磁性抛光对3D打印微结构的参数影响

对微结构精密加工时要能够控制高低不平的材料去除,以保证不破坏微结构原来的三维形貌特征。通过自行搭建的实验平台对3D打印出来的微结构工件进行抛光实验,主要研究了机床主轴转速、加工间隙、抛光时间和抛光路径等工艺参数对微结构抛光后的三维轮廓材料去除特性以及微结构的保形情况。实验结果表明:微结构保形系数随着抛光时间增加而变小,而主轴转速和加工间隙的变化对保形系数影响较小;采用等高线移动式抛光的保形系数比采用水平移动式大;相同工艺参数抛光对包体状和圆环阵列微结构工件保形效果较好,对三棱锥工件保形效果较差。国家自然科学基金(51675453);;深圳市科技计划项目(JCYJ20160517103720819

Study on Remove of Free-Form Surface Structure by Magnetic Polishing

磁性抛光因柔性工具的工件表面适应性高而具有较好的应用潜力。自行设计抛光工具头,制备磁性抛光体,搭建试验平台,并对不锈钢平面工件进行定点抛光试验,平均去除效率为0.231μm/10min,且工件表面质量得到了很大的改善,验证了该磁性抛光方法的可行性。继而对两种自由曲面结构工件进行抛光：一是采用工具头水平移动式、工具头等高线移动式两种不同的抛光进给运动方式对不同曲率的不锈钢工件进行抛光去除试验,试验证明：两种抛光方式对每个曲率的轮廓均有去除能力,去除量在0.14~1.33μm之间;二是对3D打印的光敏树脂微结构自由曲面定点抛光,单位时间去除效率在8.957~12.587μm/10min之间,且改善了轮廓的光滑度。初步试验表明,磁性抛光方法对两种自由曲面结构均有一定的去除能力,可进一步探索磁性抛光技术应用于自由曲面结构确定性抛光。Magnetic polishing technique has wide application potential due to the high adaptability of flexible tool to the workpiece surface. The relevant polishing tools were developed, and a test platform was established in the paper. The workpiece finish had been greatly improved after spot polishing on stainless steel flat parts, and the average removal efficiency was 0.231μm/10 min, which verified the feasibility of the magnetic polishing method. Then two kinds of free-form surface structures were polished by magnetic polishing method. First, stainless steel parts with different curvatures were polished by two different polishing feed movement ways. Experimental results showed that two polishing methods had the ability to remove the contours of each curvature, and the removal amount falls between 0.14-1.33μm. Secondly, the removal efficiency was between 8.957-12.587μm/10 min after spot polishing the microstructured free-form surface, and the smoothness of the contour is improved. Preliminary experiments showed that the magnetic polishing method had the ability to remove both free-form surface structures, so it can explore further magnetic polishing technology used in deterministic polishing of free-form surface structure.深圳科技计划项目（JCYJ20160517103720819

焙烧温度对甲硫醇催化剂K_2WO_4/Al_2O_3结构和性能的影响

研究了焙烧温度对溶胶-凝胶法制备的甲硫醇催化剂K2WO4/Al2O3的表面结构和催化性能的影响.表征结果显示,K2WO4在Al2O3上分散得较好,在450和550oC焙烧的催化剂颗粒大小均匀,无明显团聚现象.随着焙烧温度的升高,催化剂的比表面积减小,表面钨物种与Al2O3的相互作用减弱,与碱物种的相互作用增强,酸碱强度降低.K2WO4/Al2O3表面不含质子酸.催化剂活性与其比表面积及表面的共轭酸碱对密切相关.评价结果表明,在550oC焙烧而制得的催化剂活性最高

Effect of Calcination Temperature on the Structure and Catalytic Performance of K_2WO_4/Al_2O_3 Catalysts for Methanethiol Synthesis

通讯联系人. 电话/传真: (0592)2182368; 电子信箱: [email protected][中文文摘]研究了焙烧温度对溶胶-凝胶法制备的甲硫醇催化剂K2WO4/Al2O3的表面结构和催化性能的影响.表征结果显示,K2WO4在Al2O3上分散得较好,在450和550oC焙烧的催化剂颗粒大小均匀,无明显团聚现象.随着焙烧温度的升高,催化剂的比表面积减小,表面钨物种与Al2O3的相互作用减弱,与碱物种的相互作用增强,酸碱强度降低.K2WO4/Al2O3表面不含质子酸.催化剂活性与其比表面积及表面的共轭酸碱对密切相关.评价结果表明,在550oC焙烧而制得的催化剂活性最高.[英文文摘]The effect of calcination temperature on the surface morphology and catalytic performance of the K2WO4/Al2O3 catalyst prepared by the sol-gel method for the synthesis of methanethiol from methanol and hydrogen sulfide was investigated.Physicochemical characterization results of the catalyst showed that the K2WO4 is well dispersed on Al2O3,and the catalyst possesses uniform particle size after calcination at 450 or 550 oC.With increasing the calcination temperature,the specific surface area decreases,the interaction of W species with Al2O3 was weakened, but strengthened with basic species, leading to the decrease of surface acidity and basicity. No Brönsted acid was found on the catalyst surface. The catalytic activity of the catalyst is closely related with the specific surface area and the presence of conjugate acid-base pairs on the surface. Activity assay results show that the catalyst calcined at 550 oC exhibits the highest activity for the reaction.重庆紫光化工股份有限公司的经费资

