30 research outputs found
2-Chloro-4-{(E)-[(4-chlorophenyl)imino]methyl}phenol
In the title Schiff base compound, C13H9Cl2NO, the dihedral angle between the mean planes of the benzene rings is 10.20 (10)°. The crystal structure is stabilized by O—H⋯N hydrogen bonds and weak π–π stacking interactions [centroid–centroid distance = 3.757 (1) Å]
(E)-2-[(2,4-Dichlorophenyl)iminomethyl]benzene-1,4-diol monohydrate
The title compound, C13H9Cl2NO2·H2O, represents a Schiff base which adopts the phenol–imine tautomeric form in the solid state. The molecule is approximately planar (r.m.s. deviation 0.0818 Å), and the dihedral angle between the two aromatic rings is 7.46 (12)°. An O—H⋯N interaction generates an S(6) ring. In the crystal, molecules are linked by intermolecular O—H⋯O hydrogen bonds involving the solvent water molecule, forming chains
(E)-2-[3-(Trifluoromethyl)phenyliminomethyl]benzene-1,4-diol
In the title compound, C14H10F3NO2, the two benzene rings are oriented at a dihedral angle of 31.94 (14)°. An intramolecular O—H⋯N hydrogen bond helps to stabilize the molecular structure. In the crystal, intermolecular O—H⋯O hydrogen bonding links the molecules, forming chains running along the crystallographic a axis. The F atoms of the trifluoromethyl group are disordered over two positions with refined site occupancies of 0.488 (5) and 0.512 (5)
(E)-2-[(2,4-Dichlorophenyl)iminomethyl]-6-methylphenol
The title compound, C14H11Cl2NO, is a Schiff base which adopts the phenol–imine tautomeric form in the solid state. There are two molecules in the asymmetric unit. Head-to-tail π–π interactions [centroid-to-centroid distances of 3.682 (2), 3.708 (2), 3.904 (2) and 3.910 (2) Å] between adjacent molecules produce two symmetry-independent infinite chains running along the b axis
3,5-Dibenzoyl-2,6-dimethyl-1-pentyl-4-pyridone
In the crystal structure of the title compound, C26H27NO3, a one-dimensional network of C—H⋯O hydrogen bonds and π-ring interactions is responsible for crystal stabilization. Intermolecular hydrogen bonds and C—H⋯ π interactions produce R
2
2(10), R
4
4(27) and R
4
4(29) rings
2-[(4-Ethylphenyl)iminomethyl]-3,5-dimethoxyphenol
The title compound, C17H19NO3, adopts the phenol–imine tautomeric form, with a resonance-assisted O—H⋯N intramolecular hydrogen bond [O⋯N = 2.551 (3) Å]. The dihedral angle between the two benzene rings is 45.42 (7)°. The two methoxy groups are coplanar with the attached benzene ring [C—O—C—C torsion angles = −1.1 (5) and 3.2 (4)°]
3,5-Dimethoxy-2-[(4-propylphenyl)iminomethyl]phenol
The title compound, C18H21NO3, crystallizes in the phenol–imine tautomeric form, with the H atom attached to oxygen rather than on nitrogen. This H atom is involved in a strong intramolecular O—H⋯N hydrogen bond. A C—H⋯π interaction is also present. The dihedral angle between the aromatic rings is 12.23 (7)°
(E)-2-[(4-Iodophenyl)iminomethyl]-6-methylphenol
The title compound, C14H12INO, adopts the phenol–imine tautomeric form. The dihedral angle between the aromatic rings is 20.6 (3)°. The molecular conformation is stabilized by an intramolecular O—H⋯N hydrogen bond while in the crystal, weak intermolecular C—H⋯O hydrogen bonds link the molecules into a zigzag chain parallel to the b axis