21,880 research outputs found
The Thermal degradation of Bisphenol A Polycarbonate in Air
The thermal degradation of polycarbonate in air was studied as a function of mass loss using TGA/FTIR, GC/MS and LC/MS. In the main degradation region, 480–560 °C, the assigned structures of smaller molecules and linear molecules that evolved in air were very similar to those obtained from the degradation in nitrogen; the degradation of polycarbonate follows chain scission of the isopropylidene linkage, in agreement with the bond dissociation energies, and hydrolysis/alcoholysis of carbonate linkage. Compared to the degradation in nitrogen, some differences were observed primarily in the beginning stage of degradation. Oxygen may facilitate branching as well as radical formation via the formation of peroxides. These peroxides undergo further dissociations and combinations, producing aldehydes, ketones and some branched structures, mainly in the beginning stage of degradation. It is speculated that the intermediate char formed in the beginning due to branching reactions of peroxide interferes with the mass transfer through the surface of degrading polycarbonate in the main degradation. Thus, even though the mass loss begins earlier in air, a slower mass loss rate is observed
The Effects Of Triphenylphosphate and Recorcinolbis(Diphenylphosphate) on the Thermal Degradation Of Polycarbonate in Air
The thermal degradation of polycarbonate/triphenylphosphate (PC/TPP) and PC/resocinolbis(diphenylphosphate) (PC/RDP) in air has been studied using TGA/FTIR and GC/MS. In PC/phosphate blends, the phosphate stabilizes the carbonate group of polycarbonate from alcoholysis between the alcohol products of polycarbonate degradation and the carbonate linkage. Thus, the evolution of bisphenol A, which is mainly produced via hydrolysis/alcoholysis of the carbonate linkage, is significantly reduced, while, the evolution of various alkylphenols and diarylcarbonates increases. The bonds that are broken first in the thermal degradation of both the carbonate and isopropylidene linkages of polycarbonate are the weakest bonds in each, when a phosphate is present. Triphenylphosphate and resocinolbis(diphenyl-phosphate), even though they exhibit a significant difference in their volatilization temperature, appear to play a similar role in the degradation pathway of polycarbonate
A TGA/FTIR and Mass Spectral Study on the Thermal Degradation of Bisphenol A Polycarbonate
The thermal degradation of polycarbonate under nitrogen was studied using TGA/FTIR, GC/MS and LC/MS as a function of mass loss. The gases evolved during degradation were inspected by in situ FTIR and then the evolved products were collected and analysed using FTIR, GC–MS and LC–MS. The structures of the evolved products are assigned on the basis of FTIR and GC/MS results. The main thermal degradation pathways follow chain scission of the isopropylidene linkage, and hydrolysis/alcoholysis and rearrangement of carbonate linkages. In the case of chain scission, it was proposed that methyl scission of isopropylidene occurs first, according to the bond dissociation energies. The presence of carbonate structures, 1,1′-bis(4-hydroxyl phenyl) ethane and bisphenol A in significant amounts, supports the view that chain scission and hydrolysis/alcoholysis are the main degradation pathways for the formation of the evolved products
Aeroservoelastic tailoring for lateral control enhancement
The need for effective aileron power for aircraft lateral control and turning maneuvers dates back to the Wright Brothers and their wing warping concept for active stabilization of their aircraft. Early researchers in Great Britain, Japan, Germany and the United States explored ways to increase the effectiveness of control aileron to generate a roll moment. The basic problem of aileron effectiveness and the interrelationship between structural distortion and the loads applied by the control surface is illustrated. A rigid wing/aileron surface will develop the capability to generate increased roll rates as airspeed increases. A flexible surface will become less effective as airspeed increases because of the twisting distortion created by the aft-mounted control surface. This tendency is further worsened by bending distortion of an aft swept wing. This study focuses its attention on the ability of a combined effort between structural redesign of a wing and sizing and placement of a control surface to create specified roll performance with a minimum hinge moment. This design optimization problem indicates the advantages of simultaneous consideration of structural design and control design
Production of the pentaquark in scattering
We study and processes
for both of the positive and negative parities of the . Employing
the effective chiral Lagrangians for the and interactions, we
calculate differential cross sections as well as total cross sections for the
and reactions. The total
cross sections for the positive-parity turn out to be approximately
ten times larger than those for the negative parity in the range of
the CM energy . The results are
rather sensitive to the mechanism of exchanges in the -- channel.Comment: 9 pages and 11 figure
Recommended from our members
Multi-Nozzle Biopolymer Deposition for Freeform Fabrication of Tissue Constructs
Advanced freeform fabrication techniques have been recently used for the construction of tissue
scaffolds because of the process repeatability and capability of high accuracy in fabrication
resolution at the macro and micro scales. Among many applicable tissue scaffolding materials,
polymeric materials have unique properties in terms of the biocompatibility and degradation, and
have thus been widely utilized in tissue engineering applications. Hydrogels, such as alginate,
has been one of the most important polymer scaffolding materials because of its biocompatibility
and internal structure similarity to that of the extracellular matrix of many tissues, and its
relatively moderate processing. Three-dimensional deposition has been an entreating freeform
fabrication method of biopolymer and particularly hydrogel scaffolds because of its readiness to
deposit fluids at ambient temperatures. This paper presents a recent development of biopolymer
deposition based freeform fabrication for 3-diemnsinal tissue scaffolds. The system
configuration of multi-nozzles used in the deposition of sodium alginate solutions and Poly-?-
Caprolactone (PCL) are described. Studies on polymer deposition feasibility and structural
formability are conducted, and the preliminary results are presented.Mechanical Engineerin
Unpolarized fragmentation function for the pion and kaon via the nonlocal chiral-quark model
In this talk we present our recent studies for the unpolarized fragmentation
functions for the pion and kaon, employing the nonlocal chiral quark model,
which manifests the nonlocal interaction between the quarks and pseudoscalar
mesons, in the light-cone frame. It turns out that the nonlocal interaction
produces considerable differences in comparison to typical local-interaction
models.Comment: 4 pages, 2 figures, Talk given at the international conference The
Fifth Asia-Pacific Conference on Few-Body Systems in Physics 2011 (APFB2011),
Seoul, Republic of Korea, 22-26 August 201
- …