21 research outputs found
Aquabis(4-fluorobenzoato-κO)bis(nicotinamide-κN 1)copper(II) nicotinamide hemisolvate trihydrate
The asymmetric unit of the title compound, [Cu(C7H4FO2)2(C6H6N2O)2(H2O)]·0.5C6H6N2O·3H2O, contains two aquabis(4-fluorobenzoato)bis(nicotinamide)copper(II) molecules, one nicotinamide solvent molecule and six water molecules. The CuII ion is coordinated by two O atoms from two 4-fluorobenzoate ligands, two N atoms from two nicotinamide ligands and one water O atom in a distorted square-pyramidal geometry. In the crystal, O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds consolidate the crystal packing, which also exhibits π–π interactions between the aromatic rings [centroid–centroid distances 3.692 (2)–3.794 (2) Å]
Di-μ-nicotinamide-κ2 N 1:O;κ2 O:N 1-bis[aquabis(4-bromobenzoato)-κO;κ2 O,O′-manganese(II)]
In the centrosymmetric dinuclear title compound, [Mn2(C7H4BrO2)4(C6H6N2O)2(H2O)2], the MnII atom is coordinated by one N atom from one bridging nicotinamide ligand and one O atom from another symmetry-related bridging nicotinamide ligand, three O atoms from two 4-bromobenzoate ligands and one water molecule in a distorted octahedral geometry. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 10.89 (16) and 8.4 (2)°, while the benzene rings are oriented at a dihedral angle of 6.09 (13)°. Intermolecular O—H⋯O, N—H⋯O and weak C—H⋯O hydrogen bonds link the molecules into a three-dimensional network. π–π interactions, indicated by short centroid–centroid distances [3.845 (2) Å between the benzene rings, 3.650 (2) Å between the pyridine rings and 3.700 (3) Å between the benzene and pyridine rings] further stabilize the structure
Bis(4-fluorobenzoato)-κ2 O,O′;κO-(4-fluorobenzoic acid-κO)bis(nicotinamide-κN 1)copper(II)
In the title CuII complex, [Cu(C7H4FO2)2(C7H5FO2)(C6H6N2O)2], the CuII cation is coordinated by two N atoms of two nicotinamide (NA) ligands, and by four O atoms from two 4-fluorobenzoate (PFB) anions and one 4-fluorobenzoic acid (PFBA) molecule, in a distorted octahedral geometry. In the molecule, two Cu—O bond lengths are significantly longer than the other two. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 11.08 (14), 7.62 (13) and 5.73 (11)°, while the benzene rings are oriented at dihedral angles of 15.62 (6), 33.71 (8) and 26.60 (8)°. In the crystal structure, extensive N—H⋯O, C—H⋯F and C—H⋯O hydrogen bonds link the molecules into a three-dimensional network. π–π contacts between the benzene rings [centroid-to-centroid distances = 3.5517 (15), 3.8456 (14) and 3.9265 (13) Å] further stabilize the crystal structure
Poly[[diaquamanganese(II)]-bis(μ-4-fluorobenzoato-κ2 O:O′)]
In the crystal structure of the title complex, [Mn(C7H4FO2)2(H2O)2]n, the MnII atom is located on an inversion centre. It is coordinated by two water molecules in the apical directions and four 4-fluorobenzoate (PFB) anions, bridging the symmetry related Mn atoms in the basal plane to form an infinite two-dimensional polymeric structure parallel to (100). The four O atoms of the PFB anions around the MnII atom form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two O atoms of the water molecules. The dihedral angle between the carboxylate group and the adjacent benzene ring is 27.29 (16)°. The O—H⋯O hydrogen bonds further connect the manganese-carboxylate units. π–π contacts between the benzene rings [centroid-centroid distance = 3.6894 (15) Å] further stabilize the crystal structure
Bis(4-ethylbenzoato-κO)bis(nicotinamide-κN 1)zinc(II)
The title ZnII complex, [Zn(C9H9O2)2(C6H6N2O)2], contains two 4-ethylbenzoate and two nicotinamide monodentate ligands, leading to a distorted tetrahedral coordination of the ZnII ion. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 10.33 (13) and 2.38 (11)°, while opposite pyridine and benzene rings are oriented at dihedral angles of 68.46 (5) and 81.09 (6)°. In the crystal, intermolecular N—H⋯O hydrogen bonds link the molecules, forming a three-dimensional network. C—H⋯O interactions also occur as well as two weak C—H⋯π interactions involving the benzene rings
Diaquabis(N,N-diethylnicotinamide-κN 1)bis(4-ethylbenzoato-κO)cobalt(II)
