MEIS investigations of surface structure

The early work of the FOM-AMOLF group in Amsterdam clearly demonstrated the potential of medium energy ion scattering (MEIS), typically using 100 keV H+ incident ions, to investigate the structure of surfaces, but most current applications of the method are focussed on near-surface compositional studies of non-crystalline films. However, the key strengths of the MEIS technique, notably the use of blocking curves in double-alignment experiments and absolute yield measurements, are extremely effective in providing detailed near-surface structural information for a wide range of crystalline materials. This potential and the underlying methodology, is illustrated through examples of applications to the study of layer-dependent composition and structure in alloy surfaces, in studies of the surface crystallography of an oxide surface (rutile TiO2(1 1 0)) and in investigations of complex adsorbate-induced reconstruction of metal surfaces, including the pseudo-(1 0 0) reconstruction of Cu(1 1 1) induced by adsorption of atomic N and molecular methylthiolate (CH3S–). In addition to the use of calibrated blocking curves, the use of the detailed spectral shape of the surface peak in the scattered ion energy spectra, as a means of providing single-atomic layer resolution of the surface structure, is also discussed

On the surface structure of sunspots

A precise knowledge of the surface structure of sunspots is essential to construct adequate input models for helioseismic inversion tools. We summarize our recent findings about the velocity and magnetic field in and around sunspots using HINODE observation. To this end we quantize the horizontal and vertical component of the penumbral velocity field at different levels of precision and study the moat flow around sunspot. Furthermore, we find that a significant amount of the penumbral magnetic fields return below the surface within the penumbra. Finally, we explain why the related opposite polarity signals remain hidden in magnetograms constructed from measurements with limited spectral resolution.Comment: 5 Pages, 2 Figures, 3 Movies To appear in Astronomical Notes Vol 333, Issue 10, pp.1009-101

Nanoscale surface structure–activity in electrochemistry and electrocatalysis

Nanostructured electrochemical interfaces (electrodes) are found in diverse applications ranging from electrocatalysis and energy storage to biomedical and environmental sensing. These functional materials, which possess compositional and structural heterogeneity over a wide range of length scales, are usually characterized by classical macroscopic or “bulk” electrochemical techniques that are not well-suited to analyzing the nonuniform fluxes that govern the electrochemical response at complex interfaces. In this Perspective, we highlight new directions to studying fundamental electrochemical and electrocatalytic phenomena, whereby nanoscale-resolved information on activity is related to electrode structure and properties colocated and at a commensurate scale by using complementary high-resolution microscopy techniques. This correlative electrochemical multimicroscopy strategy aims to unambiguously resolve structure and activity by identifying and characterizing the structural features that constitute an active surface, ultimately facilitating the rational design of functional electromaterials. The discussion encompasses high-resolution correlative structure–activity investigations at well-defined surfaces such as metal single crystals and layered materials, extended structurally/compositionally heterogeneous surfaces such as polycrystalline metals, and ensemble-type electrodes exemplified by nanoparticles on an electrode support surface. This Perspective provides a roadmap for next-generation studies in electrochemistry and electrocatalysis, advocating that complex electrode surfaces and interfaces be broken down and studied as a set of simpler “single entities” (e.g., steps, terraces, defects, crystal facets, grain boundaries, single particles), from which the resulting nanoscale understanding of reactivity can be used to create rational models, underpinned by theory and surface physics, that are self-consistent across broader length scales and time scales

Liquid Surface Wave Band Structure Instabilities

We study interfacial instabilities between two spatially periodically sheared ideal fluids. Bloch wavefunction decompositions of the surface deformation and fluid velocities result in a nonhermitian secular matrix with an associated band structure that yields both linear oscillating and nonoscillating instabilities, enhanced near Bragg planes corresponding to the periodicity determined by converging or diverging surface flows. The instabilities persist even when the dynamical effects of the upper fluid are neglected, in contrast to the uniform shear Kelvin-Helmholtz (KH) instability. Periodic flows can also couple with uniform shear and suppress standard KH instabilities.Comment: Dedicated to the memory of Marko V. Jaric'. 5 pp, 3 .eps figures, slightly shortened version to appear in Phys. Rev. let

