680 research outputs found
Universal pair-breaking in transition metal-substituted iron-pnictide superconductors
The experimental transport scattering rate was determined for a wide range of
optimally doped transition metal-substituted FeAs-based compounds with the
ThCr2Si2 (122) crystal structure. The maximum transition temperature Tc for
several Ba-, Sr-, and Ca-based 122 systems follows a universal rate of
suppression with increasing scattering rate indicative of a common
pair-breaking mechanism. Extraction of standard pair-breaking parameters puts a
limit of \sim26 K on the maximum Tc for all transition metal-substituted 122
systems, in agreement with experimental observations, and sets a critical
scattering rate of 1.5x10^14 s^-1 for the suppression of the superconducting
phase. The observed critical scattering rate is much weaker than that expected
for a sign-changing order parameter, providing important constraints on the
nature of the superconducting gap in the 122 family of iron-based
superconductors.Comment: 4 pages, 3 figure
Rejecting Collective Bargaining Agreements Under Section 1113 of the Bankruptcy Code - Judicial Precision or Economic Reality?
Before a Chapter 11 debtor in possession can reject the collective bargaining agreement, section 1113 of the Bankruptcy Code requires it to bargain with the representative of its employees and then obtain court approval. Because Congress sought to accommodate the interests of both organized labor and the business community, section 1113 contains numerous terms of compromise which ultimately are interpreted by the courts. The authors have reviewed the major litigation, and have suggested trends in the judicial interpretation of section 1113. However, rejection of collective bargaining litigation is counterproductive with respect to Chapter 11 reorganizations. Rather, the authors believe that the debtor and the union should focus on the economical reality of their situation, rather than the strength of their respective legal positions, to reach agreement at the bargaining table and avoid contract rejection litigation
Breaking the degeneracy of the genetic code
A mutant yeast phenylalanine transfer RNA (ytRNA^(Phe)_(AAA)) containing a modified (AAA) anticodon was generated to explore the feasibility of breaking the degeneracy of the genetic code in Escherichia coli. By using an E. coli strain co-transformed with ytRNA^(Phe)_(AAA) and a mutant yeast phenylalanyl-tRNA synthetase, we demonstrate efficient replacement of phenylalanine (Phe) by L-3-(2-naphthyl)alanine (Nal) at UUU, but not at UUC codons
Spatially resolved femtosecond pump-probe study of topological insulator Bi2Se3
Carrier and phonon dynamics in Bi2Se3 crystals are studied by a spatially
resolved ultrafast pump-probe technique. Pronounced oscillations in
differential reflection are observed with two distinct frequencies, and are
attributed to coherent optical and acoustic phonons, respectively. The rising
time of the signal indicates that the thermalization and energy relaxation of
hot carriers are both sub-ps in this material. We found that the thermalization
and relaxation time decreases with the carrier density. The expansion of the
differential reflection profile allows us to estimate an ambipolar carrier
diffusion coefficient on the order of 500 square centimeters per second. A
long-term slow expansion of the profile shows a thermal diffusion coefficient
of 1.2 square centimeters per second.Comment: 8 pages, 6 figure
Superconductivity at 23 K in Pt doped BaFe2As2 single crystals
We report superconductivity in single crystals of the new iron-pnictide
system BaFe1.9Pt0.1As2 grown by a self-flux solution method and characterized
via x-ray, transport, magnetic and thermodynamic measurements. The magnetic
ordering associated with a structural transition at 140 K present in BaFe2As2
is completely suppressed by substitution of 5% Fe with Pt and superconductivity
is induced at a critical temperature Tc=23 K. Full diamagnetic screening in the
magnetic susceptibility and a jump in the specific heat at Tc confirm the bulk
nature of the superconducting phase. All properties of the superconducting
state including transition temperature Tc, the lower critical field Hc1=200 mT,
upper critical field Hc2~65 T, and the slope dHc2/dT are comparable in value to
the those found in other transition-metal-substituted BaFe2As2 series,
indicating the robust nature of superconductivity induced by substitution of
Group VIII elements.Comment: 6 pgs, 4 figs, and 1 tbl, slightly revised, updated reference
A noncontact measurement technique for the density and thermal expansion coefficient of solid and liquid materials
Discovery of Stable and Selective Antibody Mimetics from Combinatorial Libraries of Polyvalent, Loop-Functionalized Peptoid Nanosheets.
The ability of antibodies to bind a wide variety of analytes with high specificity and high affinity makes them ideal candidates for therapeutic and diagnostic applications. However, the poor stability and high production cost of antibodies have prompted exploration of a variety of synthetic materials capable of specific molecular recognition. Unfortunately, it remains a fundamental challenge to create a chemically diverse population of protein-like, folded synthetic nanostructures with defined molecular conformations in water. Here we report the synthesis and screening of combinatorial libraries of sequence-defined peptoid polymers engineered to fold into ordered, supramolecular nanosheets displaying a high spatial density of diverse, conformationally constrained peptoid loops on their surface. These polyvalent, loop-functionalized nanosheets were screened using a homogeneous Förster resonance energy transfer (FRET) assay for binding to a variety of protein targets. Peptoid sequences were identified that bound to the heptameric protein, anthrax protective antigen, with high avidity and selectivity. These nanosheets were shown to be resistant to proteolytic degradation, and the binding was shown to be dependent on the loop display density. This work demonstrates that key aspects of antibody structure and function-the creation of multivalent, combinatorial chemical diversity within a well-defined folded structure-can be realized with completely synthetic materials. This approach enables the rapid discovery of biomimetic affinity reagents that combine the durability of synthetic materials with the specificity of biomolecular materials
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