Fabrication of Hollow AlAu2 Nanoparticles by Solid State Dewetting and Oxidation of Al on Sapphire Substrate

The Al-Au binary diffusion couple is a classic example of the system exhibiting Kirkendall voiding during interdiffusion. We demonstrate that this effect, which is a major reason for failures of the wire bonds in microelectronics, can be utilized for producing hollow AlAu2 nanoparticles attached to sapphire substrate. To this end, we produced the core-shell Al-Au nanoparticles by performing a solid state dewetting treatment of Al thin film deposited on sapphire substrate, followed by the deposition of thin Au layer on the top of dewetted sample. Annealing of the core-shell nanoparticles in air resulted in outdiffusion of Al from the particles, formation of pores, and growth of the AlAu2 intermetallic phase in the particles. We demonstrated that the driving force for hollowing is the oxidation reaction of the Al atoms at the Au-sapphire interface, leading to the homoepitaxial growth of newly formed alumina at the interface. We developed a kinetic model of hollowing controlled by diffusion of oxygen through the Au thin film, and estimated the solubility of oxygen in solid Au. Our work demonstrates that the core-shell nanoparticles attached to the substrate can be hollowed by the Kirkendall effect in the thin film spatially separated from the particles.Comment: 27 pages, 8 figure

In search of the hollow crown

The first volume in a series of comparative studies within the ESRC's Whitehall Programme focuses on core executives in five parliamentary democracies comparing the Westminster model as in Australia, Canada and Britain with the continental democracies of Germany and the Netherlands showing how political leadership is shackled by a vast array of constraints, from globalisation to internal fragmentation and rationalisation, making a heroic model of decisive political leadership hard to sustain

Static and dynamic properties of shell-shaped condensates

Static, dynamic, and topological properties of hollow systems differ from those that are fully filled as a result of the presence of a boundary associated with an inner surface. Hollow Bose-Einstein condensates (BECs) naturally occur in various ultracold atomic systems and possibly within neutron stars but have hitherto not been experimentally realized in isolation on Earth because of gravitational sag. Motivated by the expected first realization of fully closed BEC shells in the microgravity conditions of the Cold Atomic Laboratory aboard the International Space Station, we present a comprehensive study of spherically symmetric hollow BECs as well as the hollowing transition from a filled sphere BEC into a thin shell through central density depletion. We employ complementary analytic and numerical techniques in order to study equilibrium density profiles and the collective mode structures of condensate shells hosted by a range of trapping potentials. We identify concrete and robust signatures of the evolution from filled to hollow structures and the effects of the emergence of an inner boundary, inclusive of a dip in breathing-mode-type collective mode frequencies and a restructuring of surface mode structure across the transition. By extending our analysis to a two-dimensional transition of a disk to a ring, we show that the collective mode signatures are an essential feature of hollowing, independent of the specific geometry. Finally, we relate our work to past and ongoing experimental efforts and consider the influence of gravity on thin condensate shells. We identify the conditions under which gravitational sag is highly destructive and study the mode-mixing effects of microgravity on the collective modes of these shells.Comment: 26 pages, 13 figure

The Japanese model in retrospective : industrial strategies, corporate Japan and the 'hollowing out' of Japanese industry

This article provides a retrospective look at the Japanese model of industrial development. This model combined an institutional approach to production based around the Japanese Firm (Aoki's, J-mode) and strategic state intervention in industry by the Japanese Ministry of International Trade and Industry (MITI). For a long period, the alignment of state and corporate interests appeared to match the wider public interest as the Japanese economy prospered. However, since the early 1990s, the global ambitions of the corporate sector have contributed to a significant 'hollowing out' of Japan's industrial base. As the world today looks for a new direction in economic management, we suggest the Japanese model provides policy-makers with a salutary lesson in tying the wider public interest with those of the corporate sector

Changes in Manufacturing Linkage Patterns in Scotland and Wales: Hollowing Out and Foreign Direct Investment?

Trends in inward investment in Scotland and Wales have influenced manufacturing’s inter-linkages with the local economy in different ways. The paper shows that there could be a hollowing out of the manufacturing sector in these regional economies which is linked to trends in inward investment.

THE PROBLEM OF REGIONAL "HOLLOWING OUT" IN JAPAN : LESSONS FOR REGIONAL INDUSTRIAL POLICY

This paper considers the problems of "hollowing out" using a Case Study of Japan's machinery sector. In doing so, it explores the roots of the present crisis by focusing upon the role played by Japan's large transnational corporations. This is important because these corporations are the "central actors" within the Japanese economy and they control a significant proportion of Japanese manufacturing. It is their strategic decisions - those that determine the level and location of investment, employment and output - which ultimately shape the development path for Japanese industry (see Cowling and Sugden, 1994, 1998). In recent years, Japan’s large transnationals have become engaged in the process of elite globalisation, pursuing their own interests at the expense of domestic Japanese industry. This is a fundamental insight that is crucial for designing appropriate policy responses to arrest Japan's current industrial decline. It is argued that the lessons from Japan's experience might guide policymakers in other regions, such as Wisconsin, who are concerned with future industrial development, the effects of globalisation and problems of "hollowing out".Machinery sector ; strategic-decision making ; strategic failure ; industrial policy.

From 3D Models to 3D Prints: an Overview of the Processing Pipeline

Due to the wide diffusion of 3D printing technologies, geometric algorithms for Additive Manufacturing are being invented at an impressive speed. Each single step, in particular along the Process Planning pipeline, can now count on dozens of methods that prepare the 3D model for fabrication, while analysing and optimizing geometry and machine instructions for various objectives. This report provides a classification of this huge state of the art, and elicits the relation between each single algorithm and a list of desirable objectives during Process Planning. The objectives themselves are listed and discussed, along with possible needs for tradeoffs. Additive Manufacturing technologies are broadly categorized to explicitly relate classes of devices and supported features. Finally, this report offers an analysis of the state of the art while discussing open and challenging problems from both an academic and an industrial perspective.Comment: European Union (EU); Horizon 2020; H2020-FoF-2015; RIA - Research and Innovation action; Grant agreement N. 68044

Enhancing Robustness and Immunization in geographical networks

We find that different geographical structures of networks lead to varied percolation thresholds, although these networks may have similar abstract topological structures. Thus, the strategies for enhancing robustness and immunization of a geographical network are proposed. Using the generating function formalism, we obtain the explicit form of the percolation threshold $q_{c}$ for networks containing arbitrary order cycles. For 3-cycles, the dependence of $q_c$ on the clustering coefficients is ascertained. The analysis substantiates the validity of the strategies with an analytical evidence.Comment: 6 pages, 8 figure