Device optimization Based on Electrical and Optical Simulation of Tris(8-hydroxyquinoline) Aluminium Based Microacavity Organic Light Emitting Diode (MOLED)

OLED has emerged as a potential candidate for applications in display devices due to its prominent advantages in size, brightness and wide viewing angle. Following our previous work, where optical analysis of the OLED has been documented1 we present in this work detailed examination optical and electrical analysis of the performance of an OLEDs based on two organic layers: N,N'-di(naphthalene-1-yl)-N,N'-diphenylbenzidine (NPB) as the hole transport layer and tris (8-hydroxyquinoline) aluminium (Alq3) as the emitting layer, and two metallic mirrors. Our optical model fully takes into account dispersion in glass substrate, organic layers as well as the dispersion in metal contacts/mirrors. Influence of the incoherent transparent glass substrate is also accounted for. Two metal contacts Ag and Cu have been considered for anode and cathode respectively. For the hole transport layer NPB was used. The OLED structure is examined as a function of: thickness of the organic layers, and position of the hole transport layer/Alq3 interface. In order to obtain better agreement with EL experimental data, electrical models was developed in conjunction with the existing optical model to facilitate accurate optimisation of the OLED structure. The electrical model developed considers the metal contact as Schottky contact, the carrier mobility is taken to be field dependent with the Poole-Frenkel-like form and Langevin recombination model is used. The carrier transport was simulated using one-dimensional time-independent drift-diffusion model using device simulation software ATLAS.2 Finally, the optimised devices were fabricated and characterised and experimental and calculated optical emission spectra were compared together with results obtained from electrical transport model

Electrical and Optical Simulation of Tris(8-hydroxyquinoline) Aluminium-Based Microcavity Organic Light Emitting Diode (MOLED)

A detailed examination of the emitted radiation spectrum from tris(8-hydroxyquinoline) aluminum (Alq) based OLEDs on optical and electrical models have been presented. The OLED structure is examined as a function of choice of anode material and position of the NPB/Alq interface. The simulation results have been compared to those obtained from experiments, showing good agreement in both electrical and optical characteristics. The enhancement in light emission by aligning antinode of the stand wave pattern with effective carrier recombination region has been observed

Shape transition in ZnO nanostructures and its effect on blue-green photoluminescence

We report that ZnO nanostructures synthesized by chemical route undergo a shape transition at ~ 20 nm from spherical to hexagonal morphology thereby changing the spectral components of the blue-green emission. Spherically shaped nanocrystals (size range 11 -18 nm) show emission in the range of 555-564 nm and the emission shifts to the longer wavelength as the size increases. On the other hand, rods and hexagonal platelets (size range 20-85 nm), which is the equilibrium morphology after the shape transition, show emission near 465-500 nm and it shifts to shorter wavelength as the size increases. The shape transition also leads to relaxation of microstrain in the system. Our analysis shows that the visible emission originates from a defect layer on the nanostructure surface which is affected by the shape transition. The change in the spectral component of the blue green emission on change of shape has been explained as arising from band bending due to depletion layer in smaller spherical particles which is absent in the larger particles with flat faces.Comment: 8 pages, 8 figure

Optimization of Organic Light Emitting Diode Structures

In this work we present detailed analysis of the emitted radiation spectrum from tris(8-hydroxyquinoline) aluminum (Alq3) based OLEDs as a function of: the choice of cathode, the thickness of organic layers, and the position of the hole transport layer/Alq3 interface. The calculations fully take into account dispersion in glass substrate, indium tin oxide anode, and in the organic layers, as well as the dispersion in the metal cathode. Influence of the incoherent transparent substrate (1 mm glass substrate) is also fully accounted for. Four cathode structures have been considered: Mg/Ag, Ca/Ag, LiF/Al, and Ag. For the hole transport layer, N,N'-diphenyl-N,N'-(3-methylphenyl)-1,1'-biphenyl-4,4'-diamine (TPD) was considered. As expected, emitted radiation is strongly dependent on the position of the emissive layer inside the cavity and its distance from the metal cathode. Although our optical model for an OLED does not explicitly include exciton quenching in vicinity of the metal cathode, designs placing emissive layer near the cathode are excluded to avoid unrealistic results. Guidelines for designing devices with optimum emission efficiency are presented. Finally, the optimized devices were fabricated and characterized and experimental and calculated emission spectra were compared

