5 research outputs found

    Lead tetra-acetate oxidation of saturated aliphatic alcohols-V. Factors influencing the formation of cyclic ethers and carbonyl compounds

    No full text
    Factors influencing the relative rates of the homolytic and heterolytic processes in the lead tetra-acetate oxidation of unbranched primary and secondary aliphatic alcohols have been investigated, with a view to determine the conditions giving optimal yields of cyclic ethers or carbonyl compounds

    Lead tetraacetate oxidation of saturated aliphatic alcohols.-III. Unbranched primary and secondary alcohols

    No full text
    The action of lead tetraacetate, in benzene solution, on various unbranched primary and secondary aliphatic alcohols containing 4 to 12 carbon atoms has been investigated and the ratio of carbonyl compounds, cyclic ethers and fragmentation products determined. The results obtained are discussed with regard to the number and length of the n-alkyl rests attached to the carbinol carbon atom of the starting alcohol

    Thiyl Radicals in Organic Synthesis

    No full text
    corecore