Determination of Grain-Size Distributions from Ultrasonic Attenuation

The overall research goal of this project is the nondestructive measurement of grain-size distribution parameters using ultrasonic attenuation. Ultrasonic attenuation α is dependent upon the sound wavelength (λ), the size of the grains (D), and in many cases elastic constants and sound velocities of the material. Assuming that multiple scattering can be ignored, the expression for the wavelength dependence of the attenuation is 1 α(λ)=∫0∞N(D)α(λ,D)dD where N(D) is the grain-size distribution. In previous work [1] the sizes were assumed to be distributed following a power-law with exponent γ: 2 N(D)=KD−γ,

Artificial Intelligence for the Management of Servitization 5.0

Purpose-The sale of physical products has been manufacturing companies' main revenue source. A trend is known as servitization for earning revenue comes from services. With the convergence of servitization and digitization, many manufacturing organizations are undergoing digital servitization. In parallel, the digitization of industry is pushing new technological solutions to the top of the business agenda. Artificial intelligence can play a substantial role in this digital business transformation. This evolution is referred to in this paper as Servitization 5.0 and requires substantial changes. Aim-This paper explores the applications of artificial intelligence to Servitization 5.0 strategies and its role, particularly in changing organizations to EverythiA.I.ng as a Service. The paper underlines the contribution that A.I. can provide in moving to a human-centric, sustainable, and resilient servitization. Method used-The basis of the work is a literature review supported by information collected from business case studies by the authors. A follow-up study defined the models. The validity of the model was tested by collecting ten experts' opinions who currently work within servitization contracts sessions. Findings-For manufacturing companies, selling services requires completely different business models. In this situation, it is essential to consider advanced solutions to support these new business models. Artificial Intelligence can make it possible. On the inter-organizational side, empirical evidence also points to the support of A.I. in collaborating with ecosystems to support sustainability and resilience, as requested by Industry 5.0. Original value-Regarding theoretical implications, this paper contributes to interdisciplinary research in corporate marketing and operational servitization. It is part of the growing literature that deals with the applications of artificial intelligence-based solutions in different areas of organizational management. The approach is interesting because it highlights that digital solutions require an integrated business model approach. It is necessary to implement the technological platform with appropriate processes, people, and partners (the four Ps). The outcome of this study can be generalized for industries in high-value manufacturing. Implications-As implications for management, this paper defines how to organize the structure and support for Servitization 5.0 and how to work with the external business environment to support sustainability

Talaromyces–insect relationships

Facing the urgent need to reduce the input of agrochemicals, in recent years, the ecological relationships between plants and their associated microorganisms have been increasingly considered as an essential tool for improving crop production. New findings and data have been accumulated showing that the application of fungi can go beyond the specific role that has been traditionally assigned to the species, employed in integrated pest management as entomopathogens or mycopara-sites, and that strains combining both aptitudes can be identified and possibly used as multipurpose biocontrol agents. Mainly considered for their antagonistic relationships with plant pathogenic fungi, species in the genus Talaromyces have been more and more widely reported as insect associates in investigations carried out in various agricultural and non-agricultural contexts. Out of a total of over 170 species currently accepted in this genus, so far, 27 have been found to have an association with insects from 9 orders, with an evident increasing trend. The nature of their mutualistic and antagonistic relationships with insects, and their ability to synthesize bioactive compounds possibly involved in the expression of the latter kind of interactions, are analyzed in this paper with reference to the ecological impact and applicative perspectives in crop protection

Anomalous relaxation kinetics and charge density wave correlations in underdoped BaPb1-xBixO3

