Cost-efficient one-part alkali-activated mortars with low global warming potential for floor heating systems applications

Increasing building energy efficiency is one the most cost-effective ways to reduce emissions. The use of thermal insulation materials mitigates heat loss in buildings, therefore minimising heat energy needs. In recent years, several papers were published on the subject of foam alkali-activated cements with enhanced thermal conductivity. However, on those papers cost analysis was strangely avoided. This paper presents experimental results on one-part alkali-activated cements. It also includes global warming potential assessment and cost analysis. Foam one-part alkali-activated cements cost simulations considering two carbon dioxide social costs scenarios are also included. The results show that one-part alkali-activated cements mixtures based on 26%OPC + 58.3%FA + 8%CS + 7.7%CH and 3.5% hydrogen peroxide constitute a promising cost-efficient (67 euro/m3), thermal insulation solution for floor heating systems. This mixture presents a low global warming potential of 443 KgCO2eq/m3. The results confirm that in both carbon dioxide social cost scenarios the mixture 26 OPC + 58.3 FA + 8 CS + 7.7 CH with 3.5% hydrogen peroxide foaming agent is still the most cost efficient

Alkali activated slag mortars provide high resistance to chloride-induced corrosion of steel

The pore solutions of alkali-activated slag cements and Portland-based cements are very different in terms of their chemical and redox characteristics, particularly due to the high alkalinity and high sulfide content of alkali-activated slag cement. Therefore, differences in corrosion mechanisms of steel elements embedded in these cements could be expected, with important implications for the durability of reinforced concrete elements. This study assesses the corrosion behavior of steel embedded in alkali-activated blast furnace slag (BFS) mortars exposed to alkaline solution, alkaline chloride-rich solution, water, and standard laboratory conditions, using electrochemical techniques. White Portland cement (WPC) mortars and blended cement mortars (WPC and BFS) were also tested for comparative purposes. The steel elements embedded in immersed alkali-activated slag mortars presented very negative redox potentials and high apparent corrosion current values; the presence of sulfide reduced the redox potential, and the oxidation of the reduced sulfur-containing species within the cement itself gave an electrochemical signal that classical electrochemical tests for reinforced concrete durability would interpret as being due to steel corrosion processes. However, the actual observed resistance to chloride-induced corrosion was very high, as measured by extraction and characterization of the steel at the end of a 9-month exposure period, whereas the steel embedded in WPC mortars was significantly damaged under the same conditions

Mechanical performance of glass-based geopolymer matrix composites reinforced with cellulose fibers

Glass-based geopolymers, incorporating fly ash and borosilicate glass, were processed in conditions of high alkalinity (NaOH 10-13 M). Different formulations (fly ash and borosilicate in mixtures of 70-30 wt% and 30-70 wt%, respectively) and physical conditions (soaking time and relative humidity) were adopted. Flexural strength and fracture toughness were assessed for samples processed in optimized conditions by three-point bending and chevron notch testing, respectively. SEM was used to evaluate the fracture micromechanisms. Results showed that the geopolymerization efficiency is strongly influenced by the SiO2/Al2O3 ratio and the curing conditions, especially the air humidity. The mechanical performances of the geopolymer samples were compared with those of cellulose fiber-geopolymer matrix composites with different fiber contents (1 wt%, 2 wt%, and 3 wt%). The composites exhibited higher strength and fracture resilience, with the maximum effect observed for the fiber content of 2 wt%. A chemical modification of the cellulose fiber surface was also observe

Management and valorisation of wastes through use in producing alkali-activated cement materials

There is a growing global interest in maximising the re-use and recycling of waste, to minimise the environmental impacts associated with waste treatment and disposal. Use of high-volume wastes in the production of blended or novel cements (including alkali-activated cements) is well known as a key pathway by which these wastes can be re-used. This paper presents a critical overview of the urban, agricultural, mining and industrial wastes that have been identified as potential precursors for the production of alkali-activated cement materials, or that can be effectively stabilised/solidified via alkali activation, to assure their safe disposal. The central aim of this review is to elucidate the potential advantages and pitfalls associated with the application of alkali-activation technology to a wide variety of wastes that have been claimed to be suitable for the production of construction materials. A brief overview of the generation and characteristics of each waste is reported, accompanied by identification of opportunities for the use of alkali-activation technology for their valorisation and/or management

Development of durable “green” concrete exposed to deicing chemicals via synergistic use of locally available recycled materials and multi-scale modifiers

From the economic and social perspectives, the use of waste materials would not be attractive until their costs and quality can satisfy the construction requirements. In this study, a pure fly ash paste (PFAP) was developed in place of ordinary Portland cement paste (OPCP). This PFAP was prepared at room temperature and without direct alkali activation. The samples were prepared using only the as-received class C coal fly ash, water, and a very small amount of borax (Na2B4O7). On average, the PFAP featured 28-d compressive strength of about 36 MPa, and micro-nano hardness and elastic modulus 29% and 5%, higher than the OPCP, respectively. These mechanical and other properties of the PFAP make it a viable “green” construction binder suitable for a host of structural and non-structural applications. Advanced characterization of the raw material and PFAP pastes was employed to elucidate the hydration mechanisms of this “green” binder. The obtained knowledge sheds light on the role of class C CFA in the hydration process and may benefit the expanded use of various CFAs in cementitious materials

Hybrid fly ash based alkali activated cements

Alkaline activation is one of the most perspective ways for creating very high volumes fly ash cements. The main phases of structure in such “hybrid” systems are represented by mixes N-A-S-H and N-C-A-S-H new formations. The paper is showing differences in structure formation and properties of low-Ca and high-Ca-containing fly ash alkali activated cements. Appropriate pplications are shown

The reaction of slag in cement: theory and computer modelling

In this study, theoretical models available for the reaction of both pure slag\ud (alkali-activated) and slag-blended cement are reviewed. They were developed by using stoichiometric computations