Temperature oscillations of magnetization observed in nanofluid ferromagnetic graphite

We report on unusual magnetic properties observed in the nanofluid room-temperature ferromagnetic graphite (with an average particle size of l=10nm). More precisely, the measured magnetization exhibits a low-temperature anomaly (attributed to manifestation of finite size effects below the quantum temperature) as well as pronounced temperature oscillations above T=50K (attributed to manifestation of the hard-sphere type pair correlations between ferromagnetic particles in the nanofluid)

Tetra­kis[μ-2-(3-phenoxy­phen­yl)propionato-κ2 O:O′]bis­[(dimethyl­formamide-κO)copper(II)]

The title compound, [Cu2(C15H13O3)4(C3H7NO)2], is formed by the chelate coordination of four racemic fenoprofenate (fenoprofenate is 2,3-phenoxyphenyl propionate) anions and two dimethyl­formamide mol­ecules to two copper(II) ions, building a paddle-wheel dinuclear mol­ecule. The distorted square-pyramidal coordination of each CuII atom is made up of four O atoms of the four fenoprofenate units and another O atom from a dimethyl­formamide mol­ecule. The two enanti­omeric forms of the fenoprofenate anions are present in the complex, in an optically inactive centrosymmetric arrangement

Manifestation of finite temperature size effects in nanogranular magnetic graphite

In addition to the double phase transition (with the Curie temperatures T_C=300K and T_{Ct}=144K), a low-temperature anomaly in the dependence of the magnetization is observed in the bulk magnetic graphite (with an average granular size of L=10nm), which is attributed to manifestation of the size effects below the quantum temperature. The best fits of the high-temperature data (using the mean-field Curie-Weiss and Bloch expressions) produced reasonable estimates for the model parameters, such as defects mediated effective spin exchange energy J=12meV (which defines the intragranular Curie temperature T_C) and proximity mediated interactions between neighboring grains (through potential barriers created by thin layers of non-magnetic graphite) with energy J_t=exp(-d/s)J=5.8meV (which defines the intergranular Curie temperature T_{Ct}) with d=1.5nm and s=2nm being the intergranular distance and characteristic length, respectively

Mechanical properties of Graphene Nanoribbons

Herein, we investigate the structural, electronic and mechanical properties of zigzag graphene nanoribbons upon the presence of stress applying Density Functional Theory within the GGA-PBE approximation. The uniaxial stress is applied along the periodic direction, allowing a unitary deformation in the range of +/- 0.02%. The mechanical properties show a linear-response within that range while the non-linear dependence is found for higher strain. The most relevant results indicate that Young's modulus is considerable higher than those determined for graphene and carbon nanotubes. The geometrical reconstruction of the C-C bonds at the edges hardness the nanostructure. Electronic structure features are not sensitive to strain in this linear elastic regime, being an additional promise for the using of carbon nanostructures in nano-electronic devices in the near future.Comment: 30 pages. J. Phys.: Condens. Matter (accepted

Ferromagnetism in graphene nanoribbons: split versus oxidative unzipped ribbons

Two types of graphene nanoribbons: (a) potassium-split graphene nanoribbons (GNRs), and (b) oxidative unzipped and chemically converted graphene nanoribbons (CCGNRs) were investigated for their magnetic properties using the combination of static magnetization and electron spin resonance measurements. The two types of ribbons possess remarkably different magnetic properties. While the low temperature ferromagnet-like feature is observed in both types of ribbons, such room temperature feature persists only in potassium-split ribbons. The GNRs show negative exchange bias, but the CCGNRs exhibit a 'positive exchange bias'. Electron spin resonance measurements infer that the carbon related defects may responsible for the observed magnetic behaviour in both types of ribbons. Furthermore, proton hyperfine coupling strength has been obtained from hyperfine sublevel correlation experiments performed on the GNRs. Electron spin resonance provides no indications for the presence of potassium (cluster) related signals, emphasizing the intrinsic magnetic nature of the ribbons. Our combined experimental results may infer the coexistence of ferromagnetic clusters with anti-ferromagnetic regions leading to disordered magnetic phase. We discuss the origin of the observed contrast in the magnetic behaviours of these two types of ribbons