1,869 research outputs found
Dynamics of Spreading of Small Droplets of Chainlike Molecules on Surfaces
Dynamics of spreading of small droplets on surfaces has been studied by the
molecular dynamics method. Simulations have been performed for mixtures of
solvent and dimer, and solvent and tetramer droplets. For solvent particles and
dimers, layering occurs leading to stepped droplet shapes. For tetramers such
shapes occur for relatively deep and strong surface potentials only. For wider
and more shallow potentials, more rapid spreading and rounded droplet shapes
occur. These results are in accordance with experimental data on small non -
volatile polymer droplets. PACS numbers: 68.10Gw, 05.70.Ln, 61.20.Ja, 68.45GdComment: to appear in Europhys. Letters (1994), Latex, 12 page
Induced superconductivity in noncuprate layers of the BiSrCaCuO high-temperature superconductor: Modeling of scanning tunneling spectra
We analyze how the coherence peaks observed in Scanning Tunneling
Spectroscopy (STS) of cuprate high temperature superconductors are transferred
from the cuprate layer to the oxide layers adjacent to the STS microscope tip.
For this purpose, we have carried out a realistic multiband calculation for the
superconducting state of BiSrCaCuO (Bi2212) assuming a
short range d-wave pairing interaction confined to the nearest-neighbor Cu
orbitals. The resulting anomalous matrix elements of the Green's
function allow us to monitor how pairing is then induced not only within the
cuprate bilayer but also within and across other layers and sites. The symmetry
properties of the various anomalous matrix elements and the related selection
rules are delineated.Comment: 9 pages, 2 figures. Accepted for publication in Phys. Rev.
Origin of electron-hole asymmetry in the scanning tunneling spectrum of
We have developed a material specific theoretical framework for modelling
scanning tunneling spectroscopy (STS) of high temperature superconducting
materials in the normal as well as the superconducting state. Results for
(Bi2212) show clearly that the tunneling process
strongly modifies the STS spectrum from the local density of states (LDOS) of
the orbital of Cu. The dominant tunneling channel to the surface
Bi involves the orbitals of the four neighbouring Cu atoms. In
accord with experimental observations, the computed spectrum displays a
remarkable asymmetry between the processes of electron injection and
extraction, which arises from contributions of Cu and other orbitals
to the tunneling current.Comment: 5 pages, 4 figures, published in PR
Far-infrared spectra of lateral quantum dot molecules
We study effects of electron-electron interactions and confinement potential
on the magneto-optical absorption spectrum in the far-infrared range of lateral
quantum dot molecules. We calculate far-infrared (FIR) spectra for three
different quantum dot molecule confinement potentials. We use accurate exact
diagonalization technique for two interacting electrons and calculate
dipole-transitions between two-body levels with perturbation theory. We
conclude that the two-electron FIR spectra directly reflect the symmetry of the
confinement potential and interactions cause only small shifts in the spectra.
These predictions could be tested in experiments with nonparabolic quantum dots
by changing the number of confined electrons. We also calculate FIR spectra for
up to six noninteracting electrons and observe some additional features in the
spectrum.Comment: For better quality Figs download manuscript from
http://www.fyslab.hut.fi/~mma/FIR/Helle_qdmfir.ps.g
Towards efficient modelling of optical micromanipulation of complex structures
Computational methods for electromagnetic and light scattering can be used
for the calculation of optical forces and torques. Since typical particles that
are optically trapped or manipulated are on the order of the wavelength in
size, approximate methods such as geometric optics or Rayleigh scattering are
inapplicable, and solution or either the Maxwell equations or the vector
Helmholtz equation must be resorted to. Traditionally, such solutions were only
feasible for the simplest geometries; modern computational power enable the
rapid solution of more general--but still simple--geometries such as
axisymmetric, homogeneous, and isotropic scatterers. However, optically-driven
micromachines necessarily require more complex geometries, and their
computational modelling thus remains in the realm of challenging computational
problems. We review our progress towards efficient computational modelling of
optical tweezers and micromanipulation, including the trapping and manipulation
of complex structures such as optical micromachines. In particular, we consider
the exploitation of symmetry in the modelling of such devices.Comment: 5 pages, 4 figure
Circular dichroism of cholesteric polymers and the orbital angular momentum of light
We explore experimentally if the light's orbital angular momentum (OAM)
interacts with chiral nematic polymer films. Specifically, we measure the
circular dichroism of such a material using light beams with different OAM. We
investigate the case of strongly focussed, non-paraxial light beams, where the
spatial and polarization degrees of freedom are coupled. Within the
experimental accuracy, we cannot find any influence of the OAM on the circular
dichroism of the cholesteric polymer.Comment: 3 pages, 4 figure
Dynamics of Spreading of Chainlike Molecules with Asymmetric Surface Interactions
In this work we study the spreading dynamics of tiny liquid droplets on solid
surfaces in the case where the ends of the molecules feel different
interactions with respect to the surface. We consider a simple model of dimers
and short chainlike molecules that cannot form chemical bonds with the surface.
We use constant temperature Molecular Dynamics techniques to examine in detail
the microscopic structure of the time dependent precursor film. We find that in
some cases it can exhibit a high degree of local order that can persist even
for flexible chains. Our model also reproduces the experimentally observed
early and late-time spreading regimes where the radius of the film grows
proportional to the square root of time. The ratios of the associated transport
coefficients are in good overall agreement with experiments. Our density
profiles are also in good agreement with measurements on the spreading of
molecules on hydrophobic surfaces.Comment: 12 pages, LaTeX with APS macros, 21 figures available by contacting
[email protected], to appear in Phys. Rev.
Modelling optical micro-machines
A strongly focused laser beam can be used to trap, manipulate and exert
torque on a microparticle. The torque is the result of transfer of angular
momentum by scattering of the laser beam. The laser could be used to drive a
rotor, impeller, cog wheel or some other microdevice of a few microns in size,
perhaps fabricated from a birefringent material. We review our methods of
computationally simulating the torque and force imparted by a laser beam. We
introduce a method of hybridizing the T-matrix with the Finite Difference
Frequency Domain (FDFD) method to allow the modelling of materials that are
anisotropic and inhomogeneous, and structures that have complex shapes. The
high degree of symmetry of a microrotor, such as discrete or continuous
rotational symmetry, can be exploited to reduce computational time and memory
requirements by orders of magnitude. This is achieved by performing
calculations for only a given segment or plane that is repeated across the
whole structure. This can be demonstrated by modelling the optical trapping and
rotation of a cube.Comment: 4 pages, 3 figure
Optical application and measurement of torque on microparticles of isotropic nonabsorbing material
We show how it is possible to controllably rotate or align microscopic
particles of isotropic nonabsorbing material in a TEM00 Gaussian beam trap,
with simultaneous measurement of the applied torque using purely optical means.
This is a simple and general method of rotation, requiring only that the
particle is elongated along one direction. Thus, this method can be used to
rotate or align a wide range of naturally occurring particles. The ability to
measure the applied torque enables the use of this method as a quantitative
tool--the rotational equivalent of optical tweezers based force measurement. As
well as being of particular value for the rotation of biological specimens,
this method is also suitable for the development of optically-driven
micromachines.Comment: 8 pages, 6 figure
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