Bis(μ-2-fluoro­benzoato-1:2κ2 O:O′)(2-fluoro­benzoato-1κ2 O,O′)(2-fluoro­benzoato-2κO)dinicotinamide-1κN 1,2κN 1-dizinc(II)–2-fluoro­benzoic acid (1/1)

The asymmetric unit of the title compound, [Zn2(C7H4FO2)4(C6H6N2O)2]·C7H5FO2, consists of a binuclear ZnII complex bridged by two carboxyl groups of 2-fluoro­benzoate (FB) anions and a 2-fluoro­benzoic acid mol­ecule. The two bridging FB anions, one chelating FB anion and one nicotinamide (NA) ligand coordinate to one Zn cation with a distorted square-pyramidal geometry, while the two bridging FB anions, one monodentate FB anion and one NA ligand coordinate to the other Zn cation with a distorted tetra­hedral geometry. Within the binuclear mol­ecule, the pyridine rings are oriented at a dihedral angle of 19.41 (14)°. In the crystal structure, the uncoordinated 2-fluorobenzoic acid mol­ecules are linked by O—H⋯O hydrogen bonding, forming centrosymmetric supra­molecular dimers. Inter­molecular N—H⋯O hydrogen bonds link the complex mol­ecules into a three-dimensional network. The π–π contacts between nearly parallel pyridine and benzene rings [dihedral angles of 19.41 (14) and 12.72 (16)°, respectively, centroid–centroid distances = 3.701 (2) and 3.857 (3) Å] may further stabilize the crystal structure. The fluorine atoms in two FB ligands are disordered over two positions, with occupancy ratios of 0.70:0.30

Tetra­aqua­bis(nicotinamide-κN 1)nickel(II) bis­(2-fluoro­benzoate)

The asymmetric unit of the title complex, [Ni(C6H6N2O)2(H2O)4](C7H4FO2)2, contains one-half of the complex cation with the NiII atom located on an inversion center, and a 2-fluoro­benzoate (FB) counter-anion. The four O atoms in the equatorial plane around the Ni atom form a slightly distorted square-planar arrangement with an average Ni—O bond length of 2.079 Å, and the slightly distorted octa­hedral coordination is completed by the two N atoms of the nicotinamide (NA) ligands in the axial positions. The dihedral angle between the carboxyl group and the attached benzene ring is 28.28 (11)°, while the pyridine and benzene rings are oriented at a dihedral angle of 8.31 (4)°. In the crystal structure, O—H⋯O, N—H⋯O, C—H⋯O, and C—H⋯F hydrogen bonds link the mol­ecules into a three-dimensional network. π–π Contacts between the pyridine and benzene rings [centroid–centroid distance = 3.626 (1) Å] may further stabilize the crystal structure. The 2-fluoro­benzoate anion is disordered over two orientations, with an occupancy ratio of 0.85:0.15

Diaqua­bis(2-bromo­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN 1)nickel(II)

In the monomeric centrosymmetric title NiII complex, [Ni(C7H4BrO2)2(C10H14N2O)2(H2O)2], the NiII ion is located on an inversion center. The asymmetric unit contains one 2-bromo­benzoate ligand, one diethyl­nicotinamide (DENA) ligand and one coordinated water mol­ecule. The four O atoms in the equatorial plane around the NiII ion form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by two N atoms of two DENA ligands in the axial positions. The dihedral angle between the benzene ring and the attached carboxyl­ate group is 87.73 (15)°, while the pyridine and benzene rings are oriented at a dihedral angle of 42.48 (7)°. In the crystal structure, O—H⋯O hydrogen bonds link the mol­ecules into a two-dimensional network parallel to (10). In addition, C—H⋯O hydrogen bonds are observed

Diaqua­bis(2-bromo­benzoato-κO)bis­(nicotinamide-κN 1)nickel(II)

The title NiII complex, [Ni(C7H4BrO2)2(C6H6N2O)2(H2O)2], is centrosymmetric. It contains two 2-bromo­benzoate (BB) ligands, two nicotinamide (NA) ligands and two water mol­ecules, all of them being monodentate. The four O atoms in the equatorial plane around the Ni atom form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl­ate group and the adjacent benzene ring is 30.81 (17)°, while the pyridine and benzene rings are oriented at a dihedral angle of 84.66 (6)°. In the crystal structure, O—H⋯O and N—H⋯O hydrogen bonds link the mol­ecules into a supra­molecular structure. A weak C—H⋯π inter­action is also found

Diaqua­bis(2-chloro­benzoato-κO)bis­(nicotinamide-κN 1)nickel(II)

