Efficient Hardware Design Of Iterative Stencil Loops

A large number of algorithms for multidimensional signals processing and scientific computation come in the form of iterative stencil loops (ISLs), whose data dependencies span across multiple iterations. Because of their complex inner structure, automatic hardware acceleration of such algorithms is traditionally considered as a difficult task. In this paper, we introduce an automatic design flow that identifies, in a wide family of bidimensional data processing algorithms, sub-portions that exhibit a kind of parallelism close to that of ISLs; these are mapped onto a space of highly optimized ad-hoc architectures, which is efficiently explored to identify the best implementations with respect to both area and throughput. Experimental results show that the proposed methodology generates circuits whose performance is comparable to that of manually-optimized solutions, and orders of magnitude higher than those generated by commercial HLS tools

Synthesis and matrix properties of α-cyano-5-phenyl-2,4-pentadienic acid (CPPA) for intact proteins analysis by matrix-assisted laser desorption/ionization mass spectrometry

The effectiveness of a synthesized matrix, α-cyano-5-phenyl-2,4-pentadienic acid (CPPA), for protein analysis by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF MS) in complex samples such as foodstuff and bacterial extracts, is demonstrated. Ultraviolet (UV) absorption along with laser desorption/ionization mass spectrometry (LDI-MS) experiments were systematically conducted in positive ion mode under standard Nd:YLF laser excitation with the aim of characterizing the matrix in terms of wavelength absorption and proton affinity. Besides, the results for standard proteins revealed that CPPA significantly enhanced the protein signals, reduced the spot-to-spot variability and increased the spot homogeneity. The CPPA matrix was successful employed to investigate intact microorganisms, milk and seed extracts for protein profiling. Compared to conventional matrices such as sinapinic acid (SA), α-cyano-4-hydroxycinnamic acid (CHCA) and 4-chloro-α-cyanocinnamic acid (CClCA), CPPA exhibited better signal-to-noise (S/N) ratios and a uniform response for most examined proteins occurring in milk, hazelnut and in intact bacterial cells of E. coli. These findings not only provide a reactive proton transfer MALDI matrix with excellent reproducibility and sensitivity, but also contribute to extending the battery of useful matrices for intact protein analysis

Deep control of linear oligomerization of glycerol using lanthanum catalyst on mesoporous silica gel

The valorization of glycerol (1), a waste of biodiesel production of Fatty Acid Methyl Esters (FAMEs), adopting a “green” approach, represents an important goal of sustainable chemistry. While the polymerization of 1 to hyperbranched oligomers is a well-established process, the linear analogues are difficult to obtain. In this context, we explore the reaction without the solvent of heterogeneous hybrid La(III)O-KIT-6 catalyst (2), which is based on lanthanum oxide on mesoporous silica gel, showing a superior linear selectivity compared to most of the analogous catalysts recently reported

Valorization of cigarette butts for synthesis of levulinic acid as top value-added chemicals

Unprecedented in the literature, levulinic acid (LA), one of the top value-added intermediates of chemical industry, is obtained from cigarette butts as cellulose feedstock by means of a one-pot hydrothermal process carried out at 200 °C for 2 h and catalysed by phosphoric acid. The protocol avoids the use of more aggressive and toxic H2SO4 and HCl, that are generally employed on several cellulose sources (e.g. sludge paper), thus minimizing corrosion phenomena of plants. Neither chemical pre-treatment of butts nor specific purification procedure of LA are required. Notably, by simply modifying acid catalyst (e.g. using CH3COOH), another top value-added fine chemical such as 5-hydroxymethylfuraldehyde (HMF) is obtained, thus widening the scope of the method. Being cigarette filters a waste available in quantities of megatonnes per year, they represent an unlimited at no cost source of cellulose, thus enabling the up-scale to an industrial level of LA production

Consistent Posttest Calculations for LOCA Scenarios in LOBI Integral Facility

Integral test facilities (ITFs) are one of the main tools for the validation of best estimate thermalhydraulic system codes. The experimental data are also of great value when compared to the experiment-scaled conditions in a full NPP. The LOBI was a single plus a triple-loop (simulated by one loop) test facility electrically heated to simulate a 1300 MWe PWR. The scaling factor was 712 for the core power, volume, and mass flow. Primary and secondary sides contained all main active elements. Tests were performed for the characterization of phenomenologies relevant to large and small break LOCAs and special transients in PWRs. The paper presents the results of three posttest calculations of LOBI experiments. The selected experiments are BL-30, BL-44, and A1-84. They are LOCA scenarios of different break sizes and with different availability of safety injection components. The goal of the analysis is to improve the knowledge of the phenomena occurred in the facility in order to use it in further studies related to qualifying nodalizations of actual plants or to establish accuracy data bases for uncertainty methodologies. An example of procedure of implementing changes in a common nodalization valid for simulating tests occurred in a specific ITF is presented along with its confirmation based on posttests results