40 research outputs found
Highly thermostable, non-oxidizable indium, gallium, and aluminium perfluorophthalocyanines with n-type character
Synthesis and spectroscopic properties of 5-tert-butyl-3-(trifluoromethyl)phthalonitrile : a novel precursor for the synthesis of phthalocyanines
An improved synthesis, characterization, and X-ray studies of 5-"tert"-butyl-3-nitrophthalonitrile
Synthesis of thermally robust, photostable aza-dipyrromethene ligands substituted with nitro groups
Own Method of Forehead Skin-Sinus Fistula Treatment with Enabling and Maintaining Physiological Drainage in Overgrowing Inflammation of the Sinuses-A Case Report
Surgical treatment of craniofacial region diseases associated with soft tissue and bone loss is always a challenge for medical specialists. The paper reports a case of a 70-year-old patient who presented with a defect in the forehead area that had been dermatologically treated. Following clinical, laboratory and imaging diagnostics, the lesion was classified as skin sinus fistula. The case study analyzes overgrowth of the nasofrontal duct associated with the laryngological endoscopic procedure (restoring the patency of the frontal sinus was performed as the initial part of the treatment.) Maxillofacial surgeons made an attempt to create an acrylic “space maintainer” which can be used either temporarily or as the ultimate option. The manuscript also describes a method of multi-specialized surgical treatment and subsequent esthetic management with the use of an individualized epithesis for soft tissue replacement
Own Method of Forehead Skin-Sinus Fistula Treatment with Enabling and Maintaining Physiological Drainage in Overgrowing Inflammation of the Sinuses-A Case Report
Surgical treatment of craniofacial region diseases associated with soft tissue and bone loss is always a challenge for medical specialists. The paper reports a case of a 70-year-old patient who presented with a defect in the forehead area that had been dermatologically treated. Following clinical, laboratory and imaging diagnostics, the lesion was classified as skin sinus fistula. The case study analyzes overgrowth of the nasofrontal duct associated with the laryngological endoscopic procedure (restoring the patency of the frontal sinus was performed as the initial part of the treatment.) Maxillofacial surgeons made an attempt to create an acrylic “space maintainer” which can be used either temporarily or as the ultimate option. The manuscript also describes a method of multi-specialized surgical treatment and subsequent esthetic management with the use of an individualized epithesis for soft tissue replacement
A beneficial effect of bromination on the photophysical and photochemical properties of aza‐BODIPY dyes with electron‐donating groups
Polyelectrolyte multilayers with perfluorinated phthalocyanine selectively entrapped inside the perfluorinated nanocompartments
A novel per
fl
uorinated magnesium phthalocyanine (MgPcF
64
) was synthesized and employed to probe
nanodomains in hydrophobically modi
fi
ed, amphiphilic cationic polyelectrolytes bearing alkyl and/or
fl
uoroalkyl side chains. MgPcF
64
was found to be solubilized exclusively in the aqueous solutions of the
fl
uorocarbon modi
fi
ed polycations, occupying the per
fl
uorinated nanocompartments provided, while
analogous polyelectrolytes with alkyl side chains forming hydrocarbon nanocompartments could not
host the MgPcF
64
dye. Multilayer
fi
lms were fabricated by means of the layer-by-layer (LbL) deposition
method using sodium poly(styrene sulfonate) as a polyanion. Linear multilayer growth was con
fi
rmed by
UV-Vis spectroscopy and spectroscopic ellipsometry. Atomic force microscopy studies indicated that the
micellar conformation of the polycations is preserved in the multilayer
fi
lms. Fluorescence spectroscopy
measurements con
fi
rmed that MgPcF
64
stays embedded inside the
fl
uorocarbon domains after the
deposition process. This facile way of selectively incorporating water-insoluble, photoactive molecules
into the structure of polyelectrolyte multilayers may be utilized for nanoengineering of ultrathin
fi
lm-
based optoelectronic devices