Sample preparation of metal alloys by electric discharge machining

Electric discharge machining was investigated as a noncontaminating method of comminuting alloys for subsequent chemical analysis. Particulate dispersions in water were produced from bulk alloys at a rate of about 5 mg/min by using a commercially available machining instrument. The utility of this approach was demonstrated by results obtained when acidified dispersions were substituted for true acid solutions in an established spectrochemical method. The analysis results were not significantly different for the two sample forms. Particle size measurements and preliminary results from other spectrochemical methods which require direct aspiration of liquid into flame or plasma sources are reported

Development of a drift-correction procedure for a direct-reading spectrometer

A procedure which provides automatic correction for drifts in the radiometric sensitivity of each detector channel in a direct-reading emission spectrometer is described. Such drifts are customarily controlled by the regular analyses of standards, which provide corrections for changes in the excitational, optical, and electronic components of the instrument. This standardization procedure, however, corrects for the optical and electronic drifts. It is a step that must be taken if the time, effort, and cost of processing standards is to be minimized. This method of radiometric drift correction uses a 1,000-W tungsten-halogen reference lamp to illuminate each detector through the same optical path as that traversed during sample analysis. The responses of the detector channels to this reference light are regularly compared with channel response to the same light intensity at the time of analytical calibration in order to determine and correct for drift. Except for placing the lamp in position, the procedure is fully automated and compensates for changes in spectral intensity due to variations in lamp current. A discussion of the implementation of this drift-correction system is included

Analysis and geological interpretation of gravity data from GEOS-3 altimeter

A number of detailed gravimetric geoids of portions of the world's oceans from marine gravity measurements were constructed. The geoids were constructed by computing 1 x 1 deg or 10 x 10 deg averages of free-air anomaly data and subtracting these values from currently used satellite derived Earth models. The resulting difference gravity anomalies are then integrated over a sphere using a simplified form of Stoke's equation to obtain a difference geoid. This difference geoid is added to the satellite derived model to obtain a 1 x 1 deg or 10 x 10 deg total gravimetric geoid. The geoid undulations are studied by comparison of the altimeter measurements with the morphology of the ocean floor. Utilizing a combination of altimetry data, gravity and seismic reflection data, geophysical models of the earth can be constructed

Imaging ionospheric inhomogeneities using spaceborne synthetic aperture radar

We present a technique and results of 2-D imaging of Faraday rotation and total electron content using spaceborne L band polarimetric synthetic aperture radar (PolSAR). The results are obtained by processing PolSAR data collected using the Phased Array type L-band Synthetic Aperture Radar (PALSAR) on board the Advanced Land Observation Satellite. Distinguished ionospheric inhomogeneities are captured in 2-D images from space with relatively high resolutions of hundreds of meters to a couple of kilometers in auroral-, middle-, and low-latitude regions. The observed phenomena include aurora-associated ionospheric enhancement arcs, the middle-latitude trough, traveling ionospheric disturbances, and plasma bubbles, as well as ionospheric irregularities. These demonstrate a new capability of spaceborne synthetic aperture radar that will not only provide measurements to correction of ionospheric effects in Earth science imagery but also significantly benefit ionospheric studies

Oral History Interview: A. B. Chapman

This interview is one of series conducted concerning the Oral History of Appalachia. Mr. Chapman was born in Lawrence County in Ironton, Ohio. He discusses: detailed information about his childhood and the town he grew up in; an anecdote about a dog stealing newspapers; an anecdote about his brother falling into a drop pit; as well as his employment history, including very detailed information about his apprenticeship as a blacksmith. It also contains an extra page describing Dutchman welding as shown for the top rail of a locomotive frame.https://mds.marshall.edu/oral_history/1092/thumbnail.jp

Squeezing out the last 1 nanometer of water: A detailed nanomechanical study

In this study, we present a detailed analysis of the squeeze-out dynamics of nanoconfined water confined between two hydrophilic surfaces measured by small-amplitude dynamic atomic force microscopy (AFM). Explicitly considering the instantaneous tip-surface separation during squeezeout, we confirm the existence of an adsorbed molecular water layer on mica and at least two hydration layers. We also confirm the previous observation of a sharp transition in the viscoelastic response of the nanoconfined water as the compression rate is increased beyond a critical value (previously determined to be about 0.8 nm/s). We find that below the critical value, the tip passes smoothly through the molecular layers of the film, while above the critical speed, the tip encounters "pinning" at separations where the film is able to temporarily order. Pre-ordering of the film is accompanied by increased force fluctuations, which lead to increased damping preceding a peak in the film stiffness once ordering is completed. We analyze the data using both Kelvin-Voigt and Maxwell viscoelastic models. This provides a complementary picture of the viscoelastic response of the confined water film

Using Proxies for the Short Rate: When are Three Months Like an Instant?

The dynamics of the unobservable "short" or "instantaneous" rate of interest are frequently estimated using a proxy variable. We show the biases resulting from this practice (the "proxy" problem) are related to the derivatives of the proxy with respect to the short rate and the (inverse) function from the proxy to the short rate. Analytic results show that the proxy problem is not economically significant for single- factor affine models, for parameter values consistent with US data. In addition, for the two-factor affine model of Longstaff and Schwartz (1992), the proxy problem is only economically significant for pricing discount bonds with maturities of more than 5 years. We also describe two different procedures which can be used to assess the magnitude of the proxy problem in more general interest rate models. Numerical evaluation of a nonlinear single-factor model suggests that the proxy problem can significantly affect both estimates of the diffusion function and discount bond prices.interest rates, proxies, term structure

Depth dependence of atomic mixing by ion beams

Ion backscattering spectrometry has been used to investigate the depth dependence of atomic mixing induced by ion beams. Samples consisting of a thin Pt (or Si) marker a few tens of angstroms thick buried at different depths in a deposited Si (or Pt) layer were bombarded with Xe+ of 300 keV at 2×10^16 cm^–2 dose and Ar+ of 150 keV at 5×10^15cm^–2 dose. Significant spreading of the marker was observed as a result of ion irradiation. The amount of spreading was measured as a function of depth of the marker, which was then compared with the deposited energy distribution. Measurements of this kind promise new insight into the nature of the interaction between ion beams and solids

Improving the Functional Control of Aged Ferroelectrics using Insights from Atomistic Modelling

We provide a fundamental insight into the microscopic mechanisms of the ageing processes. Using large scale molecular dynamics simulations of the prototypical ferroelectric material PbTiO3, we demonstrate that the experimentally observed ageing phenomena can be reproduced from intrinsic interactions of defect-dipoles related to dopant-vacancy associates, even in the absence of extrinsic effects. We show that variation of the dopant concentration modifies the material's hysteretic response. We identify a universal method to reduce loss and tune the electromechanical properties of inexpensive ceramics for efficient technologies.Comment: 6 pages, 3 figure

A sandpile model with tokamak-like enhanced confinement phenomenology

Confinement phenomenology characteristic of magnetically confined plasmas emerges naturally from a simple sandpile algorithm when the parameter controlling redistribution scalelength is varied. Close analogues are found for enhanced confinement, edge pedestals, and edge localised modes (ELMs), and for the qualitative correlations between them. These results suggest that tokamak observations of avalanching transport are deeply linked to the existence of enhanced confinement and ELMs.Comment: Manuscript is revtex (latex) 1 file, 7 postscript figures Revised version is final version accepted for publication in PRL Revisions are mino