Calculated Cleavage Behavior and Surface States of LaOFeAs

The layered structure of the iron based superconductors gives rise to a more or less pronounced two-dimensionality of their electronic structure, most pronounced in LaOFeAs. A consequence are distinct surface states to be expected to influence any surface sensitive experimental probe. In this work a detailed density functional analysis of the cleavage behavior and the surface electronic structure of LaOFeAs is presented. The surface states are obtained to form two-dimensional bands with their own Fermi surfaces markedly different from the bulk electronic structure

Magnetic deformation of the white dwarf surface structure

The influence of strong, large-scale magnetic fields on the structure and temperature distribution in white dwarf atmospheres is investigated. Magnetic fields may provide an additional component of pressure support, thus possibly inflating the atmosphere compared to the non-magnetic case. Since the magnetic forces are not isotropic, atmospheric properties may significantly deviate from spherical symmetry. In this paper the magnetohydrostatic equilibrium is calculated numerically in the radial direction for either for small deviations from different assumptions for the poloidal current distribution. We generally find indication that the scale height of the magnetic white dwarf atmosphere enlarges with magnetic field strength and/or poloidal current strength. This is in qualitative agreement with recent spectropolarimetric observations of Grw+10\degr8247. Quantitatively, we find for e.g. a mean surface poloidal field strength of 100 MG and a toroidal field strength of 2-10 MG an increase of scale height by a factor of 10. This is indicating that already a small deviation from the initial force-free dipolar magnetic field may lead to observable effects. We further propose the method of finite elements for the solution of the two-dimensional magnetohydrostatic equilibrium including radiation transport in the diffusive approximation. We present and discuss preliminary solutions, again indicating on an expansion of the magnetized atmosphere.Comment: 14 pages with 14 figure

The emerging use of magnetic resonance imaging to study river bed dynamics

The characterization of surface and sub-surface sedimentology has long been of interest to gravel-bed river researchers. The determination of surface structure is important as it exerts control over bed roughness, near-bed hydraulics and particle entrainment for transport1. Similarly, interpretation of the sub-surface structure and flow is critical in the analysis of bed permeability, the fate of pollutants and maintaining healthy hyporheic ecology 2.For example, many invertebrates (e.g. mayfly, caddis) and fish (e.g. salmon) lay their eggs below the river bed surface, and rely on sub-surface flows to supply the necessary oxygen and nutrients. Whilst turbulent surface flows drive these small sub-surface flows, they can also convey sand and silts that clogs the surface and sub-surface pore spaces. Reduction in sub-surface flows can starve eggs of oxygen such that larvae or juveniles do not emerge. This is particularly critical in Scottish gravel-bed rivers as the rising supply and deposition of fine sediment (silts and sands) is contributing to the dramatic decline in wild salmon. In order to gain a better understanding of such flow-sediment-ecology interactions in river systems, laboratory experiments are conducted using long rectangular flow tanks called “flumes”, see figure 1a,1b. Here, traditional techniques for analysing sediment structure are typically constrained to 1D or 2D approaches, such as coring, photography etc. Even where more advanced techniques are available (e.g. laser displacement scanning), these tend to be restricted to imaging the surface of the sediment bed. Using Magnetic Resonance Imaging (MRI) overcomes these limitations, providing researchers with a non-invasive technique with which to provide novel 3D spatio-temporal data on the internal pore structure. In addition the important sub-surface flows can be investigated by adding MRI contrast agents to the flowing surface water

Higher Spin Klein Surfaces

We find all m-spin structures on Klein surfaces of genus larger than one. An m-spin structure on a Riemann surface P is a complex line bundle on P whose m-th tensor power is the cotangent bundle of P. A Klein surface can be described by a pair (P,tau), where P is a Riemann surface and tau is an anti-holomorphic involution on P. An m-spin structure on a Klein surface (P,tau) is an m-spin structure on the Riemann surface P which is preserved under the action of the anti-holomorphic involution tau. We determine the conditions for the existence and give a complete description of all real m-spin structures on a Klein surface. In particular, we compute the number of m-spin structures on a Klein surface (P,tau) in terms of its natural topological invariants.Comment: v3: minor corrections; v2: 29 pages, 4 figures; typos corrected, Theorems 4.3 and 4.4 rephrase

Structure determination of the reconstructed Au(110) surface

The LEED pattern of the Au(110) surface shows a (1 × 2) and also a (1× 3) superstructure. The (1 × 2) superstructure has been determined by comparison of LEED intensities with model calculations. The missing row model is the most probable model. A minimum of the averaged r-factor, , has been found for 15% contraction of the first layer spacing without atomic displacements in the second layer