Luminescent coordination polymers based on Ca²⁺ and octahedral cluster anions [{M₆Clⁱ₈}Clᵃ₆}²⁻ (M = Mo, W) : synthesis and thermal stability studies

Luminescent coordination polymers (CPs) based of inexpensive stable precursors are attractive materials for applications. Here we report the synthesis and evaluation of the stability and photophysical characteristics of the first examples of phosphorescent CPs based on octahedral molybdenum and tungsten cluster anions. Specifically 1D CP trans-[{Ca(OPPh₃)₄}{{M₆Clⁱ₈}Clᵃ₆}]∞ (M = Mo, W) can be obtained either directly at increased temperature or via intermediate phases [cis-Ca(OPPh₃)₄(H₂O)₂][{M₆Clⁱ₈}Clᵃ₆]∙2CH₃CN that are stable at room-temperature, but convert to the titled CP at temperatures above 100 °C

Meteoprotective properties of melaxen in old and middle aged patients with ischemic heart disease in combination with arterial hypertension

We studied 102 patients (mean age 60.1±3.3 years) with arterial hypertension (AH) II-III stage, grade 2-3 and ischemic heart disease (exertional angina functional class (FC) I-II, postinfarction cardiosclerosis). The control group of patients received traditional therapy (TT): beta -blockers, calcium channel blockers, ACE inhibitors, antiplatelet agents, diuretics and nitrate

Core acid treatment influence on well reservoir properties in Kazan oil-gas condensate field

The research involves investigation of the influence of hydrochloric acid (HCI-12%) and mud acid ( mixture: HCl - 10 % and HF - 3 %) treatment on the Upper-Jurassic reservoir properties in Kazan oil-gas condensate field wells. The sample collection included three lots of core cylinders from one and the same depth (all in all 42). Two lots of core cylinders were distributed as following: first lot - reservoir properties were determined, and, then thin sections were cut off from cylinder faces; second lot- core cylinders were exposed to hydrochloric acid treatment, then, after flushing the reservoir properties were determined, and thin sections were prepared. Based on the quantitative petrographic rock analysis, involvin 42 thin sections, the following factors were determined: granulometric mineral composition, cement content, intergranular contacts and pore space structure. According to the comparative analysis of initial samples, the following was determined: content decrease of feldspar, clay and mica fragments, mica, clay and carbonate cement; increase of pore spaces while in the investigated samples- on exposure of rocks to acids effective porosity and permeability value range is ambiguous

Empirical evidence for unique hues?

Red, green, blue, yellow, and white have been distinguished from other hues as unique. We present results from two experiments that undermine existing behavioral evidence to separate the unique hues from other colors. In Experiment 1 we used hue scaling, which has often been used to support the existence of unique hues, but has never been attempted with a set of non-unique primaries. Subjects were assigned to one of two experimental conditions. In the "unique" condition, they rated the proportions of red, yellow, blue, and green that they perceived in each of a series of test stimuli. In the "intermediate" condition, they rated the proportions of teal, purple, orange, and lime. We found, surprisingly, that results from the two conditions were largely equivalent. In Experiment 2, we investigated the effect of instruction on subjects' settings of unique hues. We found that altering the color terms given in the instructions to include intermediate hues led to significant shifts in the hue that subjects identified as unique. The results of both experiments question subjects' abilities to identify certain hues as unique

On Local Behavior of Holomorphic Functions Along Complex Submanifolds of C^N

In this paper we establish some general results on local behavior of holomorphic functions along complex submanifolds of \Co^{N}. As a corollary, we present multi-dimensional generalizations of an important result of Coman and Poletsky on Bernstein type inequalities on transcendental curves in \Co^{2}.Comment: minor changes in the formulation and the proof of Lemma 8.

Detection Statistics of Pulse Signals at Declinations from +42o+42^o to +52o+52^o at the Frequency 111 MHz

A search for pulse signals was carried out in a new sky area included in the monitoring program for the search for pulsars and transients. Processing of several months data recorded in six frequency channels with a total bandwidth of 2.5 MHz showed that, on average, 4 pulses per hour are observed in each of the 24 connected stationary beams. Of these pulses, 18.3% are similar to those of pulsars. They are visible in one or two neighboring beams and have a pronounced dispersion shift, that is, they are recorded first at a high and then at a low frequency, which indicates the possible passage of the signal through the interstellar medium. Almost 68% of such detected pulses belong to six known pulsars with dispersion measures from 9 to 141 $pc/cm^3$, and almost all of the remaining pulses are either noise of an unknown nature or artifacts of the proposed pulse separation technique. An additional study of the selected array of 3650 obvious pulsar pulses revealed 13 pulses belonging to four rotating radio transients (RRATs). Their dispersion measures are in the range of 17-51 $pc/cm^3$. A search for regular (periodic) RRAT emission was carried out using power spectra summed over 121 days. Periodic radiation was not detected, but for two RRATs, upper estimates of the periods were obtained from measurements of the time intervals between pulses. The upper estimates of the integrated flux density of the detected RRATs are in the range 2-4 mJy at the frequency 111 MHz.Comment: published in Astronomy Report, translated by Yandex translator with correction of scientific lexis, 6 pages, 3 figures, 2 table

Detection of two new RRATs at 111 MHz

A search for pulse signals in a area with declinations of +52\degr <\delta <+55\degr was carried out on the LPA LPI radio telescope. When processing ten months of observations recorded in six frequency channels with a channel width of 415 kHz and a total bandwidth of 2.5 MHz, 22 thousand events were found with a pronounced dispersion delay of signals over frequency channels, i.e. having signs of pulsar pulses. It turned out that the found pulses belong to four known pulsars and two new rotating radio transients (RRATs). An additional pulse search conducted in 32-channel data with a channel width of 78 kHz revealed 8 pulses for the transient J0249+52 and 7 pulses for the transient J0744+55. Periodic radiation of transients was not detected. The analysis of observations shows that the found RRATs are most likely pulsars with nullings, where the proportion of nulling is greater than 99.9\%.Comment: published in Astronomy Reports, translated by Yandex translator with correction of scientific lexis, 5 pages, 2 figures, 1 tabl

Pushchino multibeams pulsar search. IV. Detection of new pulsars at declinations -9o < \delta < +55o

The search for pulsars in monitoring data obtained at the radio telescope Large Phased Array (LPA) at a frequency of 111 MHz was carried out. Daily round-the-clock observations were carried out for about 3,000 days. The duration of the observation session for each direction in the sky was 3.5 minutes per day. The search for pulsars was carried out using power spectra. To search for weak pulsars, power spectra were summed up. The expected increase in sensitivity was 35-40 times compared to observations in one session. In a blind search, 330 pulsars with regular radiation were detected, with periods (P) from 0.0333 to 3.7455 s and dispersion measures (DM) up to 249 pc/cm3. 39 pulsars turned out to be new. Average profiles were obtained for 6 pulsars. The DM for 7 pulsars previously detected on the LPA have been clarified.Comment: published in MNRAS, 13 pages, 4 figures, 4 tables, 4 appendixe

GEMINGA: NEW OBSERVATIONS AT LOW RADIO FREQUENCIES

ABSTRACT. After nearly 10 years, we have succeeded to detect radio emission from Geminga more again. In this report we present new evidence for presence of radio emission from Geminga in the range 42-112 MHz. The observations were carried out on two sensitive transit radio telescopes We used three new digital receivers to detect the pulses and to obtain dynamic spectra.The examples of mean pulse profiles are presented. Exact value of the dispersion measure have been calculated using the simultaneous observations at three frequencies