Green process intensification using microreactor technology for the synthesis of biobased chemicals and fuels

Microreactor technology as an important means of process intensification has opened vast opportunities for green and sustainable chemical synthesis. Over the past decade, a promising research direction has been seen in the utilization of microreactors for intensifying catalytic biomass conversion. This Perspective provides a concise overview on green process intensification in microreactors for the synthesis of value-added chemicals and fuels from biomass. The focus is laid on process intensification merits of microreactor technology, its alignment with green chemistry and green engineering principles, typical application examples for manufacturing biobased chemicals and fuels including the synthesis of furanic platform chemicals and their derivatives from mono- and disaccharides, liquid-phase oxidation and hydrogenation of lignocellulosic biomass derivatives, and biodiesel synthesis. Finally, an outlook is provided for future research directions, including among others solid (catalyst, feed and product) handling strategies, process integration in cascades or one microreactor, expanding biomass transformation database, photocatalysis and use of novel solvents in microflow

Systematic sustainable process design and analysis of biodiesel processes

Biodiesel is a promising fuel alternative compared to traditional diesel obtained from conventional sources such as fossil fuel. Many flowsheet alternatives exist for the production of biodiesel and therefore it is necessary to evaluate these alternatives using defined criteria and also from process intensification opportunities. This work focuses on three main aspects that have been incorporated into a systematic computer-aided framework for sustainable process design. First, the creation of a generic superstructure, which consists of all possible process alternatives based on available technology. Second, the evaluation of this superstructure for systematic screening to obtain an appropriate base case design. This is done by first reducing the search space using a sustainability analysis, which provides key indicators for process bottlenecks of different flowsheet configurations and then by further reducing the search space by using economic evaluation and life cycle assessment. Third, the determination of sustainable design with/without process intensification using a phenomena-based synthesis/design method. A detailed step by step application of the framework is highlighted through a biodiesel production case study

Synergism of microwaves and ultrasound for advanced biorefineries

AbstractConventional energy sources are limited and non-renewable and their consumption contributes to greenhouse gas emissions. The world is in need of advanced biorefineries to meet ever growing energy demands associated with population growth and economic development. An advanced biorefinery should use renewable and sustainable (both in quality and quantity) feedstock that gives rise to higher energy gains with minimum non-renewable energy and resource consumption. Development of advanced biorefineries is currently encircled by two major issues. The first issue is to ensure adequate biofuel feedstock supplies while the second issue is to develop resource-efficient technologies for the feedstock conversion to maximize energy and economic and environmental benefits. While microalgae, microbial derived oils, and agricultural biomass and other energy crops show great potential for meeting current energy demands in a sustainable manner, process intensification and associated synergism can improve the resource utilization efficiency. Synergism of process intensification tools is important to increase energy efficiency, reduce chemical utilization and associated environmental impacts, and finally process economics. Among the many process intensification methods, this commentary provides a perspective on the essential role of MWs and US and their synergy in biofuel production. Individual, sequential, and simultaneous applications of MWs and US irradiations can be utilized for process intensification of various biofuels production and selective recovery of high value bioproducts. Process related barriers, namely mass and heat transfer limitations, can be eliminated by this synergism while improving the reaction efficiency and overall process economics significantly. In this article, a brief review focused on recent developments in MW and US mediated process intensification for biofuel synthesis and associated issues in their synergism followed by a discussion on current challenges and future prospective is presented

Intensified processes for FAME production from waste cooking oil: a technological review

This article reviews the intensification of fatty acid methyl esters (FAME) production from waste cooking oil (WCO) using innovative process equipment. In particular, it addresses the intensification of WCO feedstock transformation by transesterification, esterification and hydrolysis reactions. It also discusses catalyst choice and product separation. FAME production can be intensified via the use of a number of process equipment types, including as cavitational reactors, oscillatory baffled reactors, microwave reactors, reactive distillation, static mixers and microstructured reactors. Furthermore, continuous flow equipment that integrate both reaction and separation steps appear to be the best means for intensifying FAME production. Heterogeneous catalysts have also shown to provide attractive results in terms of reaction performance in certain equipment, such as microwave reactors and reactive distillation

Sustainable development : a model Indonesian SRI co-operative : this research paper is presented in partial fulfilment of the requirements for the degree of Master of International Development, Massey University, New Zealand

This research report explores how ‘sustainable livelihoods’ have been achieved at a model cooperative using the ‘System of Rice Intensification’ named SIMPATIK. To conduct the research a novel template was developed. The framework was required following a review of sustainable livelihood literature which found deficiencies with the ‘sustainable livelihoods framework’, particularly its treatment of equity, social capital, culture and agro-ecology which disqualified the framework as an appropriate approach for the research. Amekawa’s (2011) ‘Integrated Sustainable Livelihoods Framework’ which synthesises agro-ecology and the sustainable livelihoods framework is then discussed. Further work is then presented on social capital which this paper argues has a critical role in facilitating access to livelihood capitals. A discussion of the significance of culture then follows to underline its importance as a form of livelihood capital. The research then introduces an operational model that is appropriate to the local cultural, institutional and geographical context to demonstrate how livelihood capitals are linked to livelihood outcomes, a model I have labelled the ‘Apt-Integrated Sustainable Livelihoods Framework’. This framework is then informed through field research at the SIMPATIK co-operative. Impact pathways through ‘synergetic forms of social capital’ and the System of Rice Intensification (SRI) are shown indeed to lead to sustainable livelihood outcomes for research participants. The ‘sequencing’ of livelihood capitals is seen to be critical and the research culminates in the development of a ‘SRI Co-operative Template for Sustainable Livelihoods’; a transferable model that shows how SRI can be promoted as a sustainable livelihood strategy

CGIAR Research Program on Forests, Trees and Agroforestry - Plan of Work and Budget 2020

There were no significant changes in 2019 to FTA’s theory of change1. FTA plans all its work on the basis of its operational priorities. These, in turn, focusresearch towards major development demands and knowledge gaps, orienting FTA towards the implementation of the SDGs and other global commitments. Three operational priorities were added in 2020 (see list in Appendix 1) to better delineate pre-existing research areas addressing development bottlenecks needing dedicated investment and visibility: smallholder tree-crop commodities, tree seeds and seedlings delivery systems, and foresight. FTA organized in 2019, at the request of its ISC, a joint ISC-FTA workshop on impact assessment methods for the program. Based on the outcomes of this workshop FTA will, inter alia, revisit in 2020 its impact pathways and end of programme outcomes, and if need be, corresponding adjustments to the ToC of FTA and/or of its FPs will be made