169 research outputs found
Spin density distribution in a partially magnetized organic quantum magnet
Polarized neutron diffraction experiments on an organic magnetic material
reveal a highly skewed distribution of spin density within the magnetic
molecular unit. The very large magnitude of the observed effect is due to
quantum spin fluctuations. The data are in quantitative agreement with direct
diagonalization results for a model spin Hamiltonian, and provide insight on
the actual microscopic origin of the relevant exchange interactions.Comment: 5 pages 4 figure
Crystal and magnetic structure of La_{1-x}Sr_{1+x}MnO_{4} : role of the orbital degree of freedom
The crystal and magnetic structure of La_{1-x}Sr_{1+x}MnO_4 (0<x<0.7) has
been studied by diffraction techniques and high resolution capacitance
dilatometry. There is no evidence for a structural phase transition like those
found in isostructural cuprates or nickelates, but there are significant
structural changes induced by the variation of temperature and doping which we
attribute to a rearrangement of the orbital occupation.Comment: 8 pages, 6 figures, submitted to PR
Crystal structures and proton dynamics in potassium and cesium hydrogen bistrifluoroacetate salts with strong symmetric hydrogen bonds
The crystal structures of potassium and cesium bistrifluoroacetates were
determined at room temperature and at 20 K and 14 K, respectively, with the
single crystal neutron diffraction technique. The crystals belong to the I2/a
and A2/a monoclinic space groups, respectively, and there is no visible phase
transition. For both crystals, the trifluoroacetate entities form dimers linked
by very short hydrogen bonds lying across a centre of inversion. Any proton
disorder or double minimum potential can be rejected. The inelastic neutron
scattering spectral profiles in the OH stretching region between 500 and 1000
cm^{-1} previously published [Fillaux and Tomkinson, Chem. Phys. 158 (1991)
113] are reanalyzed. The best fitting potential has the major characteristics
already reported for potassium hydrogen maleate [Fillaux et al. Chem. Phys. 244
(1999) 387]. It is composed of a narrow well containing the ground state and a
shallow upper part corresponding to dissociation of the hydrogen bond.Comment: 31 pages, 7 figure
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