Immersed nano-sized Al dispersoids in an Al matrix; effects on the structural and mechanical properties by Molecular Dynamics simulations

We used molecular dynamics simulations based on a potential model in analogy to the Tight Binding scheme in the Second Moment Approximation to simulate the effects of aluminum icosahedral grains (dispersoids) on the structure and the mechanical properties of an aluminum matrix. First we validated our model by calculating several thermodynamic properties referring to the bulk Al case and we found good agreement with available experimental and theoretical data. Afterwards, we simulated Al systems containing Al clusters of various sizes. We found that the structure of the Al matrix is affected by the presence of the dispersoids resulting in well ordered domains of different symmetries that were identified using suitable Voronoi analysis. In addition, we found that the increase of the grain size has negative effect on the mechanical properties of the nanocomposite as manifested by the lowering of the calculated bulk moduli. The obtained results are in line with available experimental data.Comment: 15 pages, 8 figures. Submitted to J. Phys: Condens. Matte

Experiments on higher-order and degenerate Akhmediev breather-type rogue water waves

A possible mechanism that is responsible for the occurrence of rogue waves in the ocean is the Benjamin–Feir instability or modulation instability. The deterministic framework that describes this latter instability of Stokes waves in deep water is provided by the family of Akhmediev breather (AB) solutions of the nonlinear Schrödinger equation (NLS). It is indeed very convenient to use these exact pulsating envelopes particularly for laboratory experiments, since they allow to generate extreme waves at any location in space at any instant of time. As such, using this framework is more advantageous compared to the classical initialization of the unstable wave dynamics from a three wave system (main wave frequency and one pair of unstable sidebands). In this work, we report an experimental study on higher-order AB hydrodynamics that describe a higher-order stage of modulation instability, namely, starting from five wave systems (main wave frequency and two pairs of unstable sidebands). The corresponding laboratory experiments, that have been conducted in a large water wave facility, confirm the NLS wave dynamics forecast while boundary element method-based numerical wave tank simulations show a very good agreement with the experimental data.A.C. acknowledges the support from the Japan Society for the Promotion of Science (JSPS) and the Burgundy Region (France). A.C. and T.W. acknowledges the support from the Japan Society for the Promotion of Science (JSPS) through Grants-in-Aid for Scientific Research (KAKENHI). B.K. is thankful for support from French project PIA2/ISITE-BFC. N.A. acknowledges the support of the Australian Research Council (Discovery Project numbers DP140100265 and DP150102057) and support from the Volkswagen Stiftung

Exact limiting relation between the structure factors in neutron and x-ray scattering

The ratio of the static matter structure factor measured in experiments on coherent X-ray scattering to the static structure factor measured in experiments on neutron scattering is considered. It is shown theoretically that this ratio in the long-wavelength limit is equal to the nucleus charge at arbitrary thermodynamic parameters of a pure substance (the system of nuclei and electrons, where interaction between particles is pure Coulomb) in a disordered equilibrium state. This result is the exact relation of the quantum statistical mechanics. The experimental verification of this relation can be done in the long wavelength X-ray and neutron experiments.Comment: 7 pages, no figure

An accurate determination of the Avogadro constant by counting the atoms in a 28Si crystal

The Avogadro constant links the atomic and the macroscopic properties of matter. Since the molar Planck constant is well known via the measurement of the Rydberg constant, it is also closely related to the Planck constant. In addition, its accurate determination is of paramount importance for a definition of the kilogram in terms of a fundamental constant. We describe a new approach for its determination by "counting" the atoms in 1 kg single-crystal spheres, which are highly enriched with the 28Si isotope. It enabled isotope dilution mass spectroscopy to determine the molar mass of the silicon crystal with unprecedented accuracy. The value obtained, 6.02214084(18) x 10^23 mol^-1, is the most accurate input datum for a new definition of the kilogram.Comment: 4 pages, 5 figures, 3 table

Structural Stability of Amorphous Metals

Effects of annealing and plastic deformation on structure of several amorphous metals (Pd-Si, Fe-Si-B, Ni-Si-B, Co-Si-B, etc.) were examined by using dark-field electron microscopy, x-ray and electron diffraction, hardness, specific gravity and electrical resistivity. In T-T-T diagrams, distinct differences in transformation sequence were observed beyond and below the critical temperature. Above this temperature, crystallization proceeds through two metastable phases and finally to the stable phase by nucleation and growth mechanisms. Below the temperature, however, progressive aging gradually changes the structure through two stages ; the first stage is due to release of internal strain in the rapidly quenched specimens and the second stage due to transformation from amorphous to single phase with the same structure as the major element. Plastic deformation at room temperature produces a much more disordered atomic structure than is present in the as-quenched state perhaps by introducing additional irregularities

Persistent Oscillations of X-ray Speckles: Pt (001) Step Flow

We have performed coherent x-ray scattering experiments on the hexagonally reconstructed Pt (001) surface to study the temperature-dependent surface dynamics. By correlating speckle patterns collected at the (001) anti-Bragg position we are able to measure surface dynamics when the averaged incoherent x-ray scattering appears static. In the temperature range above the rotational epitaxy transition and below the roughening transition (1750 K - 1830 K), we have observed well-defined oscillatory autocorrelations of speckles that persist for tens of minutes, in addition to the expected thermal decorrelation. The observed oscillations indicate surface dynamics due to "step-flow" motion. This is shown with a simple model in which the phase of the scattered x-rays from the steps within the illumination area is retained in the coherent x-ray scattering. This demonstrates a possibility that x-ray speckles can be used to monitor the real-space real-time evolution of surfaces in addition to the traditional decorrelation measurements.Comment: 12 pages, 3 figure

Peak positions and shapes in neutron pair correlation functions from powders of highly anisotropic crystals

The effect of the powder average on the peak shapes and positions in neutron pair distribution functions of polycrystalline materials is examined. It is shown that for highly anisotropic crystals, the powder average leads to shifts in peak positions and to non-Gaussian peak shapes. The peak shifts can be as large as several percent of the lattice spacing

Structural and dynamical properties of liquid Si. An orbital-free molecular dynamics study

Several static and dynamic properties of liquid silicon near melting have been determined from an orbital free {\em ab-initio} molecular dynamics simulation. The calculated static structure is in good agreement with the available X-ray and neutron diffraction data. The dynamical structure shows collective density excitations with an associated dispersion relation which closely follows recent experimental data. It is found that liquid silicon can not sustain the propagation of shear waves which can be related to the power spectrum of the velocity autocorrelation function. Accurate estimates have also been obtained for several transport coefficients. The overall picture is that the dynamic properties have many characteristics of the simple liquid metals although some conspicuous differences have been found.Comment: 12 pages, 11 figure

Measurement of the mechanical loss of a cooled reflective coating for gravitational wave detection

We have measured the mechanical loss of a dielectric multilayer reflective coating (ion-beam sputtered SiO$_2$ and Ta$_2$O$_5$) in cooled mirrors. The loss was nearly independent of the temperature (4 K $\sim$ 300 K), frequency, optical loss, and stress caused by the coating, and the details of the manufacturing processes. The loss angle was $(4 \sim 6) \times 10^{-4}$. The temperature independence of this loss implies that the amplitude of the coating thermal noise, which is a severe limit in any precise measurement, is proportional to the square root of the temperature. Sapphire mirrors at 20 K satisfy the requirement concerning the thermal noise of even future interferometric gravitational wave detector projects on the ground, for example, LCGT.Comment: 8 pages, 6 figures, 3 tables : accepted version (by Physical Review D