Dynamics Analysis of Surface Layer Thickness Growth of Hot Dip RE-Al Coating under Ultrasonic Vibration Field

用溶剂法制备了稀土铝镀层,采用金相显微镜、扫描电镜观察测定了超声场对热浸镀稀土铝表面层厚度的影响,绘制了表面层厚度变化的动力学曲线.研究得知,稀土铝镀层由表面层和过渡层组成.通过厚度测定发现,过渡层厚度遵循抛物线生长规律,而表面层的厚度变化则明显不同.随着热浸稀土铝时间的延长,表面层厚度经历了先减少至谷值,然后增加到峰值,又减少至稳定值的3个阶段.每一阶段控制厚度变化的因素不同,将其变化过程分为由凝固-重熔控制的第Ⅰ阶段,由浸润-凝固控制的第Ⅱ阶段和完全由浸润控制的第Ⅲ阶段.不管是否施加超声场,表面层厚度变化的规律相似,只不过施加超声场后表面层厚度有不同程度的减小,同时表面层的组织变得更加均匀

扩散处理热浸镀铝钢高温抗氧化行为的研究

对经不同扩散工艺处理的热浸镀铝层高温抗氧化性进行了研究,通过SEM、TEM、XRD分析了经扩散处理后,热浸镀铝层高温氧化过程中组织结构的变化情况,分析了热浸镀铝层高温抗氧化性能和微观结构的关系,确定了提高热浸镀铝层高温抗氧化性的适宜扩散温度。结果表明,经750℃扩散处理,热浸镀铝层结构由较厚的外表层(Fe2Al5+FeAl2)及内层(FeAl+条状:FeAl2)组成,条状FeAl2的形成为氧提供了扩散通道,其抗氧化性较差;经950℃扩散处理,镀层外表层变薄,外表层转为单一FeAl2、内层为FeAl,并出现早期内氧化裂纹,其抗氧化性较差:当扩散处理温度为850℃时,镀层外表层变薄,结构转为FeAl2+少量Fe2Al5,而内层增厚,其结构为FeAl+球状FeAl2,而内层FeAl2球化,增强了氧由内层向基体扩散的阻碍作用,使氧只能逐层形成Al2O3+Fe2O3的氧化膜,提高了镀层的高温抗氧化性

稀土铈对热浸镀铝层组织和性能的影响

研究了稀土铈对热浸镀铝层组织结构、耐蚀和耐热性能的影响。结果表明：稀土铈质量分数低于0．3％时，热浸镀铝层的耐蚀性能和高温抗氧化性能都得到提高，超过此含量镀层的性能下降。稀土铈使得过渡层由锯齿形结构转变为平滑结构，使镀层中FeAl3析出相在表层中呈网状分布，随其含量增加过渡层厚度减小。稀土含量超过0．3％时，稀土化合物在表层中呈条块状第二相析出并偏聚，并且随著稀土铈含量增加，表面层中稀土化合物呈块状，且偏聚程度加大

Effect of Rare Earth Element Cerium on Properties and Microstructure of Hot Dip Aluminum Coating on Q235 Steel

研究了稀土铈对热浸镀铝层组织结构、耐蚀和耐热性能的影响。结果表明：稀土铈质量分数低于0．3％时，热浸镀铝层的耐蚀性能和高温抗氧化性能都得到提高，超过此含量镀层的性能下降。稀土铈使得过渡层由锯齿形结构转变为平滑结构，使镀层中FeAl3析出相在表层中呈网状分布，随其含量增加过渡层厚度减小。稀土含量超过0．3％时，稀土化合物在表层中呈条块状第二相析出并偏聚，并且随著稀土铈含量增加，表面层中稀土化合物呈块状，且偏聚程度加大

Effect of diffusion on coating microstructure and oxidation resistance of aluminizing steel

The effect of diffuse treatment on coating microstructure and oxidation resistance at high-temperature of hot-dip aluminum were studied by means of TEM, SEM and XRD. The results show that, the diffusion temperature has significant effect on structure of coatings and its oxidation resistance. After diffusion at 750 degreesC, the coating consists of thick outer surface layer (Fe2Al5+ FeAl2), thin internal layer (FeAl + stripe FeAl2), and its oxidation resistance is poor. After diffusion at 950 degreesC, the outer surface layer is composed of single FeAl2 phase, the internal layer is composed of FeAl phase, and its oxidation resistance declines due to the occurrence of early stage internal oxidation cracks in the coating. After diffusion at 850 degreesC, the outer surface layer becomes thinner and consists of FeAl2 Fe2Al5(small amount), the internal layer becomes thicker and consists of FeAl+spherical FeAl2, and the spheroidized FeAl2 phase in the internal layer and its existing in FeAl phase steadily improve the oxidation resistance of the coating

Effect of diffusion on coating microstructure and oxidation resistance of aluminizing steel

The effect of diffuse treatment on coating microstructure and oxidation resistance at high-temperature of hot-dip aluminum were studied by means of TEM, SEM and XRD. The results show that, the diffusion temperature has significant effect on structure of coatings and its oxidation resistance. After diffusion at 750 degreesC, the coating consists of thick outer surface layer (Fe2Al5+ FeAl2), thin internal layer (FeAl + stripe FeAl2), and its oxidation resistance is poor. After diffusion at 950 degreesC, the outer surface layer is composed of single FeAl2 phase, the internal layer is composed of FeAl phase, and its oxidation resistance declines due to the occurrence of early stage internal oxidation cracks in the coating. After diffusion at 850 degreesC, the outer surface layer becomes thinner and consists of FeAl2 Fe2Al5(small amount), the internal layer becomes thicker and consists of FeAl+spherical FeAl2, and the spheroidized FeAl2 phase in the internal layer and its existing in FeAl phase steadily improve the oxidation resistance of the coating

The Effect of the Thickness of Fe2 Al5 Phase Layer at Fe/Al Interface on the Mechanics Behavior of Hot Dip Aluminizing Coating

Hot Dip Aluminized Coatings with different thickness were prepared on Q235 steel in aluminum solutions with different temperature for certain time. Through tensile tests and in-situ SEM observations, the effect of the coating's microstructure on the tensile strength of the samples was studied. It was disclosed at certain aluminum solution temperature,transaction layers mainly composed of Fe2 Al5 phase got thicker with time prolonging, and this changed initial crack's extending direction from parallel with to vertical with stretching direction. The change in crack direction decreased tensile strength of samples, thus made the coating easy to break. It was concluded that the existence of thick Fe2 Al5 phase layer was the basic reason for the lowering of tensile strength of the coating

Formation and Structure of Composite Coating of HAD and Micro-Plasma Oxidation on A3 Steel

Composite coatings were obtained on A3 steel by hot dipping aluminum(HAD) at 720 degreesC for 6 min and micro-plasma oxidation (MPO) in alkali electrolyte. The surface morphology, element distribution and interface structure of composite coatings were studied by means of XRD, SEM and EDS. The results show that the composite coatings obtained through HAD/MPO on A3 steel consist of four layers. From the surface to the substrate, the layer is loose Al2O3 ceramic, compact Al2O3 ceramic, At and FeAl intermetallic compound layer in turn. The adhesions among all the layers are strengthened because the ceramic layer formed at the At surface originally, FeAl intermetallic compound layer and substrate are combined in metallurgical form through mutual diffusion during HAD process. Initial experiment results disclose that the anti-corrosion performance and wear resistance of composite coating are obviously improved through HAD/MPO treatment