The title CoII complex, [Co(C9H9O2)2(C10H14N2O)2(H2O)2], contains two 4-ethylbenzoate (PEB), two monodentate diethylnicotinamide (DENA) ligands and two water molecules. The four O atoms in the equatorial plane around the CoII ion form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two N atoms of the DENA ligands in the axial positions. Intramolecular O—H⋯O hydrogen bonds link the water molecules to the carboxylate groups. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 4.52 (18) and 4.56 (18)°, while the pyridine rings and the benzene rings are oriented at dihedral angles of 7.76 (10) and 5.67 (13)°. In the crystal, intermolecular O—H⋯O hydrogen bonds link the molecules into chains propagating along [010]. C—H⋯O interactions and a π–π contact between the pyridine rings [centroid–centroid distance = 3.476 (2) Å] are also observed
Diaquabis(4-bromobenzoato-κO)bis(N,N-diethylnicotinamide-κN 1)manganese(II)
In the crystal structure of the title MnII complex, [Mn(C7H4BrO2)2(C10H14N2O)2(H2O)2], the MnII cation is located on an inversion center and coordinated by two diethylnicotinamide (DENA) ligands, two 4-bromobenzoate (PBB) anions and two water molecules in a distorted octahedral geometry. The dihedral angle between the carboxylate group and the adjacent benzene ring is 3.25 (14)°. In the molecule, the pyridine ring and the benzene ring are oriented at a dihedral angle of 77.24 (5)°. In the crystal, intermolecular C—H⋯O hydrogen bonds link the molecules into a two-dimensional network. Weak intermolecular C—H⋯O hydrogen bonds and π–π interactions between the pyridine rings of neighbouring molecules [centroid–centroid distance = 3.537 (1) Å] further consolidate the crystal packing
trans-Diaquabis(4-fluorobenzoato-κO)bis(nicotinamide-κN 1)nickel(II)
In the mononuclear NiII title complex, [Ni(C7H4FO2)2(C6H6N2O)2(H2O)2], the NiII atom, located on an inversion center, is coordinated by two nicotinamide and two 4-fluorobenzoate ligands and two water molecules in a distorted N2O4 octahedral geometry. The dihedral angle between the carboxylate group and the adjacent benzene ring is 8.95 (8)°, while the pyridine ring and the benzene ring are oriented at a dihedral angle of 75.01 (7)°. The water molecule links the adjacent carboxylate O atom via an intramolecular O—H⋯O hydrogen bond. In the crystal, O—H⋯O, N—H⋯O, C—H⋯O and C—H⋯F hydrogen bonds link the molecules into a three-dimensional network. π–π stacking between parallel pyridine rings [centroid–centroid distance = 3.7287 (11) Å] is also observed
Diaquabis(4-bromobenzoato-κO)bis(nicotinamide-κN 1)copper(II)
The asymmetric unit of the title mononuclear CuII complex, [Cu(C7H4BrO2)2(C6H6N2O)2(H2O)2], contains one half-molecule, the CuII atom being located on an inversion center. The unit cell contains two nicotinamide (NA), two 4-bromobenzoate (PBB) ligands and two coordinated water molecules. The four O atoms in the equatorial plane around the CuII ion form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxylate group and the adjacent benzene ring is 22.17 (16)°, while the pyridine ring and the benzene ring are oriented at a dihedral angle of 82.80 (6)°. In the crystal, N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds link the molecules into a three-dimensional network. A weak C—H⋯π interaction is also observed
Synthesis and characterization of mix-ligand complexes of Metal(II) 4- Ethylbenzoates
Bu çalışmada Cu(II), Co(II), Ni(II), Pb(II), Mn(II) ve Zn(II) 4-etilbenzoatların nikotinamid/N,N’-
dietilnikotinamid ligandları ile kompleksleri sentezlenmiştir. Komplekslerin yapılarını aydınlatmak için
elementel analiz, IR, UV-Vis,
1
H ve
13
C NMR spektroskopisi yöntemleri kullanılmıştır. Sentezlenen
komplekslerin termik özelliklerine bakıldığında su ligandı içeren komplekslerde ilk bozunma
basamağında su molekülleri yapıdan ayrılmaktadır. Devam eden basamaklarda organik ligandlar
tamamen veya kısmen bozunmaya uğramaktadır. Komplekslerin nihai termal bozunma ürünleri uygun
gelen metal veya metal oksittir.In this study, metal complexes of 4-ethylbenzoate containing nicotinamide and N,N’diethylnicotinamide
were synthesized. Elemental analysis, IR, UV-VIS,
1
H and
13
C NMR Spectroscopy methods were used for
the elucidation of the structures of complexes. The thermal behaviors of complexes were determined
by simultaneous thermal analysis techniques. The thermal decomposition of hydrated complexes
started with dehydration process. Organic ligands were partially or fully degraded at continued steps.
The final products of thermal decomposition have been determined as metal or metal oxides