Cavity Design and Optimization for Organic Microcavity OLEDs

We report on detailed simulations of the emission from microcavity OLEDs consisting of widely used organic materials, n,N'-di(naphthalene-1-yl)-N,N'-diphenyl-benzidine (NPB) as a hole transport layer and tris (8-hydroxyquinoline) (Alq3) as emitting and electron transporting layer. The thick silver film was considered as a top mirror, while silver or copper films on quartz substrate were considered as bottom mirrors. The electroluminescence emission spectra, electric field distribution inside the device, carrier density and recombination rate were calculated as a function of the position of the emission layer, i.e. interface between NPB and Alq3. In order to achieve optimum emission from a microcavity OLED, it is necessary to align the position of the recombination region with the antinode of the standing wave inside the cavity. Once the optimum structure has been determined, the microcavity OLED devices were fabricated and characterized. The experimental results have been compared to the simulations and the influence of the emission region width and position on the performance of microcavity OLEDs was discussed

Influence of layer thickness to the emission spectra in microcavity organic light emitting diodes

Microcavity organic light emitting diodes (OLEDs) have attracted great attention because they can reduce the width of emission spectra from organic materials, enhance brightness and achieve multipeak emission from the same material. In this work, we have fabricated microcavity OLEDs with widely used organic materials, such as N,N'-di(naphthalene-1-yl)-N,N'-diphenylbenzidine (NPB) as a hole transport layer and tris (8-hydroxyquinoline) (Alq) as emitting and electron transporting layer. These organic materials are sandwiched either between two thick silver mirrors or one thin copper and one thick silver mirrors. The influence of total cavity length (from 164 nm to 243nm) and the cavity Q-factor to the emission behavior has been investigated. In all cases, an OLED without bottom mirror, i.e. with the organic materials sandwiched between indium tin oxide and a thick silver mirror, has been fabricated for comparison. We have characterized the devices with photoluminescence, electroluminescence, and reflectance measurements. Multiple peaks have been observed for some devices at larger viewing angles

Modeling the optical constants of AlxGa1-xAs alloys

The extension of Adachi's model with a Gaussian-like broadening function, in place of Lorentzian, is used to model the optical dielectric function of the alloy AlxGa1-xAs. Gaussian-like broadening is accomplished by replacing the damping constant in the Lorentzian line shape with a frequency dependent expression. In this way, the comparative simplicity of the analytic formulas of the model is preserved, while the accuracy becomes comparable to that of more intricate models, and/or models with significantly more parameters. The employed model accurately describes the optical dielectric function in the spectral range from 1.5 to 6.0 eV within the entire alloy composition range. The relative rms error obtained for the refractive index is below 2.2% for all compositions. (C) 1999 American Institute of Physics. [S0021-8979(99)00512-5]

Rayleigh Imaging of Graphene and Graphene Layers

We investigate graphene and graphene layers on different substrates by monochromatic and white-light confocal Rayleigh scattering microscopy. The image contrast depends sensitively on the dielectric properties of the sample as well as the substrate geometry and can be described quantitatively using the complex refractive index of bulk graphite. For few layers (<6) the monochromatic contrast increases linearly with thickness: the samples behave as a superposition of single sheets which act as independent two dimensional electron gases. Thus, Rayleigh imaging is a general, simple and quick tool to identify graphene layers, that is readily combined with Raman scattering, which provides structural identification.Comment: 8 pages, 9 figure

Primer to Voltage Imaging With ANNINE Dyes and Two-Photon Microscopy

ANNINE-6 and ANNINE-6plus are voltage-sensitive dyes that when combined with two-photon microscopy are ideal for recording of neuronal voltages in vivo, in both bulk loaded tissue and the dendrites of single neurons. Here, we describe in detail but for a broad audience the voltage sensing mechanism of fast voltage-sensitive dyes, with a focus on ANNINE dyes, and how voltage imaging can be optimized with one-photon and two-photon excitation. Under optimized imaging conditions the key strengths of ANNINE dyes are their high sensitivity (0.5%/mV), neglectable bleaching and phototoxicity, a linear response to membrane potential, and a temporal resolution which is faster than the optical imaging devices currently used in neurobiology (order of nanoseconds). ANNINE dyes in combination with two-photon microscopy allow depth-resolved voltage imaging in bulk loaded tissue to study average membrane voltage oscillations and sensory responses. Alternatively, if ANNINE-6plus is applied internally, supra and sub threshold voltage changes can be recorded from dendrites of single neurons in awake animals. Interestingly, in our experience ANNINE-6plus labeling is impressively stable in vivo, such that voltage imaging from single Purkinje neuron dendrites can be performed for 2 weeks after a single electroporation of the neuron. Finally, to maximize their potential for neuroscience studies, voltage imaging with ANNINE dyes and two-photon microscopy can be combined with electrophysiological recording, calcium imaging, and/or pharmacology, even in awake animals