2-{[4-(Diethyl­amino)­phen­yl]imino­methyl}-4,6-diiodo­phenol

In the title compound, C17H18I2N2O, the dihedral angle between the aromatic rings is 5.4 (1)°. An intra­molecular O—H⋯N hydrogen bond generates an S(6) ring motif. The crystal packing is stabilized by C—H⋯π and π–π inter­actions [centroid–centroid distance = 3.697 (1) Å]

Diethyl 2-{[3-(2-meth­oxy­benz­yl)thio­phen-2-yl]methyl­idene}malonate

In the title compound, C20H22O5S, the dihedral angle between the mean planes through the thio­phene and benzene rings is 75.2 (1)°. The meth­oxy group is essentially coplanar with the benzene ring, the largest deviation from the mean plane being 0.019 (2) Å for the O atom. The malonate group assumes an extended conformation

Amino­guanidinium hydrogen succinate

The title compound, CH7N4 +·C4H5O4 −, is a molecular salt containing discrete amino­guanidinium and succinate ions. The amino­guanidinium cation is nearly planar, with a maximum deviation of 0.035 (1) Å. The dihedral angle between the amino­guanidinium cation and the succinate anion is 3.35 (6)°. The crystal packing exhibits inter­molecular N—H⋯O and O—H⋯·O hydrogen bonds

Antimicrobial nature of specific compounds of Ampelomyces quisqualis identified from gas chromatography-mass spectrometry (GCMS) analysis and their mycoparasite nature against powdery mildew of grapes

Grapevine powdery mildew is the world's most important plant disease, and Ampelomyces frequently fight them. While it does not usually cause plant death, its major infections can result in significant production losses and severely impact wine quality. Fungicides are frequently used to control the disease, which can have long-term adverse effects on the ecosystem. As a result, alternative and environmentally friendly disease management approaches must be developed. The study aimed to reduce costly and toxic fungicide use by using Ampelomyces, a natural biofungicide, against various powdery mildew fungi. GC-MS analysis was also used to determine the antagonistic potential and efficacy of volatile organic chemicals produced by several Ampelomyces spp. against Erysiphe necator, which causes powdery mildew of grapes. The molecular characterization of A. quisqualis isolates based on using rDNA ITS region was also carried out and sequenced. GC-MS analysis identified various antimicrobial compounds, such as squalene (4.643%), octadecanoic acid (3.862%), tetradecanoic acid (3.600%), and 9,12-octadecadienoic acid (Z,Z) (1.451%). The least abundant compounds were 2-Hexadecanol, 1-Tricosanol, and 2-propenyl ester, with percentages of 0.485, 0.519, and 0.560, respectively. These bioactive compounds revealed by GC-MS analysis in crude extracts of A. quisqualis had a stronger antifungal and antibacterial activity against E. necator. As a result, using A. quisqualis to control the powdery mildew of grapes significantly reduced pathogen growth and disease incidence