2,918 research outputs found
Dielectric Metamaterials with Toroidal Dipolar Response
Toroidal multipoles are the terms missing in the standard multipole
expansion; they are usually overlooked due to their relatively weak coupling to
the electromagnetic fields. Here we propose and theoretically study
all-dielectric metamaterials of a special class that represent a simple
electromagnetic system supporting toroidal dipolar excitations in the THz part
of the spectrum. We show that resonant transmission and reflection of such
metamaterials is dominated by toroidal dipole scattering, the neglect of which
would result in a misunderstanding interpretation of the metamaterials
macroscopic response. Due to the unique field configuration of the toroidal
mode the proposed metamaterials could serve as a platform for sensing, or
enhancement of light absorption and optical nonlinearities
Noninvasive Embedding of Single Co Atoms in Ge(111)2x1 Surfaces
We report on a combined scanning tunneling microscopy (STM) and density
functional theory (DFT) based investigation of Co atoms on Ge(111)2x1 surfaces.
When deposited on cold surfaces, individual Co atoms have a limited diffusivity
on the atomically flat areas and apparently reside on top of the upper
pi-bonded chain rows exclusively. Voltage-dependent STM imaging reveals a
highly anisotropic electronic perturbation of the Ge surface surrounding these
Co atoms and pronounced one-dimensional confinement along the pi-bonded chains.
DFT calculations reveal that the individual Co atoms are in fact embedded in
the Ge surface, where they occupy a quasi-stationary position within the big
7-member Ge ring in between the 3rd and 4th atomic Ge layer. The energy needed
for the Co atoms to overcome the potential barrier for penetration in the Ge
surface is provided by the kinetic energy resulting from the deposition
process. DFT calculations further demonstrate that the embedded Co atoms form
four covalent Co-Ge bonds, resulting in a Co4+ valence state and a 3d5
electronic configuration. Calculated STM images are in perfect agreement with
the experimental atomic resolution STM images for the broad range of applied
tunneling voltages.Comment: 19 pages, 15 figures, 3 table
In situ visualization of Ni-Nb bulk metallic glasses phase transition
We report the results of the Ni-based bulk metallic glass structural
evolution and crystallization behavior in situ investigation. The X-ray
diffraction (XRD), transmission electron microscopy (TEM), nano-beam
diffraction (NBD), differential scanning calorimetry (DSC), radial distribution
function (RDF) and scanning probe microscopy/spectroscopy (STM/STS) techniques
were applied to analyze the structure and electronic properties of Ni63.5Nb36.5
glasses before and after crystallization. It was proved that partial surface
crystallization of Ni63.5Nb36.5 can occur at the temperature lower than for the
full sample crystallization. According to our STM measurements the primary
crystallization is originally starting with the Ni3Nb phase formation. It was
shown that surface crystallization drastically differs from the bulk
crystallization due to the possible surface reconstruction. The mechanism of
Ni63.5Nb36.5 glass alloy 2D-crystallization was suggested, which corresponds to
the local metastable (3x3)-Ni(111) surface phase formation. The possibility of
different surface nano-structures development by the annealing of the
originally glassy alloy in ultra high vacuum at the temperature lower, than the
crystallization temperature was shown. The increase of mean square surface
roughness parameter Rq while moving from glassy to fully crystallized state can
be caused by concurrent growth of Ni3Nb and Ni6Nb7 bulk phases. The simple
empirical model for the estimation of Ni63.5Nb36.5 cluster size was suggested,
and the obtained values (7.64 A, 8.08 A) are in good agreement with STM
measurements data (8 A-10 A)
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