Superconductivity often emerges in proximity of other symmetry-breaking ground states, such as antiferromagnetism or charge-density-wave (CDW) order. However, the subtle inter-relation of these phases remains poorly understood, and in some cases even the existence of short-range correlations for superconducting compositions is uncertain. In such circumstances, ultrafast experiments can provide new insights, by tracking the relaxation kinetics following excitation at frequencies related to the broken symmetry state. Here, we investigate the transient terahertz conductivity of BaPb1-xBixO3 - a material for which superconductivity is adjacent to a competing CDW phase - after optical excitation tuned to the CDW absorption band. In insulating BaBiO3 we observed an increase in conductivity and a subsequent relaxation, which are consistent with quasiparticles injection across a rigid semiconducting gap. In the doped compound BaPb0.72Bi0.28O3 (superconducting below Tc=7K), a similar response was also found immediately above Tc. This observation evidences the presence of a robust gap up to T=40 K, which is presumably associated with short-range CDW correlations. A qualitatively different behaviour was observed in the same material fo T>40 K. Here, the photo-conductivity was dominated by an enhancement in carrier mobility at constant density, suggestive of melting of the CDW correlations rather than excitation across an optical gap. The relaxation displayed a temperature dependent, Arrhenius-like kinetics, suggestive of the crossing of a free-energy barrier between two phases. These results support the existence of short-range CDW correlations above Tc in underdoped BaPb1-xBixO3, and provide new information on the dynamical interplay between superconductivity and charge order.Comment: 19 pages, 4 figure

Magnetic-Field Tuning of Light-Induced Superconductivity in Striped La2−x_{2-x}Bax_xCuO4_4

Optical excitation of stripe-ordered La$_{2-x}$Ba$_x$CuO$_4$ has been shown to transiently enhance superconducting tunneling between the CuO$_2$ planes. This effect was revealed by a blue-shift, or by the appearance of a Josephson Plasma Resonance in the terahertz-frequency optical properties. Here, we show that this photo-induced state can be strengthened by the application of high external magnetic fields oriented along the c-axis. For a 7-Tesla field, we observe up to a ten-fold enhancement in the transient interlayer phase correlation length, accompanied by a two-fold increase in the relaxation time of the photo-induced state. These observations are highly surprising, since static magnetic fields suppress interlayer Josephson tunneling and stabilize stripe order at equilibrium. We interpret our data as an indication that optically-enhanced interlayer coupling in La$_{2-x}$Ba$_x$CuO$_4$ does not originate from a simple optical melting of stripes, as previously hypothesized. Rather, we speculate that the photo-induced state may emerge from activated tunneling between optically-excited stripes in adjacent planes.Comment: 35 pages, 13 figure

Mild behavioral impairment in Parkinson's disease: Data from the Parkinson's disease cognitive impairment study (PACOS)

Neuropsychiatric symptoms (NPS) have been frequently described in Parkinson's disease (PD), even in the earliest stages of the disease. Recently the construct of mild behavioral impairment (MBI) has been proposed as an at-risk state for incident cognitive decline and dementia. The aim of the present study is to evaluate the prevalence and associated factors of MBI in PD. Cross-sectional data from 429 consecutive PD patients enrolled in the PArkinson's disease COgnitive impairment Study (PACOS) were included in the study. All subjects underwent neuropsychological assessment, according to the MDS Level II criteria. NPS were evaluated with the Neuropsychiatric Inventory. Multivariate logistic regression models were used to evaluate clinical and behavioral characteristics, which are associated with PD-MBI. The latter was ascertained in 361 (84.1%) subjects of whom 155 (36.1%) were newly diagnosed patients (disease duration ≥1 year) and 206 (48.0%) had a disease duration <1 year. Furthermore, 68 (15.9%) out of 429 subjects were PDw (without MBI). Across the MBI domains, Impulse Dyscontrol was significantly more prevalent among PD-MBI with disease duration <1 year than newly diagnosed patients. The frequency of Social Inappropriateness and Abnormal Perception significantly increased throughout the entire PD-MBI sample with increasing Hoehn andYahr (H&Y) stages. PD-MBI in newly diagnosed PDwas significantly associated with H&Y stage (OR 2.35, 95% CI 1.05-5.24) and marginally with antidepressant drug use (OR 2.94, 95% CI 0.91-9.47), while in patients with a disease duration >1 year was associated with UPDRS-ME (OR 3.37, 95% CI 1.41-8.00). The overall MBI frequency in the PACOS sample was 84% and 36% among newly diagnosed patients. The presence of MBI mainly related to motor impairment and disability

Measles in Italy: Viral strains and crossing borders.

