THE CONTROLLED SYNTHESIS OF NANOMATERIALS —TWO DIMENSIONAL COMPOSITE SILICA NANOPARTICLES

本文主要研究了在反向胶束体系中合成纳米材料，在CA630-环己烷和Brij56-环己烷两个体系中，通过控制反应条件，包括：反应物种类，量，加入顺序，合成了不同结构和形状的氧化物-SiO2复合材料。 1．利用这两种反向胶束体系，分别合成直径70nm和40nm，尺寸单一，具有很好分散性的SiO2球； 2．在CA630-环己烷反向胶束中，通过改水相为Ni（NO3）2溶液，可以合成了含NiO的SiO2球，NiO均匀分布在SiO2球的孔隙中。 3.在Brij56-环己烷反向胶束中，通过改水相为Ni（NO3）2溶液，合成NiO@SiO2核-壳机构，酸洗去掉NiO，形成SiO2空心球。改变Ni(NO3...The synthesis of nanomaterial in reverse micelles was investigated in this thesis, including CA 630-cyclohexane and Brij 56-cyclehexane system. The nano-particles with different structure and shape was obtained by controlling experimental condition, i.e. reactant species, scale, adding order. - Monodispersive, SiO2 spheres with sizes of 70 nm and 40nm were synthesized in the two revers...学位：博士后院系专业：化学化工学院化学系_无机化学学号：BH1700019

An Assembly Route to Inorganic Catalytic Nanoreactors Containing Sub-10-nm Gold Nanoparticles with Anti-Aggregation Properties

通讯作者地址: Zheng, NF (通讯作者), Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China 地址: 1. Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China 2. Xiamen Univ, Dept Chem, Xiamen 361005, Peoples R China 3. Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA 电子邮件地址: [email protected], [email protected] Ministry of Education,108077 NNSFC,20871100 20721001 20423002 MSTC,2007CB815303 2009CB930703 NFFTBS,J063042