Adsorption Performance of Arsenic(Ⅲ) in Water on Hyperaccumulating Plant-Pteris vittata

采用流动注射-氢化物发生-电热石英管原子吸收光谱法研究了超富集植物蜈蚣草对水中As(Ⅲ)的吸附行为。探讨了蜈蚣草的前处理方法、溶液pH值、吸附时间、吸附剂用量、As(Ⅲ)浓度和溶液体积等因素对蜈蚣草吸附As(Ⅲ)的吸附率的影响。结果表明,以50 mg经2 mol.L-1HCl洗脱处理后的蜈蚣草粉末为吸附剂,在pH为2.0、As(Ⅲ)浓度为20 ng.mL-1、溶液体积50 mL、吸附时间15 min条件下,蜈蚣草对As(Ⅲ)的吸附率可达86.1%,水中残余As(Ⅲ)仅为2.8 ng.mL-1。本法成本低廉、操作简便,可望直接用于地下水中As(Ⅲ)的去除。The adsorption performance on As(Ⅲ) in water with Pteris vittata(hyperaccumulating plant) was studied.The concentration of As(Ⅲ) in water was determined by flow injection-hydride generation-atomic adsorption spectrometry(FI-HG-AAS).The influence factors,including the pre-treatment of Pteris vittata,pH value,concentration of adsorbate,sample volume,adsorption time and amount of adsorbent were studied.The adsorption ratio of 20 ng/mL As(Ⅲ) with Pteris vittata(L) which was pre-treated by 2 mol/L HCl was 86.1% and the residual concentration of As(Ⅲ) was reduced to 2.8 ng/mL under the optimum conditions.The method was economical,manipulated simple and convenient,which could be used to remove As(Ⅲ) of groundwater directly,and met the standards of drinking water made by EU,EPA and WHO.国家自然科学基金(No.40506020