating different relaxation times of terminal ethylene groups. We show that, in the ground state, the behavior observed for nominally pure single crystals from both syntheses is consistent with unconventional d-wave order parameter. The in-plane penetration depth lambda_in(T) is strongly linear, whereas the out-of-plane component lambda_out(T) varies as T^2. In contrast, the behavior of single crystals with long relaxation times observed after slow (-0.2 K/h) cooling is as expected for a d-wave superconductor with impurities (i.e. lambda_in(T) propto lambda_out(T) propto T^2) or might be also reasonably well described by the s-wave model. Our results might reconcile the contradictory findings previously reported by different authors.Comment: 13 pages, 10 figures, submitted to Phys. Rev.