Transition Metal Promoted ZSM-5 Catalysts for the Conversion of Dimethyl Sulfide into Methanethiol

负载过渡金属的zSM-5催化剂用于催化甲硫醚(dMS)转化成甲硫醇(MT)的反应.实验结果表明,催化剂的甲硫醚转化率提高和甲硫醇选择性降低的趋势一样,都是以下顺序:CO/zSM-5>MO/zSM-5>nI/zSM-5>W/zSM-5.表征结果表明,由于过渡金属阳离子(W6+、nI2+、CO3+、MO6+)比Al3+活泼,而改性过程中W6+、nI2+、CO3+、MO6+分别代替了部分Al3+,使得改性催化剂对dMS和MT的化学吸附作用更强.过渡金属的引入使得zSM-5总酸度增强,提高了C―S键的裂解能力,从而改进了催化转化dMS的能力.研究结果发现,在转化dMS的过程中,金属活性位和酸性位之间通过强的协同效应起作用.ZSM-5-supported transition metal catalysts were prepared and used to catalyze the conversion of dimethyl sulfide(DMS) into methanethiol(MT).Test results indicated that the activities of the catalysts for the conversion of DMS increased as follows: Co/ZSM-5>Mo/ZSM-5>Ni/ZSM-5>W/ZSM-5.The decrease in MT selectivity followed the same trend.The characterization results showed that transition metal cations(W6 +, Ni2 +, Co3 +, Mo6 +) replaced some Al3 +sites leading to more active in chemiadsorption of DMS and MT since transition metal cations are more active than Al3 +.The incorporation of transition metals into ZSM-5enhances the total acidity of ZSM-5 and increases its capacity to rupture C―S bonds.This subsequently improves its catalytic behavior in the conversion of DMS.We found that the metal active sites and closely situated acidic sites have a strong synergistic effect when converting DMS

Membrane Deformability and Membrane Tension of Single Isolated Mitochondria

Mitochondria dynamics is crucial to many biological processes such as mitochondria fusion and fission, which is highly correlated to the mechanics of single mitochondria. However, the mechanobiological coupling of mitochondria has been poorly understood. Here membrane deformability and membrane tension of individual mitochondria isolated from MtDsRed labeled human embryonic T-Rex-293 kidney cells were measured using a micropipette aspiration assay. The results demonstrated that membrane deformation of isolated mitochondria exhibited an elastic transition phase followed by an equilibrium phase, and mitochondrial membrane tension was proportional to the area compressibility. It was also indicated that mitochondrial membrane deformability was significantly affected by physical chemical factors such as osmotic pressure or pH value, and was further correlated to mitochondrial functionality in different respiratory states and Ca2+ regulation. These findings provide a new insight into understanding the mechanical regulation of mitochondrial physiology.</p

第十八届美国理论与应用力学大会总结

1会议概况2018年6月5—9日,第18届美国理论与应用力学大会(18th U.S. National Congress of Theoretical and Applied Mechanics, USNCTAM2018)在美国芝加哥召开.本次大会由美国力学国家委员会和中国力学学会联合主办,旨在探讨和交流近四年世界范围内在理论和应用力学领域的基础研究、创新技术的最新进展,吸引了来自世界各地的近千名专家学

Studies On Systematics of Crawfurdia Wall. and Its Related Taxa in the Gentianaceae

