Studies on Catalytic Mechanism of Li/SOCl_2 Batteries by Metal Phthalocyanine Complexes

合成过渡金属酞菁配合物MPc(M=Mn(Ⅱ),Fe(Ⅱ),Co(Ⅱ),N i(Ⅱ),Cu(Ⅱ)),研究MPc及其中心离子对L i/SOC l2电池正极的催化作用,并提出相关催化机理.Effects of metal phthalocyanine comlexes MPc(M= Mn(Ⅱ),Fe(Ⅱ),Co(Ⅱ),Ni(Ⅱ),Cu(Ⅱ)) as electrochemical catalysts on the performance of Li/SOCl2 batteries have been examined at constant resistance.And the reasons of MPc affecting the discharged voltage and discharged time of Li/SOCl2 batteries were also brought forward.A few new viewpoints on the catalytic mechanism of the reduction of thionyl chloride by phthalocyanine complexes were proposed.作者联系地址：西北大学化学系陕西省物理无机化学重点实验室,西北大学化学系陕西省物理无机化学重点实验室,西北大学化学系陕西省物理无机化学重点实验室,西北大学化学系陕西省物理无机化学重点实验室,西北大学化学系陕西省物理无机化学重点实验室,西安机电信息研究所,西北大学化学系陕西省物理无机化学重点实验室 陕西西安710069,陕西西安710069,陕西西安710069,陕西西安710069,陕西西安710069,陕西西安710065,陕西西安710069Author's Address: 1.Shaanxi Key Laboratory of Physico-Inorganic Chemistry,Department of Chemistry, Northwest University,Xi'an,710069,China,2.P.O.Box 121,Xi'an,710065,Chin