In 2017, Italy experienced one of the largest outbreaks of measles in recent years, with 5404 notified cases and 4347 confirmed cases. A further 2029 cases were notified during the first 6 months of 2018, and 1516 of them were laboratory-confirmed. The B3 and D8 genotypes were identified as those responsible for the outbreak. Possible transmission routes can be established by monitoring the circulating measles virus strains in support of the national health authorities to warn people and travellers

Pressure tuning of light-induced superconductivity in K3C60

Optical excitation at terahertz frequencies has emerged as an effective means to manipulate complex solids dynamically. In the molecular solid K3C60, coherent excitation of intramolecular vibrations was shown to transform the high temperature metal into a non-equilibrium state with the optical conductivity of a superconductor. Here we tune this effect with hydrostatic pressure, and we find it to disappear around 0.3 GPa. Reduction with pressure underscores the similarity with the equilibrium superconducting phase of K3C60, in which a larger electronic bandwidth is detrimental for pairing. Crucially, our observation excludes alternative interpretations based on a high-mobility metallic phase. The pressure dependence also suggests that transient, incipient superconductivity occurs far above the 150 K hypothesised previously, and rather extends all the way to room temperature.Comment: 33 pages, 17 figures, 2 table

Pump frequency resonances for light-induced incipient superconductivity in YBa2_2Cu3_3O6.5_{6.5}

Optical excitation in the cuprates has been shown to induce transient superconducting correlations above the thermodynamic transition temperature, $T_C$, as evidenced by the terahertz frequency optical properties in the non-equilibrium state. In YBa$_2$Cu$_3$O$_{6+x}$ this phenomenon has so far been associated with the nonlinear excitation of certain lattice modes and the creation of new crystal structures. In other compounds, like La$_{2-x}$Ba$_x$CuO$_4$, similar effects were reported also for excitation at near infrared frequencies, and were interpreted as a signature of the melting of competing orders. However, to date it has not been possible to systematically tune the pump frequency widely in any one compound, to comprehensively compare the frequency dependent photo-susceptibility for this phenomenon. Here, we make use of a newly developed optical parametric amplifier, which generates widely tunable high intensity femtosecond pulses, to excite YBa$_2$Cu$_3$O$_{6.5}$ throughout the entire optical spectrum (3 - 750 THz). In the far-infrared region (3 - 25 THz), signatures of non-equilibrium superconductivity are induced only for excitation of the 16.4 THz and 19.2 THz vibrational modes that drive $c$-axis apical oxygen atomic positions. For higher driving frequencies (25 - 750 THz), a second resonance is observed around the charge transfer band edge at ~350 THz. These observations highlight the importance of coupling to the electronic structure of the CuO$_2$ planes, either mediated by a phonon or by charge transfer.Comment: 47 pages, 21 figures, 2 table

Cryptic diversity in Cladosporium cladosporioides resulting from sequence-based species delimitation analyses

Cladosporium cladosporioides is an extremely widespread fungus involved in associations ranging from mutualistic to pathogenic and is the most frequently represented Cladosporium species in sequence databases, such as Genbank. The taxonomy of Cladosporium species, currently based on the integration of molecular data with morphological and cultural characters, is in frequent need of revision. Hence, the recently developed species delimitation methods can be helpful to explore cryptic diversity in this genus. Considering a previous study that reported several hypothetical species within C. cladosporioides, we tested four methods of species delimitation using the combined DNA barcodes internal transcribed spacers, translation elongation factor 1-α and actin 1. The analyses involved 105 isolates, revealing that currently available sequences of C. cladosporioides in GenBank actually represent more than one species. Moreover, we found that eight isolates from this set should be ascribed to Cladosporium anthropophilum. Our results revealed a certain degree of discordance among species delimitation methods, which can be efficiently treated using conservative approaches in order to minimize the risk of considering false positives