本文回顾了龙胆科蔓龙胆属、双蝴蝶属、龙胆属狭蕊组和翼萼蔓属的研究历史，对这些类群的外部形态、花部解剖结构、染色体、花粉形态及胚胎学进行了研究，并结合已有的资料，探讨了这些类群的分类学问题。主要结论如下： 1．外部形态 蔓龙胆属、双蝴蝶属、龙胆属狭蕊组和龙胆属其他组之 间以及蔓龙胆属和翼萼蔓属之间在外部形态上均存在差异。 2．花部解剖结构 蔓龙胆属、双蝴蝶属、龙胆属狭蕊组和龙胆属其他组的花部解剖结构存在较多地相似之处，同时蔓龙胆属和双蝴蝶属的花被维管束和腺体比龙胆属狭蕊组和龙胆属其他组的特化。而翼萼蔓属的花部解剖结构与蔓龙胆属的差异较大，与扁蕾属的花部解剖结构较相似。 3．染色体 本文对蔓龙胆属、双蝴蝶属、龙胆属狭蕊组和翼萼蔓属的7种植物的染色体数目、基数和核型对称性作了研究，其中6种植物的染色体为首次报道，它们是：披针叶蔓龙胆C．delavayi、双蝴蝶T.chnense、峨眉双蝴蝶T．cordatum、锯齿龙胆 G．serra、毛脉龙胆G．souliei、和翼萼蔓P．volubilis。蔓龙胆属、双蝴蝶属和龙胆属狭蕊组的核型不对称性稍强于龙胆属其他组，但在染色体组成上十分相似。翼萼蔓属和蔓龙胆属的染色体差异较大，面与扁蕾属的染色体较相似。 4.花粉形态蔓龙胆属、双蝴蝶属、龙胆属狭蕊组和龙胆属其他组均具有球形或长球形、3孔沟、沟长而宽、外壁纹饰为条纹一无穿孔和条纹一穿孔的花粉类型。而翼萼蔓属的花粉为球形、纹饰为网状纹馋与蔓龙胆属不同，与扁蕾属的花粉较相似。 5．胚胎学 本文对披针叶蔓龙胆C，delavayi、双蝴蝶T．chinense、峨眉双蝴蝶T．cordatum、条纹龙胆G. striata和翼萼蔓P．volubilis作了较详细的胚胎学研究，这些类群在花药壁的分化和形成、胚珠和胎座类型、卵器中的助细胞和反足细胞、种皮以及胚发育等特征上存在差异，并且在胚胎学特征上各自拥有原始和进化的性状。蔓龙胆属、双蝴蝶属和龙胆属之间的胚胎学性状差异较大，龙胆属狭蕊组与双蝴蝶属的胚胎学性状较相似，而与蔓龙胆属和龙胆属其他组的差吴较大。翼萼蔓属的胚胎学性状与扁蕾属的较相似，而与蔓龙胆属的差异较大。 6．综合分析外部形态、花部解剖结构、染色体、花粉形态及胚胎学性状，结果表明，蔓龙胆属、双蝴蝶属、龙胆属狭蕊组和龙胆属其他组是亲缘关系十分相近的类群，在某些特征上已存在明显地演化极向，但在大多数特征上演化极向不明。蔓龙胆属和双蝴蝶属分别作为独立属处理较为合适，而且两属的亲缘关系很近。狭蕊组仍应放在龙胆属，蔓龙胆属比双蝴蝶属与龙胆属的亲缘关系更近一些。翼萼蔓属也应作为一独立属处理，而且该属可能与扁蕾属的亲缘关系较近，而与蔓龙胆属亲缘关系较远。 7．本文还讨论了蔓龙胆属、双蝴蝶属、龙胆属狭蕊组和翼萼蔓属的地理分布

Synehronous Dynamic Random Access Memory Controller Design Based on FPGA Between Ethernet and E1

为了实现不同速率数据链路通信的相互转换,提出了一种利用现场可编程门序列(fPgA)设计并实现可对同步动态随机存储器(SdrAM)进行数据缓存并高速读写的控制器.该控制器采取状态机和令牌环机制,通过对SdrAM操作,实现了双向4路的跨时钟域的匹配.该控制器适用于任意长度的以太网帧和其他类型的数据相互转换.In order to achieve communication based on asynchronous clock,this essay comes up with a synehronous dynamic random access memory(SDRAM) controller,which can store data in and reload from SDRAM by read/write operation with high speed,for data cache.According to operating the SDRAM,this controller allows bidirectional asynchronous data to rematch in SDRAM by using state machine and token ring mechanism.It is also suitable for communication between other data and Ethernet frame with random length.福建省自然科学基金项目(2012H0038

3D打印微结构工件的磁性复合流体抛光工艺研究

对微结构精密加工时需要能够控制高低不平的材料去除,以保证不破坏原有微结构的三维形貌特征.通过自行搭建的实验平台对3D打印出来的微结构工件进行抛光实验,主要研究了机床主轴转速、加工间隙、抛光时间和抛光路径等工艺参数对微结构抛光后的三维轮廓材料去除特性以及微结构的保形情况.实验结果表明:微结构保形系数随着抛光时间增加而变小,而主轴转速和加工间隙的变化对保形系数影响较小;采用等高线移动式抛光的保形系数比采用水平移动式大;相同工艺参数抛光对包体状和截面为半圆的圆环圆周阵列微结构工件保形效果较好,对正三棱锥工件保形效果较差.国家自然科学基金(51675453);;深圳市科技计划项目(JCYJ20160517103720819