The title NiII complex, [Ni(C7H4ClO2)2(C6H6N2O)2(H2O)2], is centrosymmetric with the Ni atom located on an inversion centre. The mol­ecule contains two 2-chloro­benzoate (CB) and two nicotinamide (NA) ligands and two water mol­ecules, all ligands being monodentate. The four O atoms in the equatorial plane around the Ni atom form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl group and the adjacent benzene ring is 29.48 (16)°, while the pyridine and benzene rings are oriented at a dihedral angle of 83.16 (5)°. In the crystal structure, O—H⋯O and N—H⋯O hydrogen bonds link the mol­ecules into infinite chains. π–π Contacts between the benzene and pyridine rings [centroid–centroid distance = 3.952 (1) Å] may further stabilize the crystal structure. There is also a C—H⋯π inter­action

Tetra­aqua­bis(nicotinamide-κN 1)cobalt(II) bis­(2-fluoro­benzoate)

The title complex, [Co(C6H6N2O)2(H2O)4](C7H4FO2)2, contains one Co(II) atom (site symmetry ), two monodentate nicotin­amide (NA) ligands, four coordinated water mol­ecules and two 2-fluoro­benzoate (FB) anions. The four O atoms in the equatorial plane around the Co atom form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl group and the adjacent benzene ring is 29.8 (3)°, while the pyridine and benzene rings are oriented at a dihedral angle of 7.97 (12)°. In the crystal structure, mol­ecules are linked by O—H⋯O, N—H⋯O and N—H⋯F hydrogen bonds, forming an infinite three-dimensional network. π–π Contacts between the pyridine and benzene rings [centroid–centroid distance = 3.673 (3) Å] may further stabilize the crystal structure

Diaqua­bis(2-bromo­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN 1)zinc(II)

In the centrosymmetric title complex, [Zn(C7H4BrO2)2(C10H14N2O)2(H2O)2], the ZnII atom is located on an inversion center. The asymmetric unit contains one 2-bromo­benzoate (BB), one diethyl­nicotinamide (DENA) ligand and one coordinating water molecule. The four O atoms in the equatorial plane around the Zn atom form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two N atoms of the DENA ligands in the axial positions. The dihedral angle between the carboxyl group and the adjacent benzene ring is 85.51 (12)°, while the pyridine and benzene rings are oriented at a dihedral angle of 44.07 (6)°. In the crystal structure, O—H⋯O hydrogen bonds link the mol­ecules into infinite chains

Diaqua­bis(2-bromo­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN 1)manganese(II)

The title MnII complex, [Mn(C7H4BrO2)2(C10H14N2O)2(H2O)2], is centrosymmetric. The mol­ecule contains two 2-bromo­benzoate (BB) and two diethyl­nicotinamide (DENA) ligands and two water mol­ecules, all ligands being monodentate. The four O atoms in the equatorial plane around the Mn atom form a slightly distorted square-planar arrangement, while the distorted octa­hedral coordination is completed by the two N atoms of the DENA ligands in the axial positions. The dihedral angle between the carboxyl group and the adjacent benzene ring is 79.95 (11)°, while the pyridine and benzene rings are oriented at a dihedral angle of 45.66 (6)°. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link the mol­ecules into infinite chains

Diaqua­bis(2-bromo­benzoato-κO)bis­(nicotinamide-κN 1)zinc(II)

The title ZnII complex, [Zn(C7H4BrO2)2(C6H6N2O)2(H2O)2], is centrosymmetric with the Zn atom on an inversion center. The mol­ecule contains two 2-bromo­benzoate (BB) and two nicotinamide (NA) ligands and two coordinated water mol­ecules, all ligands being monodentate. The four O atoms in the equatorial plane around the Zn atom form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl group and the adjacent benzene ring is 31.14 (12)°, while the pyridine and benzene rings are oriented at a dihedral angle of 83.54 (5)°. In the crystal structure, O—H⋯O and N—H⋯O hydrogen bonds link the mol­ecules into infinite chains. A weak C—H⋯π inter­action is also present

Diaqua­Bis(2-Chloro­Benzoato-Κo)Bis­(N,N-Diethyl­Nicotinamide-Κn1)Manganese(Ii)

In the monomeric title complex, [Mn(C7H4ClO2)2(C10H14N2O)2(H2O)2], the MnII atom is located on a crystallographic centre of inversion. The asymmetric unit contains one 2-chloro­benzoate (CB) ligand, one diethyl­nicotinamide (DENA) ligand and one coordinated water mol­ecule, all ligands being monodentate. The four O atoms in the equatorial plane around the Mn atom form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two pyridine N atoms of the DENA ligands in the axial positions. The dihedral angle between the carboxyl group and the adjacent benzene ring is 77.9 (11)°, while the pyridine and benzene rings are oriented at a dihedral angle of 45.94 (5)°. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link the mol­ecules into infinite chains.PubMedWoSScopu