Oxidative alkylation of (η5-C5Me5)2TiR (R = Cl, Me, Et, CH=CH2, Ph, OMe, N=C(H)tBu) to (η5-C5Me5)2Ti(Me)R by group 12 organometallic compounds MMe2

Oxidative alkylation of Cp*2TiX (Cp*: η5-C5Me5; X = OMe, Cl, N=C(H)tBu) and Cp* 2TiMe by CdMe2 or ZnMe2 gives diamagnetic Cp*2Ti(Me)X and Cp*2TiMe2 respectively, and cadmium or zinc. The reactions of Cp*2TiR (R = Et, CH=CH2, Ph) with MMe2 (M = Cd, Zn) give statistical mixtures of Cp*2Ti(Me)R, Cp*2TiMe2 and Cp*2TiR2. Dimethylmercury does not react with Cp*2TiX.

The Destruction of Bars by Central Mass Concentrations

More than two thirds of disk galaxies are barred to some degree. Many today harbor massive concentrations of gas in their centers, and some are known to possess supermassive black holes (SMBHs) and their associated stellar cusps. Previous theoretical work has suggested that a bar in a galaxy could be dissolved by the formation of a mass concentration in the center, although the precise mass and degree of central concentration required is not well-established. We report an extensive study of the effects of central masses on bars in high-quality N-body simulations of galaxies. We have varied the growth rate of the central mass, its final mass and degree of concentration to examine how these factors affect the evolution of the bar. Our main conclusions are: (1) Bars are more robust than previously thought. The central mass has to be as large as several percent of the disk mass to completely destroy the bar on a short timescale. (2) For a given mass, dense objects cause the greatest reduction in bar amplitude, while significantly more diffuse objects have a lesser effect. (3) The bar amplitude always decreases as the central mass is grown, and continues to decay thereafter on a cosmological time-scale. (4) The first phase of bar-weakening is due to the destruction by the CMC of lower-energy, bar-supporting orbits, while the second phase is a consequence of secular changes to the global potential which further diminish the number of bar-supporting orbits. We provide detailed phase-space and orbit analysis to support this suggestion. Thus current masses of SMBHs are probably too small, even when dressed with a stellar cusp, to affect the bar in their host galaxies. The molecular gas concentrations found in some barred galaxies are also too diffuse to affect the amplitude of the bar significantly.Comment: AASTeX v5.0 preprint; 44 pages, including 1 table and 16 figures. To appear in ApJ. High resolution version can be found at http://www.physics.rutgers.edu/~shen/bar_destruct/paper_high_res.pd

CO(J = 1-0) Imaging of M51 with CARMA and the Nobeyama 45 m Telescope

We report the CO(J = 1-0) observations of the Whirlpool Galaxy M51 using both the Combined Array for Research in Millimeter Astronomy (CARMA) and the Nobeyama 45 m telescope (NRO45). We describe a procedure for the combination of interferometer and single-dish data. In particular, we discuss (1) the joint imaging and deconvolution of heterogeneous data, (2) the weighting scheme based on the root-mean-square (rms) noise in the maps, (3) the sensitivity and uv coverage requirements, and (4) the flux recovery of a combined map. We generate visibilities from the single-dish map and calculate the noise of each visibility based on the rms noise. Our weighting scheme, though it is applied to discrete visibilities in this paper, should be applicable to grids in uv space, and this scheme may advance in future software development. For a realistic amount of observing time, the sensitivities of the NRO45 and CARMA visibility data sets are best matched by using the single-dish baselines only up to 4-6 kλ (about 1/4-1/3 of the dish diameter). The synthesized beam size is determined to conserve the flux between the synthesized beam and convolution beam. The superior uv coverage provided by the combination of CARMA long baseline data with 15 antennas and NRO45 short spacing data results in the high image fidelity, which is evidenced by the excellent overlap between even the faint CO emission and dust lanes in an optical Hubble Space Telescope image and polycyclicaromatichydrocarbon emission in a Spitzer 8 μm image. The total molecular gas masses of NGC 5194 and 5195 (d = 8.2 Mpc) are 4.9 × 10^9 M_⊙ and 7.8 × 10^7 M_⊙, respectively, assuming the CO-to-H_2 conversion factor of X _(CO) = 1.8 × 10^(20) cm-2(K km s^(–1))^(–1). The presented images are an indication of the millimeter-wave images that will become standard in the next decade with CARMA and NRO45, and the Atacama Large Millimeter/Submillimeter Array

