Ultra low bending loss equiangular spiral photonic crystal fibers in the terahertz regime

An Equiangular Spiral Photonic Crystal Fiber (ES-PCF) design in Topas® for use in the Terahertz regime is presented. The design shows ultra low bending loss and very low confinement loss compared to conventional Hexagonal PCF (H-PCF). The ES-PCF has excellent modal confinement properties, together with several parameters to allow the optimization of the performance over a range of important characteristics. A full vector Finite Element simulation has been used to characterize the design which can be fabricated by a range of techniques including extrusion and drilling

Designing microstructured polymer optical fibers for cascaded quadratic soliton compression of femtosecond pulses

The dispersion of index-guiding microstructured polymer optical fibers is calculated for second-harmonic generation. The quadratic nonlinearity is assumed to come from poling of the polymer, which in this study is chosen to be the cyclic olefin copolymer Topas. We found a very large phase mismatch between the pump and the second-harmonic waves. Therefore the potential for cascaded quadratic second-harmonic generation is investigated in particular for soliton compression of fs pulses. We found that excitation of temporal solitons from cascaded quadratic nonlinearities requires an effective quadratic nonlinearity of 5 pm/V or more. This might be reduced if a polymer with a low Kerr nonlinear refractive index is used. We also found that the group-velocity mismatch could be minimized if the design parameters of the microstructured fiber are chosen so the relative hole size is large and the hole pitch is on the order of the pump wavelength. Almost all design-parameter combinations resulted in cascaded effects in the stationary regime, where efficient and clean soliton compression can be found. We therefore did not see any benefit from choosing a fiber design where the group-velocity mismatch was minimized. Instead numerical simulations showed excellent compression of $\lambda=800$ nm 120 fs pulses with nJ pulse energy to few-cycle duration using a standard endlessly single-mode design with a relative hole size of 0.4.Comment: 11 pages, 8 figures, submitted to JOSA

Selective Serial Multi-Antibody Biosensing with TOPAS Microstructured Polymer Optical Fibers

We have developed a fluorescence-based fiber-optical biosensor, which can selectively detect different antibodies in serial at preselected positions inside a single piece of fiber. The fiber is a microstructured polymer optical fiber fabricated from TOPAS cyclic olefin copolymer, which allows for UV activation of localized sensor layers inside the holes of the fiber. Serial fluorescence-based selective sensing of Cy3-labelled α-streptavidin and Cy5-labelled α-CRP antibodies is demonstrated

Prismatic to asbestiform offretite from Northern Italy. Occurrence, morphology and crystal-chemistry of a new potentially hazardous zeolite

A multi-methodological approach, based upon field investigation, morphological characterization, chemical analysis and structure refinement was applied to different samples of fibrous offretite, a new potentially hazardous zeolite recently discovered in northern Italy. Their morphology ranges from stocky-prismatic to asbestiform. All the investigated fibers may be considered as "inhalable", and they are well within the range of the "more carcinogenic fibers" regarding diameter. As regards the length, the main mode observed in the asbestiform samples is 20-25 mu m, and similar to 93% of the measured fibers are >5 mu m and may be significantly associated with carcinogenesis also in terms of lengths. The chemical-structural features of the investigated fibers are comparable: the extra-framework cations K+, Mg2+ and Ca2+ are present in all samples in similar proportions, and refined cell parameters are similar among the samples. Offretite occurs in 60% of the investigated sites, with an estimated amount up to 75 vol % of the associated minerals. The presence of this mineral could be of concern for risk to human health, especially if one considers the vast number of quarries and mining-related activities that are operating in the zeolite host rocks