1,052 research outputs found
Accurate prediction of heat conductivity of water by a neuroevolution potential
We propose an approach that can accurately predict the heat conductivity of
liquid water. On the one hand, we develop an accurate machine-learned potential
based on the neuroevolution-potential approach that can achieve
quantum-mechanical accuracy at the cost of empirical force fields. On the other
hand, we combine the Green-Kubo method and the spectral decomposition method
within the homogeneous nonequilibrium molecular dynamics framework to account
for the quantum-statistical effects of high-frequency vibrations. Excellent
agreement with experiments under both isobaric and isochoric conditions within
a wide range of temperatures is achieved using our approach.Comment: 8 pages, 7 figure
RbHe Potential Energy Surface Sensitivity Study
This paper studies how alterations of features of RbHe potential energy surfaces (PES) for a diode pumped alkali laser (DPAL) system effect the collisional cross section. The Split-Operator method is used to propagate a wave function along these PES and because they are radially coupled, the wave function can be transmitted from the starting surface to other energy surfaces. This transmittance is encoded in the correlation function. The full Hamiltonian used for propagation consists of the electronic potential, the nuclear kinetic energy, and the Coriolis coupling. The correlation function is used to generate the Scattering Matrix elements. These elements describe the transmittance and reflectance coefficients of the reactant wave packet. A temperature averaged cross section is then calculate for the Ï1/2 to Ï3/2 transition. Despite large changes in the correlation function and S-Matrix elements, the temperature averaged cross section varied little with change in PES and fell within experimental error margins
Linear chemically sensitive electron tomography using DualEELS and dictionary-based compressed sensing
We have investigated the use of DualEELS in elementally sensitive tilt series tomography in the scanning transmission electron microscope. A procedure is implemented using deconvolution to remove the effects of multiple scattering, followed by normalisation by the zero loss peak intensity. This is performed to produce a signal that is linearly dependent on the projected density of the element in each pixel. This method is compared with one that does not include deconvolution (although normalisation by the zero loss peak intensity is still performed). Additionaly, we compare the 3D reconstruction using a new compressed sensing algorithm, DLET, with the well-established SIRT algorithm. VC precipitates, which are extracted from a steel on a carbon replica, are used in this study. It is found that the use of this linear signal results in a very even density throughout the precipitates. However, when deconvolution is omitted, a slight density reduction is observed in the cores of the precipitates (a so-called cupping artefact). Additionally, it is clearly demonstrated that the 3D morphology is much better reproduced using the DLET algorithm, with very little elongation in the missing wedge direction. It is therefore concluded that reliable elementally sensitive tilt tomography using EELS requires the appropriate use of DualEELS together with a suitable reconstruction algorithm, such as the compressed sensing based reconstruction algorithm used here, to make the best use of the limited data volume and signal to noise inherent in core-loss EELS
The photochemical ring-opening of 1,3-cyclohexadiene imaged by ultrafast electron diffraction
The ultrafast photoinduced ring-opening of 1,3-cyclohexadiene constitutes a
textbook example of electrocyclic reactions in organic chemistry and a model
for photobiological reactions in vitamin D synthesis. Here, we present direct
and unambiguous observation of the ring-opening reaction path on the
femtosecond timescale and sub-{\AA}ngstr\"om length scale by megaelectronvolt
ultrafast electron diffraction. We follow the carbon-carbon bond dissociation
and the structural opening of the 1,3-cyclohexadiene ring by direct measurement
of time-dependent changes in the distribution of interatomic distances. We
observe a substantial acceleration of the ring-opening motion after internal
conversion to the ground state due to steepening of the electronic potential
gradient towards the product minima. The ring-opening motion transforms into
rotation of the terminal ethylene groups in the photoproduct 1,3,5-hexatriene
on the sub-picosecond timescale. Our work demonstrates the potential of
megaelectronvolt ultrafast electron diffraction to elucidate photochemical
reaction paths in organic chemistry
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