A highly efficient titanium-based olefin polymerisation catalyst with a monoanionic iminoimidazolidide pi-donor ancillary ligand

The titanium complex Cp[1,3-(2',6' Me2C6H3) (2)(CH2N)(2)C=N] Ti(CH2Ph)(2), with a monoanionic eta(1)-iminoimidazolidide ancillary ligand, is shown to be a highly efficient catalyst for olefin polymerisation when activated with the Lewis acid B(C6F5)(3)

Bar Diagnostics in Edge-On Spiral Galaxies. II. Hydrodynamical Simulations

We develop diagnostics based on gas kinematics to identify the presence of a bar in an edge-on spiral galaxy and determine its orientation. We use position-velocity diagrams (PVDs) obtained by projecting edge-on two-dimensional hydrodynamical simulations of the gas flow in a barred galaxy potential. We show that when a nuclear spiral is formed, the presence of a gap in the PVDs, between the signature of the nuclear spiral and that of the outer parts of the disk, reliably indicates the presence of a bar. This gap is due to the presence of shocks and inflows in the simulations, leading to a depletion of the gas in the outer bar region. If no nuclear spiral signature is present in a PVD, only indirect arguments can be used to argue for the presence of a bar. The shape of the signature of the nuclear spiral, and to a lesser extent that of the outer bar region, allows to determine the orientation of the bar with respect to the line-of-sight. The presence of dust can also help to discriminate between viewing angles on either side of the bar. Simulations covering a large fraction of parameter space constrain the bar properties and mass distribution of observed galaxies. The strongest constraint comes from the presence or absence of the signature of a nuclear spiral in the PVD.Comment: 25 pages (AASTeX, aaspp4.sty), 11 jpg figures. Accepted for publication in The Astrophysical Journal. Online manuscript with PostScript figures available at: http://www.strw.leidenuniv.nl/~bureau/pub_list.htm

The Galactic centre mini-spiral in the mm-regime

The mini-spiral is a feature of the interstellar medium in the central ~2 pc of the Galactic center. It is composed of several streamers of dust and ionised and atomic gas with temperatures between a few 100 K to 10^4 K. There is evidence that these streamers are related to the so-called circumnuclear disk of molecular gas and are ionized by photons from massive, hot stars in the central parsec. We attempt to constrain the emission mechanisms and physical properties of the ionized gas and dust of the mini-spiral region with the help of our multiwavelength data sets. Our observations were carried out at 1.3 mm and 3 mm with the mm interferometric array CARMA in California in March and April 2009, with the MIR instrument VISIR at ESO's VLT in June 2006, and the NIR Br-gamma with VLT NACO in August 2009. We present high resolution maps of the mini-spiral, and obtain a spectral index of 0.5 for Sgr A*, indicating an inverted synchrotron spectrum. We find electron densities within the range 0.8-1.5x10^4 cm-3 for the mini-spiral from the radio continuum maps, along with a dust mass contribution of ~0.25 solar masses from the MIR dust continuum, and extinctions ranging from 1.8-3 at 2.16 micron in the Br-gamma line. We observe a mixture of negative and positive spectral indices in our 1.3 mm and 3 mm observations of the extended emission of the mini-spiral, which we interpret as evidence that there are a range of contributions to the thermal free-free emission by the ionized gas emission and by dust at 1.3 mm.Comment: 9 pages, 11 figures, accepted to A&

Athena: A New Code for Astrophysical MHD

A new code for astrophysical magnetohydrodynamics (MHD) is described. The code has been designed to be easily extensible for use with static and adaptive mesh refinement. It combines higher-order Godunov methods with the constrained transport (CT) technique to enforce the divergence-free constraint on the magnetic field. Discretization is based on cell-centered volume-averages for mass, momentum, and energy, and face-centered area-averages for the magnetic field. Novel features of the algorithm include (1) a consistent framework for computing the time- and edge-averaged electric fields used by CT to evolve the magnetic field from the time- and area-averaged Godunov fluxes, (2) the extension to MHD of spatial reconstruction schemes that involve a dimensionally-split time advance, and (3) the extension to MHD of two different dimensionally-unsplit integration methods. Implementation of the algorithm in both C and Fortran95 is detailed, including strategies for parallelization using domain decomposition. Results from a test suite which includes problems in one-, two-, and three-dimensions for both hydrodynamics and MHD are given, not only to demonstrate the fidelity of the algorithms, but also to enable comparisons to other methods. The source code is freely available for download on the web.Comment: 61 pages, 36 figures. accepted by ApJ